Ultra-high performance liquid chromatographic method for the determination of polycyclic aromatic hydrocarbons in a passive environmental sampler

Environmental contamination; Passive sampler; Polycyclic aromatic hydrocarbon (PAH); Ultra-high performance liquid chromatography (UHPLC); Acenaphthene; Chromatographic methods; Elution temperature; Fluorenes; Limits of detection; Limits of quantification; Passive samplers; Performance criterion; Polycyclic aromatic hydrocarbons(PAHs); Regression coefficient; Solid-phase extraction; Ultra-high performance; Chromatographic analysis; Chromatography; High performance liquid chromatography; Polyethylene terephthalates; Synthetic fibers; Polycyclic aromatic hydrocarbons; Chromatography, High Pressure Liquid; Limit of Detection; Polycyclic Hydrocarbons, Aromatic; Solid Phase Extraction; Temperature

Abstract :

[en] Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous compounds released in the environment by different sources. The aim of the present work was to validate a solid-phase extraction (SPE) and a rapid ultra-high performance liquid chromatographic (UHPLC) method for the analysis of PAHs in a passive environmental sampler, namely a Dacron® (the commercial name of a synthetic fiber based on polyethylene terephthalate) textile. The elution temperature was optimized to improve the resolution of early-eluted compounds, namely acenaphthene (Ac) and fluorene (F). The UHPLC method lasts about 10 min and showed good linearity for all the 16 PAHs considered, with regression coefficients over 0.99. Recoveries, limits of detection (LODs), and limits of quantification (LOQs) of the SPE method were well within the performance criteria fixed by the Regulation n. 836/2011, namely 0.3 and 0.9 μg/kg, respectively. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Disciplines :

Chemistry
Environmental sciences & ecology

Author, co-author :

Purcaro, Giorgia ; Université de Liège - ULiège > Agronomie, Bio-ingénierie et Chimie (AgroBioChem) > Chimie des agro-biosystèmes

Moret, S.; Dipartimento di Scienze Degli Alimenti, Università di Udine, via Sondrio 2, Udine 33100, Italy

Bučar-Miklavčič, M.; LABS LCC, Institute for Ecology, Olive Oil and Control, Izola, Slovenia

Conte, L. S.; Dipartimento di Scienze Degli Alimenti, Università di Udine, via Sondrio 2, Udine 33100, Italy

Language :

English

Title :

Ultra-high performance liquid chromatographic method for the determination of polycyclic aromatic hydrocarbons in a passive environmental sampler

Publication date :

2012

Journal title :

Journal of Separation Science

ISSN :

1615-9306

eISSN :

1615-9314

Publisher :

Wiley, Weinheim, Germany

Volume :

Issue :

Pages :

922-928

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 11 January 2019

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