Self-aggregation of poly(methyl methacrylate)-block-poly(sulfonated glycidyl methacrylate) copolymers

[en] The self-aggregation of a series of amphiphilic poly(methyl methacrylate)-block-poly(sulfonated glycidyl methacrylate) (PMMA-b-PSGMA) copolymers in water has been studied by dynamic light scattering (DLS), size exclusion chromatography (SEC) and surface tension measurements. All the copolymers considered in this study form micelles which, however, aggregate into larger structures as shown by DLS and SEC. These larger structures dissociate into smaller ones upon increasing the temperature. The extent of this dissociation process is strongly dependent on the copolymer composition. It is large as the content of the hydrophilic block is high.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Gohy, Jean-François; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Antoun, Sayed; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Self-aggregation of poly(methyl methacrylate)-block-poly(sulfonated glycidyl methacrylate) copolymers

Publication date :

October 2001

Journal title :

Polymer

ISSN :

0032-3861

eISSN :

1873-2291

Publisher :

Elsevier Sci Ltd, Oxford, United Kingdom

Volume :

Issue :

Pages :

8637-8645

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TXW-43MK1FY-1G-F&_cdi=5601&_user=532038&_orig=browse&_coverDate=10%2F31%2F2001&_sk=999579978&view=c&wchp=dGLbVzW-zSkzS&md5=8bac09923c9e596c471694af6d1a3d4a&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/30466/description#description

Name of the research project :

SUPERNET program

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
ESF - European Science Foundation [FR]

Commentary :

The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.

Available on ORBi :

since 25 March 2009

Statistics

Number of views

87 (4 by ULiège)

