Determination of Size, Size Distribution, and Concentration of Nanoparticles Using ICP‐MS in the Context of SERS Substrates

Horne, Julie; Beckers, Pierre; Kemik, Kevser; De Bleye, Charlotte; Sacré, Pierre‐Yves; Thelen, Nicolas; Hubert, Philippe; Ziemons, Eric; Hubert, Cédric

doi:10.1002/jrs.6746

Article (Scientific journals)

Determination of Size, Size Distribution, and Concentration of Nanoparticles Using ICP‐MS in the Context of SERS Substrates

Horne, Julie; Beckers, Pierre; Kemik, Kevser et al.

2024 • In Journal of Raman Spectroscopy

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/324389

DOI
10.1002/jrs.6746

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Abstract :

[en] ABSTRACTSurface enhanced Raman scattering (SERS) is a widely used vibrational spectroscopic technique employing metallic nanostructures to enhance an inherent Raman signal. This study aimed to develop a method for the characterization of SERS substrates in a single analysis by inductively coupled plasma mass spectrometry (ICP‐MS) equipped with the single particle module (spICP‐MS). For this development, the well‐known Lee‐Meisel protocol was selected as starting point to synthesize gold nanoparticles (AuNps) and silver nanoparticles (AgNps). A spICP‐MS method was successfully developed and gave the mean size, size distribution, and concentration of nanoparticles in only one single analysis. Reference techniques were used to confirm these results namely dynamic light scattering, transmission electron microscopy, and UV–Visible spectroscopy. Thanks to the ICP‐MS characterization, it was observed that AgNps synthesized by chemical reduction presented more variability than the AuNps. The dissolved elements concentration in the suspension was investigated. It appeared that reaction yields were close to 100% for the six syntheses. This analysis may be repeated over time to evaluate the suspension stability and monitor any potential degradation of Nps. To conclude, ICP‐MS is a powerful technique to characterize SERS substrates and could be an interesting alternative to other characterization techniques.

Research Center/Unit :

CIRM - Centre Interdisciplinaire de Recherche sur le Médicament - ULiège

Disciplines :

Pharmacy, pharmacology & toxicology

Author, co-author :

Horne, Julie ; Université de Liège - ULiège > Unités de recherche interfacultaires > Centre Interdisciplinaire de Recherche sur le Médicament (CIRM)

Beckers, Pierre ; Université de Liège - ULiège > Département de pharmacie > Chimie analytique

Kemik, Kevser ; Université de Liège - ULiège > Unités de recherche interfacultaires > Centre Interdisciplinaire de Recherche sur le Médicament (CIRM)

De Bleye, Charlotte ; Université de Liège - ULiège > Département de pharmacie

Sacré, Pierre‐Yves; Research Support Unit in Chemometrics Department of Pharmacy University of Liege (ULiege), CIRM Liege Belgium

Thelen, Nicolas ; Université de Liège - ULiège > Département des sciences de la vie > Biologie cellulaire

Hubert, Philippe ; Université de Liège - ULiège > Département de pharmacie > Chimie analytique

Ziemons, Eric ^✱; Université de Liège - ULiège > Unités de recherche interfacultaires > Centre Interdisciplinaire de Recherche sur le Médicament (CIRM)

Hubert, Cédric ^✱; Université de Liège - ULiège > Département de pharmacie > Chimie analytique

^✱ These authors have contributed equally to this work.

Language :

English

Title :

Determination of Size, Size Distribution, and Concentration of Nanoparticles Using ICP‐MS in the Context of SERS Substrates

Publication date :

18 November 2024

Journal title :

Journal of Raman Spectroscopy

ISSN :

0377-0486

eISSN :

1097-4555

Publisher :

Wiley

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 19 November 2024

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