Modulators for comprehensive two-dimensional gas chromatography

Comprehensive two-dimensional gas chromatography; Cryogenic modulator; Flow modulator; Heart-cutting; In-line valve system; Longitudinally-modulated cryogenic system; Out-line valve system; Pneumatic modulator; Re-injection; Thermal modulator; In-line; Thermal modulators; Valve systems; Cryogenics; Modulators; Pneumatics; Smoke detectors; Two dimensional; Gas chromatography

Abstract :

[en] The analytical benefits of comprehensive two-dimensional gas chromatography (GC × GC) methods have been exploited and emphasized in the past two decades. The unexpectedly complex nature of many real-world samples amenable to GC analysis has been elucidated through the enhanced resolving power of GC × GC. Simple but fundamental devices, called modulators, enable continuous heart-cutting and re-injection, without which GC × GC analysis cannot be achieved. The present review focuses on the history (1991-2010), and present trends and future prospects for GC × GC modulation. We provide detailed descriptions and set out the advantages and the disadvantages of the most significant thermal and pneumatic modulators. © 2011 Elsevier Ltd.

Disciplines :

Chemistry

Author, co-author :

Tranchida, P. Q.; Dipartimento Farmaco-chimico, Facoltà di Farmacia, Università di Messina, Viale Annunziata, 98168 - Messina, Italy

Purcaro, Giorgia ; Université de Liège - ULiège > Agronomie, Bio-ingénierie et Chimie (AgroBioChem) > Chimie des agro-biosystèmes

Dugo, P.; Dipartimento Farmaco-chimico, Facoltà di Farmacia, Università di Messina, Viale Annunziata, 98168 - Messina, Italy

Mondello, L.; Dipartimento Farmaco-chimico, Facoltà di Farmacia, Università di Messina, Viale Annunziata, 98168 - Messina, Italy

Language :

English

Title :

Modulators for comprehensive two-dimensional gas chromatography

Publication date :

2011

Journal title :

TrAC: Trends in Analytical Chemistry

ISSN :

0165-9936

eISSN :

1879-3142

Publisher :

Elsevier, Amsterdam, Netherlands

Volume :

Issue :

Pages :

1437-1461

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 11 January 2019

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