Use of ionic liquids for biocatalytic synthesis of sugar derivatives

Galonde, Nadine; Nott, Katherine; Debuigne, Antoine; Deleu, Magali; Jérôme, Christine; Paquot, Michel; Wathelet, Jean-Paul

doi:10.1002/jctb.3745

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Use of ionic liquids for biocatalytic synthesis of sugar derivatives

Galonde, Nadine; Nott, Katherine; Debuigne, Antoine et al.

2012 • In Journal of Chemical Technology and Biotechnology, 87 (4), p. 451-471

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https://hdl.handle.net/2268/117466

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10.1002/jctb.3745

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Keywords :

enzymatic reaction; sugar; ionic liquid; review; green technology

Abstract :

[en] Sugar-based compounds are widely used in pharmaceuticals, cosmetics, detergents and food. They are mainly produced by chemical methods, but the use of enzymes as ‘a greener alternative’ to organic synthesis has been investigated for more than 20 years. Due to the low polar substrate solubility in organic solvents compatible with enzymes, research has focused on the application of substitutes for biocatalysis, especially ionic liquids (ILs). After introducing the main properties of ILs and especially their ability to solubilize sugars, this review focuses on one of their applications, the biocatalytic synthesis of carbohydrate derivatives. In this context, they can be used in pure IL systems, in IL/IL systems or in IL/organic solvent systems. Finally, this review provides an update on the environmental fate of ILs. Their exploitation in ‘green’ processes is still limited due to their low degradability but research is currently under way to design new more ‘eco-friendly’ ILs.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Galonde, Nadine ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Department of General and Organic Chemistry

Nott, Katherine ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Department of General and Organic Chemistry and Department of Industrial and Biological Chemistry

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Deleu, Magali ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Department of Industrial and Biological Chemistry

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Paquot, Michel ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Department of Industrial and Biological Chemistry

Wathelet, Jean-Paul ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Department of General and Organic Chemistry

Language :

English

Title :

Use of ionic liquids for biocatalytic synthesis of sugar derivatives

Publication date :

April 2012

Journal title :

Journal of Chemical Technology and Biotechnology

ISSN :

0268-2575

Publisher :

John Wiley & Sons Ltd., Chichester, United Kingdom

Volume :

Issue :

Pages :

451-471

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://onlinelibrary.wiley.com/doi/10.1002/jctb.3745/pdf

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
The French Community of Belgium in the frame of the SUPERZYM program

Available on ORBi :

since 24 April 2012

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