Article (Scientific journals)
Intramolecular vibrational relaxation seen as expansion in phase space. III. The long-time limit
Pavlov-Verevkin, V. B.; Lorquet, Jean-Claude
1997In Journal of Chemical Physics, 107 (17), p. 6677-6680
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Keywords :
Intramolecular vibrational relaxation; phase space sampling; Regular/chaotic dynamics
Abstract :
[en] Asymptotic formulas that describe the behavior of the function N(T) measuring the phase space volume sampled by a nonstationary wave packet during its time evolution are derived. It is shown that, in the long-time limit, N(T)∼T-1 when the dynamics is regular, whereas N(T)∼T-2 In T for the chaotic case. © 1997 American Institute of Physics.
Disciplines :
Physics
Chemistry
Author, co-author :
Pavlov-Verevkin, V. B.;  Département de Chimie, Université de Liège, B-4000 Liège 1, Belgium, Chemistry Department, Moscow State University, Moscow 119899, Russian Federation
Lorquet, Jean-Claude ;  Université de Liège > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Intramolecular vibrational relaxation seen as expansion in phase space. III. The long-time limit
Publication date :
1997
Journal title :
Journal of Chemical Physics
ISSN :
0021-9606
eISSN :
1089-7690
Publisher :
American Institute of Physics, United States - New York
Volume :
107
Issue :
17
Pages :
6677-6680
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 10 September 2015

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