Preparation of well-defined PVOH/C60 nanohybrids by cobalt-mediated radical polymerization of vinyl acetate

Detrembleur, Christophe; Stoilova, Olya; Bryaskova, Rayna; Debuigne, Antoine; Mouithys-Mickalad, Ange; Jérôme, Robert

doi:10.1002/marc.200500871

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Article (Scientific journals)

Preparation of well-defined PVOH/C60 nanohybrids by cobalt-mediated radical polymerization of vinyl acetate

Detrembleur, Christophe; Stoilova, Olya; Bryaskova, Rayna et al.

2006 • In Macromolecular Rapid Communications, 27 (7), p. 498-504

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4881

DOI
10.1002/marc.200500871

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP); carbon fullerene; biomaterial; nanomedicine

Abstract :

[en] Poly(vinyl acetate) chains end-capped by a Co(acac)(2) complex [PVAc-Co(acac)(2)] were prepared by bulk cobalt-mediated radical polymerization (CMRP) of vinyl acetate and used for grafting fullerene (C60) with four PVAc arms at low temperature (30 degrees C). A photoactive water-soluble poly(vinyl alcohol)/C60 nanohybrid was then prepared by hydrolysis of the PVAc arms of the nanohybrid. Because of photoactivity and very low cytotoxicity, this type of water-soluble nanohybrid is very promising for the photodynamic cancer therapy.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Stoilova, Olya; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Bryaskova, Rayna ; Bulgarian Academy of Sciences, Sofia, Bulgaria > Institute of Polymers > Laboratory of Bioactive Polymers

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Mouithys-Mickalad, Ange ; Université de Liège - ULiège > Centre of Oxygen R&D

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Preparation of well-defined PVOH/C60 nanohybrids by cobalt-mediated radical polymerization of vinyl acetate

Publication date :

03 April 2006

Journal title :

Macromolecular Rapid Communications

ISSN :

1022-1336

eISSN :

1521-3927

Publisher :

Wiley-V C H Verlag Gmbh, Weinheim, Germany

Volume :

Issue :

Pages :

498-504

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/112478100/PDFSTART

Funders :

Solvay sa
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Commentary :

The authors acknowledge Macromolecular Rapid Communications (Wiley) for allowing them to archive this paper.

Available on ORBi :

since 27 January 2009

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