Number of downloads

379 (1 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

Bibliography

Yokoyama M., Inoue S., Kataoka K., Yui N., Sakurai Y. Makromol Chem Rapid Commun 1987, 8:431.
Yokoyama M., Okano T., Sakurai Y., Ekimoto H., Shibazaki C., Kataoka K. Cancer Res 1991, 51:3229.
Creutz S., Jérôme R., Kaptijn G.M.P., Van der Wert A.W., Akkerman J.M. J Coat Techol 1998, 70(883):41.
Winzor C.L., Mrazek Z., Winnik M.A., Croucher R.D., Riess D. Eur Polym J 1994, 30:121.
Tuzar Z., Krachtovil P. Surface and colloid science, Matijevic E, editor. New York: Plenum Press; 1993.
Chu B. Langmuir 1995, 11:414.
Alexandridis P. Curr Opin Colloid Interf Sci 1996, 1:490.
Moffit M., Khougaz K., Eisenberg A. Acc Chem Res 1996, 29:95.
Bedells A.D., Arafeh R.M., Yang Z., Attwood D., Collet J.H., Price C., Booth C. J Chem Soc, Faraday Trans 1993, 89:1235.
Luo Y.Z., Nicholas C.V., Attwood D., Collet J.H., Price C., Booth C., Chu B., Zhou Z.K. J Chem Soc, Faraday Trans 1993, 89:539.
Nicholas C.V., Luo Y.Z., Deng N.J., Attwood D., Collet J.H., Price C., Booth C. Polymer 1993, 34:138.
Alexandridis P., Athanassiou V., Fukuda S., Hatton T.A. Langmuir 1994, 10:2604.
Yang L., Bedells A.D., Attwood D., Booth C. J Chem Soc, Faraday Trans 1992, 88:1447.
Deng Y., Ding J., Stubbersfield R.B., Heatley F., Attwood D., Price C., Booth C. Polymer 1992, 33:1963.
Brown W., Schillen K., Almgren M., Hvidt S., Bahadur P. J Phys Chem 1991, 95:1850.
Malmsten M., Lindman B. Macromolecules 1992, 25:5440.
Almgren M., Bahadur P., Jansson M., Li P., Brown W., Bahadur A. J Colloid Interf Sci 1992, 151:157.
Linse P. Macromolecules 1993, 26:4437.
Mortensen K., Brown W. Macromolecules 1993, 26:4128.
Almgren M., Brown W., Hvidt S. Colloid Polym Sci 1995, 273:2.
Wilhem M., Zhao C.L., Wang Y., Xu R., Winnik M.A., Mura J.L., Riess G., Croucher M.D. Macromolecules 1991, 24:1033.
Hruska Z., Piton M., Yekta A., Duhamel J., Winnik M.A., Riess G., Croucher M.D. Macromolecules 1993, 26:1825.
Selb J., Gallot Y. Makromol Chem 1980, 181:809.
Selb J., Gallot Y. Makromol Chem 1980, 181:2605.
Selb J., Gallot Y. Makromol Chem 1981, 182:1491.
Selb J., Gallot Y. Makromol Chem 1981, 182:2523.
Biggs S., Vincent B. Colloid Polym Sci 1992, 270:563.
Gao Z.S., Varshney S.K., Wong S., Eisenberg A. Macromolecules 1994, 27:7923.
Tuzar Z., Webber S.E., Ramireddy C., Munk P. Polym Prepr 1991, 32:525.
Cao T., Munk P., Ramireddy C., Tuzar Z., Webber S.E. Macromolecules 1991, 24:6300.
Kiserow D., Prochazka K., Ramireddy C., Tuzar Z., Munk P., Webber S.E. Macromolecules 1992, 25:461.
Prochazka K., Kiserow D., Ramireddy C., Webber S.E., Munk P., Tuzar Z. Makromol Chem Macromol Symp 1992, 58:201.
Chan J., Fox S., Kiserow D., Ramireddy C., Munk P., Webber S.E. Macromolecules 1993, 26:7016.
Tian M., Qin A., Ramireddy C., Webber S.E., Munk P., Tuzar Z., Prochakza K. Langmuir 1993, 9:1741.
Tuzar Z., Kratochvil P., Prochakza K., Munk P. Collect Czech Chem Commun 1993, 58:2362.
Baines F.L., Armes S.P., Billingham N.C., Tuzar Z. Macromolecules 1996, 29:8151.
Baines F.L., Billingham N.C., Armes S.P. Macromolecules 1996, 29:3416.
Antoun S., Gohy J.F., Jérôme R. Polymer 2001, 42:3641.
Selb J., Gallot Y. Developments in block copolymers , Goodman I, editor. Amsterdam: Elsevier; 1985, 2:85.
Zhang L., Eisenberg A. Science 1995, 268:1728.
Discher B.M., Won Y.Y., Ege D.S., Lee J.C.M., Bates F.S., Discher D.E., Hammer D.A. Science 1999, 284:1143.
Yu K., Eisenberg A. Macromolecules 1998, 31:3509.
Gohy J.F., Creutz S., Garcia M., Mahltig B., Stamm M., Jérôme R. Macromolecules 2000, 33:6378.
Leemans L., Fayt R., Teyssié Ph. J Polym Sci 1990, 28:1255.
Leemans L., Fayt R., Teyssié Ph., De Jaeger N.C. Macromolecules 1991, 24:5922.
Abraham T., Giasson S., Gohy J.F., Jérôme R. Langmuir 2000, 16:4286.
Abraham T., Giasson S., Gohy J.F., Jérôme R., Müller B., Stamm M. Macromolecules 2000, 33:6051.
Zilliox J.G., Rempp P., Parrod J. J Polym Sci, Part C 1968, 22:145.
Alexandridis P., Holzwarth J.F., Hatton T.A. Macromolecules 1994, 27:2414.
Wanka G., Hoffmann M., Ulbricht W. Macromolecules 1994, 27:4145.
Chu B., Zhou Z. (1996) Nonionic surfactants., Nace VN, editor. Polyoxyalkylene block copolymers. New York: Marcel Dekker; 60.
Astafieva I., Zhong X.F., Eisenberg A. Macromolecules 1993, 26:7339.
Wang Y., Balaji R., Quirk R.P., Mattice W.L. Polym Bull 1992, 28:333.
Creutz S., Van Stam J., Antoun S., De Schryver F., Jérôme R. Macromolecules 1997, 30:4078.
Creutz S., Van Stam J., De Schryver F., Jérôme R. Macromolecules 1998, 31:681.
Wang Q.G., Price C., Booth C. J Chem Soc, Faraday Trans 1992, 88:1437.