Electronic Autoionization in Carbon monoxide: The effects of the Vibrational Motion.

Leyh, Bernard; Delwiche, Jacques; Hubin-Franskin, Marie-Jeanne; Nenner, I.

doi:10.1016/0301-0104(87)80038-1

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Electronic Autoionization in Carbon monoxide: The effects of the Vibrational Motion.

Leyh, Bernard; Delwiche, Jacques; Hubin-Franskin, Marie-Jeanne et al.

1987 • In Chemical Physics, 115, p. 243-252

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https://hdl.handle.net/2268/9405

DOI
10.1016/0301-0104(87)80038-1

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Keywords :

Vibrationally resolved photoionization cross section; Electronic autoionization; Condon approximation

Abstract :

[en] New continuous measurements of the vibrationally resolved photoionization cross sections of CO+ X2Sigma+ and A2Pi between 63 and 83 nm are reported. We assign the Rydberg series converging to CO+ A2Pi. The effects of the vibrational motion are interpreted on the basis of the Condon approximation. This approximation is shown to allow a qualitative understanding of the decay of the Rydberg series converging to the A2Pi and B2Sigma+ states of CO+.

Research Center/Unit :

Laboratoire de Dynamique Moléculaire

Disciplines :

Chemistry

Author, co-author :

Leyh, Bernard ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire

Delwiche, Jacques ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)

Hubin-Franskin, Marie-Jeanne ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie physique, spectrométrie de masse

Nenner, I.

Language :

English

Title :

Electronic Autoionization in Carbon monoxide: The effects of the Vibrational Motion.

Alternative titles :

[fr] L'autoionisation électronique dans le Monoxide de Carbone: les effets du mouvement vibrationnel.

Publication date :

1987

Journal title :

Chemical Physics

ISSN :

0301-0104

Publisher :

Elsevier Science, Amsterdam, Netherlands

Volume :

115

Pages :

243-252

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

NATO - North Atlantic Treaty Organization
FRFC - Fonds de la Recherche Fondamentale Collective
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Funding text :

NATO (Contract n°096.82), FRFC, FNRS.

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