Article (Scientific journals)
Ultra-high performance liquid chromatographic method for the determination of polycyclic aromatic hydrocarbons in a passive environmental sampler
Purcaro, Giorgia; Moret, S.; Bučar-Miklavčič, M. et al.
2012In Journal of Separation Science, 35 (8), p. 922-928
Peer Reviewed verified by ORBi
 

Files


Full Text
27-JSS 2012 35 922-928-UHPLC.pdf
Publisher postprint (726.43 kB)
Request a copy

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
Environmental contamination; Passive sampler; Polycyclic aromatic hydrocarbon (PAH); Ultra-high performance liquid chromatography (UHPLC); Acenaphthene; Chromatographic methods; Elution temperature; Fluorenes; Limits of detection; Limits of quantification; Passive samplers; Performance criterion; Polycyclic aromatic hydrocarbons(PAHs); Regression coefficient; Solid-phase extraction; Ultra-high performance; Chromatographic analysis; Chromatography; High performance liquid chromatography; Polyethylene terephthalates; Synthetic fibers; Polycyclic aromatic hydrocarbons; Chromatography, High Pressure Liquid; Limit of Detection; Polycyclic Hydrocarbons, Aromatic; Solid Phase Extraction; Temperature
Abstract :
[en] Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous compounds released in the environment by different sources. The aim of the present work was to validate a solid-phase extraction (SPE) and a rapid ultra-high performance liquid chromatographic (UHPLC) method for the analysis of PAHs in a passive environmental sampler, namely a Dacron® (the commercial name of a synthetic fiber based on polyethylene terephthalate) textile. The elution temperature was optimized to improve the resolution of early-eluted compounds, namely acenaphthene (Ac) and fluorene (F). The UHPLC method lasts about 10 min and showed good linearity for all the 16 PAHs considered, with regression coefficients over 0.99. Recoveries, limits of detection (LODs), and limits of quantification (LOQs) of the SPE method were well within the performance criteria fixed by the Regulation n. 836/2011, namely 0.3 and 0.9 μg/kg, respectively. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Disciplines :
Chemistry
Environmental sciences & ecology
Author, co-author :
Purcaro, Giorgia  ;  Université de Liège - ULiège > Agronomie, Bio-ingénierie et Chimie (AgroBioChem) > Chimie des agro-biosystèmes
Moret, S.;  Dipartimento di Scienze Degli Alimenti, Università di Udine, via Sondrio 2, Udine 33100, Italy
Bučar-Miklavčič, M.;  LABS LCC, Institute for Ecology, Olive Oil and Control, Izola, Slovenia
Conte, L. S.;  Dipartimento di Scienze Degli Alimenti, Università di Udine, via Sondrio 2, Udine 33100, Italy
Language :
English
Title :
Ultra-high performance liquid chromatographic method for the determination of polycyclic aromatic hydrocarbons in a passive environmental sampler
Publication date :
2012
Journal title :
Journal of Separation Science
ISSN :
1615-9306
eISSN :
1615-9314
Publisher :
Wiley, Weinheim, Germany
Volume :
35
Issue :
8
Pages :
922-928
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 11 January 2019

Statistics


Number of views
37 (3 by ULiège)
Number of downloads
1 (1 by ULiège)

Scopus citations®
 
23
Scopus citations®
without self-citations
20
OpenCitations
 
22

Bibliography


Similar publications



Contact ORBi