Electronic Autoionization in Carbon monoxide: The effects of the Vibrational Motion.

Leyh, Bernard; Delwiche, Jacques; Hubin-Franskin, Marie-Jeanne; Nenner, I.

doi:10.1016/0301-0104(87)80038-1

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Electronic Autoionization in Carbon monoxide: The effects of the Vibrational Motion.

Leyh, Bernard; Delwiche, Jacques; Hubin-Franskin, Marie-Jeanne et al.

1987 • In Chemical Physics, 115, p. 243-252

Peer Reviewed verified by ORBi

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10.1016/0301-0104(87)80038-1

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Keywords :

Vibrationally resolved photoionization cross section; Electronic autoionization; Condon approximation

Abstract :

[en] New continuous measurements of the vibrationally resolved photoionization cross sections of CO+ X2Sigma+ and A2Pi between 63 and 83 nm are reported. We assign the Rydberg series converging to CO+ A2Pi. The effects of the vibrational motion are interpreted on the basis of the Condon approximation. This approximation is shown to allow a qualitative understanding of the decay of the Rydberg series converging to the A2Pi and B2Sigma+ states of CO+.

Research center :

Laboratoire de Dynamique Moléculaire

Disciplines :

Chemistry

Author, co-author :

Leyh, Bernard ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire

Delwiche, Jacques ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)

Hubin-Franskin, Marie-Jeanne ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie physique, spectrométrie de masse

Nenner, I.

Language :

English

Title :

Electronic Autoionization in Carbon monoxide: The effects of the Vibrational Motion.

Alternative titles :

[fr] L'autoionisation électronique dans le Monoxide de Carbone: les effets du mouvement vibrationnel.

Publication date :

1987

Journal title :

Chemical Physics

ISSN :

0301-0104

Publisher :

Elsevier Science, Amsterdam, Netherlands

Volume :

115

Pages :

243-252

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

NATO (Contract n°096.82), FRFC, FNRS.

Available on ORBi :

since 23 March 2009

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Bibliography

Dehmer, Dill, Parr (1985) Nato ASI series C142. Photophysics and photochemistry in the vacuum ultraviolet, S.Mc. Glynn, G. Findley, R. Huebner, Reidel, Dordrecht; .
Koy, Carlson, Lucchese (1984) Photoelectron dynamics of molecules. The Journal of Physical Chemistry 88:3188.
Natalis, Delwiche, Collin Chem. Phys. Letters 1972, 13:491.
Gardner, Samson J. Electron Spectry. 1978, 13:7.
Ederer, Parr, Cole, Stockbauer, Dehmer, West, Codling (1981) Vibrational-State Dependence of Partial Cross Sections and Photoelectron Angular Distributions through Autoionizing Resonances: The Formula Rydberg State Converging to the B Formula State of COFormula. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 378 A:423.
Natalis, Delwiche, Collin, Caprace, Praet Chem. Phys. Letters 1977, 49:177.
Morin, Nenner, Adam, Hubin-Franskin, Delwiche, Lefebvre-Brion, Giusti-Suzor Chem. Phys. Letters 1982, 92:609.
Natalis (1973) Mémoires de l'Académie Royale de Belgique. Classe des Sciences , 2ème série, XLI fasc.; 1.
Potts, Fattahallah J. Phys. 1980, 13 B:2545.
Hubin-Franskin, Delwiche, Morin, Adam, Nenner, Roy J. Chem. Phys. 1984, 81:4246.
Henning (1932) Die Absorptionsspektren von Kohlendioxyd, Kohlenmonoxyd und Wasserdampf im Gebiet von 600–900 ÅE. Annalen der Physik 13:599.
Tanaka Sci. Papers Inst. Chem. Res. (Tokyo) 1942, 39:447.
Huffman, Larrabee, Tanaka J. Chem. Phys. 1964, 40:2261.
Ogawa J. Chem. Phys. 1965, 43:2142.
Ogawa, Ogawa J. Mol. Spectry. 1972, 41:393.
Fock, Gürtler, Koch Chem. Phys. 1980, 47:87.
Lindholm Arkiv Fysik 1969, 40:103.
Leyh, Raşeev Phys. Rev. 1986, 34 A:2920.
Huber, Herzberg (1979) Molecular spectra and molecular structure. Constants of diatomic molecules , Van Nostrand-Reinhold, New York; 4:166.
Raşeev, Leyh, Lefebvre-Brion Z. Physik 1986, 500 2:319.
Ito, Tabché-Fouhailé, Fröhlich, Guyon, Nenner J. Chem. Phys. 1985, 82:1231.
Plummer, Gustafsson, Gudat, Eastman Phys. Rev. 1977, 15 A:2339.
Samson, Gardner J. Electron Spectry. 1976, 8:35.
Morin, Adam, Nenner, Delwiche, Hubin-Franskin, Lablanquie Nucl. Instr. Methods 1983, 208:761.
Lefebvre-Brion J. Mol. Spectry. 1973, 19:103.
Fano Phys. Rev. 1961, 124:1866.
Fano, Cooper Phys. Rev. 1965, 137:A1364.
Starace Phys. Rev. 1977, 16 A:231.
Smith (1970) The Role of Autoionization in Molecular Photoelectron Spectra. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 268 A:169.
Berkowitz Photoabsorption, photoionization and photoelectron spectroscopy , Academic Press, New York; 1979, 228.
Giusti-Suzor, Lefebvre-Brion Phys. Rev. 1984, 30 A:3057.
Berry (1966) Ionization of Molecules at Low Energies. The Journal of Chemical Physics 45:1228.
Berkowitz, Chupka J. Chem. Phys. 1969, 51:2341.
Raoult, Jungen J. Chem. Phys. 1981, 74:3388.
Ono, Linn, Prest, Ng, Miescher J. Chem. Phys. 1980, 73:4855.
Giusti-Suzor, Jungen (1984) Theoretical study of competing photoionization and photodissociation processes in the NO molecule. The Journal of Chemical Physics 80:986.
Berkowitz, Greene J. Chem. Phys. 1984, 81:4328.
Eland J. Chim. Phys. 1980, 77:613.
Tabché-Fouchailé, Hubin-Franskin, Delwiche, Fröhlich, Ito, Guyon, Nenner (1983) Excitation spectra of neutral fragments emissions by photodissociation of OCS using VUV photons. The Journal of Chemical Physics 79:5894.