Sodium nitrite and ascorbic acid: a metal-free combination that controls the free-radical polymerization of tert-butyl methacrylate in water

Detrembleur, Christophe; Mouithys-Mickalad, Ange; Teyssié, Philippe; Jérôme, Robert

doi:10.1515/epoly.2002.2.1.53

Article (Scientific journals)

Sodium nitrite and ascorbic acid: a metal-free combination that controls the free-radical polymerization of tert-butyl methacrylate in water

Detrembleur, Christophe; Mouithys-Mickalad, Ange; Teyssié, Philippe et al.

2002 • In e-Polymers, (4), p. 1-16

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/5559

DOI
10.1515/epoly.2002.2.1.53

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Keywords :

radical polymerization; nitroxide-mediated polymerization (NMP)

Abstract :

[en] A mixture of sodium nitrite and ascorbic acid is able to control the radical polymerization of tert-butyl methacrylate (tBMA) in water at 80°C. Indeed, sodium nitrite is reduced by the ascorbic acid, and the nitric oxide (NO) which is formed in situ is nothing but a promoter of nitroxyl radicals. The radical polymerization of tBMA is thus basically controlled by a nitroxide-mediated process.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Mouithys-Mickalad, Ange ; Université de Liège - ULiège > Center for Oxygen R&D (CORD)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Sodium nitrite and ascorbic acid: a metal-free combination that controls the free-radical polymerization of tert-butyl methacrylate in water

Publication date :

18 February 2002

Journal title :

e-Polymers

eISSN :

1618-7229

Publisher :

European Polymer Federation, Strasbourg, France

Issue :

Pages :

1-16

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.e-polymers.org/journal/abstract.cfm?abstract_Id=79#

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

Available on ORBi :

since 03 February 2009

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