Chemical interactions between Bi2Sr3CaO7(Bi-2310) and Bi2Sr2Ca0.8Dy0.2Cu2O8 (Bi-2212(Dy))

Rahier, Sébastien; Lafort, Adeline; Henrist, Catherine; Ausloos, Marcel; Cloots, Rudi; Vertruyen, Bénédicte

doi:10.1088/0953-2048/19/1/007

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Chemical interactions between Bi2Sr3CaO7(Bi-2310) and Bi2Sr2Ca0.8Dy0.2Cu2O8 (Bi-2212(Dy))

Rahier, Sébastien; Lafort, Adeline; Henrist, Catherine et al.

2006 • In Superconductor Science and Technology, 19 (1), p. 39-43

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/12004

DOI
10.1088/0953-2048/19/1/007

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Keywords :

BSCCO; superconductors

Abstract :

[en] The chemical interactions between Bi2Sr3CaO7 (Bi-2310) and Bi2Sr2Ca0.8Dy0.2Cu2O8 (Bi-2212(Dy)) at 965 degrees C were investigated by means of: (i) an interdiffusion couple and (ii) layers deposited by dip coating on oxidized nickel Substrates. The samples were characterized by optical and electron microscopies, energy-dispersive x-ray (EDX) analysis and x-ray diffraction. It turns out that at the peritectic temperature Of Bi-2212(Dy), the Bi-2310 phase reacts with the liquid phase resulting from the peritectic decomposition of the Bi-2212(Dy) phase. Dissolution of Bi-2310 leads to an enrichment in Sr and an impoverishment in Cu of the liquid phase, resulting in a shift of the composition of the insoluble phase towards the Ca-rich end of the (Ca, Sr)O Solid Solution.

Disciplines :

Physics

Author, co-author :

Rahier, Sébastien ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie Inorganique Structurale

Lafort, Adeline ; Université de Liège - ULiège > Chimie inorganique structurale

Henrist, Catherine ; Université de Liège - ULiège > Chimie inorganique structurale

Ausloos, Marcel ; Université de Liège - ULiège > Département de physique > Physique statistique appliquée et des matériaux

Cloots, Rudi ; Université de Liège - ULiège > Chimie inorganique structurale

Vertruyen, Bénédicte ; Université de Liège - ULiège > Chimie inorganique structurale

Language :

English

Title :

Chemical interactions between Bi2Sr3CaO7(Bi-2310) and Bi2Sr2Ca0.8Dy0.2Cu2O8 (Bi-2212(Dy))

Publication date :

January 2006

Journal title :

Superconductor Science and Technology

ISSN :

0953-2048

eISSN :

1361-6668

Publisher :

Iop Publishing Ltd, Bristol, United Kingdom

Volume :

Issue :

Pages :

39-43

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique

Commentary :

This is an author-created, un-copyedited version of an article accepted for publication in Superconductor Science and Technology. IOP Publishing Ltd is not responsible for any errors or omissions in this version of the manuscript or any version derived from it. The definitive publisher authenticated version is available online at doi:10.1088/0953-2048/19/1/007

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since 29 April 2009

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