Competitive interfacial behavior in sodium caseinates-hydroxypropyl cellulose mixed systems

[en] In this work, interactions between hydroxypropyl cellulose (HPC) and sodium caseinates (Na-cas) at the air-water interface were studied. The surface tension, surface rheology, and film compatibility of the mixed protein/polysaccharide system were investigated. Tensiometry experiments showed that HPC is more surface-active than proteins, and is preferentially adsorbed at the interface. This molecule is able to migrate to the interface faster than Na-cas despite its larger size. At low HPC concentration, proteins adsorb first but HPC being more surface-active will eventually substitute them at the interface. The use of the pendant drop tensiometer allowed the real-time monitoring of protein displacement; an immediate decrease in surface tension was observed when HPC was added to a Na-cas solution. The analysis of the compression isotherms of Na-cas/HPC mixed films revealed partial miscibility between the two species within the monolayer; the films were less expanded than expected from the ideal behavior of binary mixtures. The dilatational rheology experiments showed that the presence of a very small amount of HPC had a significant effect on the viscoelastic properties of the interface. This work reported for the first time the competitive adsorption between Na-cas and HPC at the A/W interface.

Research center :

SMARTECH - Smart Technologies for Food and Biobased Products - ULiège
Puratos NV

Disciplines :

Food science

Author, co-author :

Cremer, Gilles ; Université de Liège - ULiège > Département GxABT > Smart Technologies for Food and Biobased Products (SMARTECH)

Van Hoed, Vera ; Puratos NV

Danthine, Sabine ; Université de Liège - ULiège > TERRA Research Centre > Smart Technologies for Food and Biobased Products (SMARTECH)

Laveaux, Anne-Sophie; Puratos NV

Blecker, Christophe ; Université de Liège - ULiège > TERRA Research Centre > Smart Technologies for Food and Biobased Products (SMARTECH)

Language :

English

Title :

Competitive interfacial behavior in sodium caseinates-hydroxypropyl cellulose mixed systems

Alternative titles :

[fr] Comportement interfacial compétitif dans les systèmes mixtes caséinates de sodium-hydroxypropylcellulose

Publication date :

April 2023

Journal title :

Food Hydrocolloids

ISSN :

0268-005X

eISSN :

1873-7137

Publisher :

Elsevier BV

Volume :

137

Pages :

108427

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

https://api.elsevier.com/content/article/PII:S0268005X2200947X?httpAccept=text/xml

Available on ORBi :

since 29 December 2022

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