“One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres
green technology; supercritical carbon dioxide; click chemistry; copper-mediated Huisgen's cycloaddition; radical polymerization; atom transfer radical polymerization (ATRP)
Abstract :
[en] Functional polymers were successfully prepared in scCO2 by combining alkyne-azide 1,3-dipolar Huisgen’s cycloaddition and dispersion ATRP in a “one pot” process using new perfluorinated polymeric amino-based ligands that had a dual role, i.e. the complexation of the copper catalyst and the stabilization of growing particles.
Research Center/Unit :
Center for Education and Researchon Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Calberg, Cédric ; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
“One-pot” dispersion ATRP and alkyne-azide Huisgen’s 1,3-dipolar cycloaddition in supercritical carbon dioxide: towards the formation of functional microspheres
Publication date :
June 2010
Journal title :
Journal of Supercritical Fluids
ISSN :
0896-8446
Publisher :
Elsevier Science, Amsterdam, Netherlands
Volume :
53
Issue :
1-3
Pages :
151-155
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique The “Région Wallonne” and the FEDER in the frame of the POLYTISS program
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