Mesoporous Lithium Vanadium Oxide as Thin Film Electrode for Lithium-Ion Batteries: Comparison between Direct Synthesis of LiV2O5 and Electrochemical Lithium Intercalation in V2O5
[en] Research in the field of lithium-ion batteries favours electrode materials with high surface area. In this context, this paper is dedicated to mesoporous thin films (MTFs) and compares the electrochemical performance of g-LiV2O5 MTFs with post-synthesis electrochemical lithium intercalation in a-V2O5 MTFs. Formation of vanadium oxide MTFs by soft-chemistry is notoriously difficult. However, it is shown that wormlike vanadium oxide (V–O) and lithium vanadium oxide (Li–V–O) MTFs can be obtained on silicon substrates by a direct sol–gel soft-templating route (evaporation-induced micelle assembly) using a polystyrene-block-poly(ethylene oxide) (PS-b-PEO) structuring agent. Heat treatment for 1 minute at 400 C (Li–V–O system) or 30 minutes at 350 C (V–O system) leads to the crystallization of g-LiV2O5 or a-V2O5, respectively. These calcination conditions ensure the degradation of the structuring agent while preventing the collapse of the mesostructure, yielding MTFs with pore size diameter in the 30–35 nm range. Using the same set of synthesis conditions, films can be deposited on conductive glass substrates for electrochemical investigation: the a-V2O5 films display better specific capacities, while the cyclability is good for both compositions, even at a current density as high as 30 C-rate.
Disciplines :
Chemistry
Author, co-author :
Caes, Sébastien ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Arrebola, Jose Carlos
Krins, Natacha ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Eloy, Pierre; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences (IMCN), Division “MOlecules, Solids and reactiviTy” (MOST)
Gaigneaux, Eric; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences (IMCN), Division “MOlecules, Solids and reactiviTy” (MOST)
Henrist, Catherine ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Cloots, Rudi ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Vertruyen, Bénédicte ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie inorganique structurale
Language :
English
Title :
Mesoporous Lithium Vanadium Oxide as Thin Film Electrode for Lithium-Ion Batteries: Comparison between Direct Synthesis of LiV2O5 and Electrochemical Lithium Intercalation in V2O5
Publication date :
2014
Journal title :
Journal of Materials Chemistry A
ISSN :
2050-7488
eISSN :
2050-7496
Publisher :
Royal Society of Chemistry, United Kingdom
Volume :
2
Pages :
5809-5815
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
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