[en] Since 1984, about 15 000 high quality infrared solar spectra have been recorded with state-of-the-art grating and Fourier transform spectrometers at the International Scientific Station of the Jungfraujoch, Switzerland. Nonlinear least squares spectral curve fitting of selected microwindows containing isolated and well characterized lines of 20 telluric gases have allowed to retrieve their total vertical column abundances above the station, leading to observational data bases essential to derive long- and short-term changes experienced by these species during the last 12 years. In this paper, we focus on atmospheric gases of particular interest within the context of the EUROTRACTOR (Tropospheric Ozone Research) project; secular evolution as well as seasonal cycles of the minor constituents CH4, CO and of the trace gases C2H6, OCS, C2H2, HCN and H2CO are reported and discussed. The long-lived N2O is included as a tracer of the dynamic activity of the atmosphere.
Mahieu, Emmanuel ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Zander, Rodolphe ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Delbouille, Luc
Demoulin, Philippe ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Roland, Ginette
Servais, Christian ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Language :
English
Title :
Observed trends in total vertical column abundances of atmospheric gases from IR solar spectra recorded at the Jungfraujoch
Arlander, D.W., Brüning, D., Schmidt, U., Ehhalt, D.H., The tropospheric distribution of formaldehyde during TROPOZ II (1995) J. Atmos. Chem., 22, pp. 251-268
Barbe, A., Marché, P., Secroun, C., Jouve, P., Measurements of tropospheric and stratospheric H2CO by an infrared high resolution technique (1979) Geophys. Res. Lett., 6, pp. 463-465
Cicerone, R.J., Zellner, R., The atmospheric chemistry of hydrogen cyanide (HCN) (1983) J. Geophys. Res., 88, pp. 10689-10696
Coffey, M.T., Mankin, W.G., Cicerone, R.J., Spectroscopic detection of stratospheric hydrogen cyanide (1981) Science, 214, pp. 333-334
Crutzen, P.J., The possible importance of CSO for the sulfate layer of the stratosphere (1976) Geophys. Res. Lett., 3, pp. 73-76
Delbouille, L., Roland, G., Photometric atlas of the solar spectrum from λ 7498 to λ 12016 (1963) Mém. Soc. Roy. Sci. Liège, Vol. Hors Série, 4
Delbouille, L., Roland, G., High-resolution solar and atmospheric spectroscopy from the Jungfraujoch high-altitude station (1995) Optic. Engin., 34, pp. 2736-2739
Serves, C., Gas phase formaldehyde and peroxide measurements in the Arctic atmosphere (1994) J. Geophys. Res., 99, pp. 25391-25398
Dlugokencky, E.J., Masarie, K.A., Lang, P.M., Tans, P.P., Steele, L.P., Nisbet, E.G., A dramatic decrease in the growth rate of atmospheric methane in the Northern Hemisphere during 1992 (1994) Geophys. Res. Lett., 22, pp. 45-48
Ehhalt, D.H., Rudolph, J., Meixner, F., Schmidt, U., Measurements of selected C2-C5 hydrocarbons in the background troposphere: Vertical and latitudinal variations (1985) J. Atmos. Chem., 3, pp. 29-52
Ehhalt, D.H., Schmidt, U., Zander, R., Demoulin, P., Rinsland, C.P., Seasonal cycle and secular trend of the total and tropospheric column abundance of ethane above the Jungfraujoch (1991) J. Geophys. Res., 96, pp. 4985-4994
And, G.C., Brasseur, G., Impact of heterogeneous chemistry on model prediction of ozone change (1992) J. Geophys. Res., 97, pp. 18015-18033
IPCC Report on Climate Change (1994) Radiative Forcing of Climate Change and an Evaluation of the IPCC IS92 Emission Scenarios, 1995, pp. 1-339. , J. T. Houghton et al., (eds), Cambridge University Press
Johnson, J.E., The lifetime of carbonyl sulfide in the troposphere (1981) Geophys. Res. Lett., 8, pp. 938-940
Khalil, M.A.K., Rasmussen, R.A., Global sources, lifetimes and mass balances of carbonyl sulfide (OCS) and carbonyl disulfide (CS2) in the Earth's atmosphere (1984) Atmos. Environ., 18, pp. 1805-1813
Khalil, M.A.K., Rasmussen, R.A., Decreasing trend of methane: Unpredictability of future concentrations (1993) Chemosphere, 26, pp. 803-814
Khalil, M.A.K., Rasmussen, R.A., Global decrease in carbon monoxide concentration (1994) Nature, 370, p. 639
Lelieveld, J., Crutzen, P.J., Bruehl, C., Climate effects of atmospheric methane (1993) Chemosphere, 26, pp. 739-768
