Online monitoring of heterogeneous polymerizations in supercritical carbon dioxide by Raman spectroscopy

[en] A novel setup is described to monitor the kinetics of homogeneous and heterogeneous reactions online using Raman spectroscopy under high pressure. The arrangement is based on a high-pressure reactor equipped with a sapphire window in combination with a mobile probe that allows the collection of the back-scattered Raman signal at 360°.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Gilbert, Bernard ; Université de Liège - ULiège > Department of Chemistry > Analytic Chemistry and Electrochemistry

Malherbe, Cédric ; Université de Liège - ULiège > Department of Chemistry > Analytic Chemistry and Electrochemistry

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Online monitoring of heterogeneous polymerizations in supercritical carbon dioxide by Raman spectroscopy

Publication date :

06 August 2012

Journal title :

Chemphyschem: A European Journal of Chemical Physics and Physical Chemistry

ISSN :

1439-4235

eISSN :

1439-7641

Publisher :

Wiley-VCH Verlag Gmbh, Weinheim, Germany

Volume :

Issue :

Pages :

2666-2670

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://onlinelibrary.wiley.com/doi/10.1002/cphc.201200373/abstract

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
The "Région Wallonne" and the "FEDER" in the frame of the SINOPLISS project

Available on ORBi :

since 14 June 2012

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