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Article (Scientific journals)
Sodium nitrite and ascorbic acid: a metal-free combination that controls the free-radical polymerization of tert-butyl methacrylate in water
Detrembleur, Christophe; Mouithys-Mickalad, Ange; Teyssié, Philippe et al.
2002In e-Polymers, (4), p. 1-16
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Keywords :
radical polymerization; nitroxide-mediated polymerization (NMP)
Abstract :
[en] A mixture of sodium nitrite and ascorbic acid is able to control the radical polymerization of tert-butyl methacrylate (tBMA) in water at 80°C. Indeed, sodium nitrite is reduced by the ascorbic acid, and the nitric oxide (NO) which is formed in situ is nothing but a promoter of nitroxyl radicals. The radical polymerization of tBMA is thus basically controlled by a nitroxide-mediated process.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Mouithys-Mickalad, Ange ;  Université de Liège - ULiège > Center for Oxygen R&D (CORD)
Teyssié, Philippe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Sodium nitrite and ascorbic acid: a metal-free combination that controls the free-radical polymerization of tert-butyl methacrylate in water
Publication date :
18 February 2002
Journal title :
e-Polymers
eISSN :
1618-7229
Publisher :
European Polymer Federation, Strasbourg, France
Issue :
4
Pages :
1-16
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
Available on ORBi :
since 03 February 2009

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