Leuenberg, M., Siegenthaler, U., Ice-age atmospheric concentration of nitrous oxide from an Antarctic ice core (1992) Nature, 360, pp. 449-451
Mahieu, E., Rinsland, C.P., Zander, R., Demoulin, P., Delbouille, L., Roland, G., Vertical column abundances of HCN deduced from ground-based infrared solar spectra: Long-term trend and variability (1995) J. Atmos. Chem., 20, pp. 299-310
Migeotte, M., The fundamental band of carbon monoxide at 4.7μ in the solar spectrum (1949) Phys. Rev., 75, pp. 1108-1109
Migeotte, M., Neven, L., Swenson, J., The solar spectrum from 2.8 to 23.7 microns, I. Photometric atlas (1956) Mém. Soc. Roy. Sci. Liège, Vol. Hors Série, 1
Novelli, P.C., Masarie, K.A., Tans, P.P., Lang, P.M., Recent changes in atmospheric carbon monoxide (1994) Science, 263, pp. 1587-1590
Prather, M.J., Lifetimes and eigenstates in atmospheric chemistry (1994) Geophys. Res. Lett., 21, pp. 801-804
Rinsland, C.P., Smith, M.A.H., Rinsland, P.L., Goldman, A., Brault, J.W., Stokes, G.M., Ground-based infrared spectroscopic measurements of atmospheric hydrogen cyanide (1982) J. Geophys. Res., 87, pp. 1119-11125
Rinsland, C.P., Zander, R., Demoulin, P., Ground-based infrared measurements of HNO3 total column abundances: Long-term trend and variability (1991) J. Geophys. Res., 96, pp. 9379-9389
Rinsland, C.P., Levine, J.S., Goldman, A., Sze, N.D., Ko, M.K.W., Johnson, D.W., Infrared measurements of HE and HCl total column abundances above Kitt Peak, 1977-1990: Seasonal cycles, long-term increases, and comparisons with model calculations (1991) J. Geophys. Res., 96, pp. 15523-15540
Rinsland, C.P., Zander, R., Mahieu, E., Demoulin, P., Goldman, A., Ehhalt, D.H., Rudolph, J., Ground-based infrared measurements of carbonyl sulfide total column abundances: Long-term trends and variability (1992) J. Geophys. Res., 97, pp. 5995-6002
Rinsland, C.P., Zander, R., Demoulin, Ph., Mahieu, E., ClONO2 total vertical column abundances above the Jungfraujoch Station, 1986-1994: Long-term trend and winter-spring enhancements (1996) J. Geophys. Res., 101, pp. 3891-3899
Rodriguez, J.M., Ko, M.K.W., Sze, N.D., Role of heterogeneous conversion of N2O5 on sulphate aerosols in global ozone losses (1991) Nature, 352, pp. 134-137
Rothman, L.S., The HITRAN molecular database: Editions of 1991 and 1992 (1992) J. Quant. Spectrosc. Radiat. Transfer, 48, pp. 469-508
Rudolph, J., Ehhalt, D.H., Measurements of C2-C5 hydrocarbons over the North Atlantic (1981) J. Geophys. Res., 86, pp. 11959-11964
WMO Report No. 16 (1986) Atmospheric Ozone 1985: Assessment of Our Understanding of the Processes Controlling Its Present Distribution and Change, , World Meteorological Organisation, P.O. Box 2300, Geneva 2, CH 1211, Switzerland
Zander, R., Demoulin, Ph., Ehhalt, D.H., Schmidt, U., Rinsland, C.P., Secular increase of the total vertical column abundance of carbon monoxide above Central Europe since 1950 (1989) J. Geophys. Res., 94, pp. 11021-11028
Zander, R., Demoulin, Ph., Ehhalt, D.H., Schmidt, U., Secular increase of the vertical column abundance of methane derived from IR solar spectra recorded at the Jungfraujoch Station (1989) J. Geophys. Res., 94, pp. 11029-11039
Zander, R., Rinsland, C.P., Ehhalt, D.H., Rudolph, J., Demoulin, Ph., Vertical column abundances and seasonal cycle of acetylene, C2H2, above the Jungfraujoch Station, derived from IR solar observations (1991) J. Atmos. Chem., 13, pp. 359-372
Zander, R., Mahieu, E., Demoulin, Ph., Monitoring of stratospheric changes at the Jungfraujoch Station by high-resolution infrared solar observations in support of the network for detection of stratospheric changes (NDSC) (1993) NATO ASI Series, I.8, pp. 347-363. , M.-L. Chanin (ed.), Springer-Verlag, Berlin, Heidelberg
Zander, R., Ehhalt, D.H., Rinsland, C.P., Schmidt, U., Mahieu, E., Rudolph, J., Demoulin, P., Sauval, A.J., Secular trend and seasonal variability of N2O above the Jungfraujoch station determined from IR solar spectra (1994) J. Geophys. Res., 99, pp. 16745-16756
Zander, R., Demoulin, Ph., Mahieu, E., Monitoring of the atmospheric burdens of CH4, N2O, CO, CHClF2 and CF2Cl2 above Central Europe during the last decade (1994) Environ. Monitoring Assess., 31, pp. 203-209