Amphiphilic sun-shaped polymers by grafting macrocyclic copolyesters with PEO

Li, Haiying; Jérôme, Robert; Lecomte, Philippe

doi:10.1021/ma070282o

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Article (Scientific journals)

Amphiphilic sun-shaped polymers by grafting macrocyclic copolyesters with PEO

Li, Haiying; Jérôme, Robert; Lecomte, Philippe

2008 • In Macromolecules, 41 (3), p. 650-654

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/930

DOI
10.1021/ma070282o

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Keywords :

ring-opening polymerization; lactone; macrocycle

Abstract :

[en] An amphiphilic sun-shaped copolymer was successfully prepared by esterification of carboxylic acid terminated PEO with the pendent hydroxyl groups of high molecular weight (M-n = 28 000) cyclic PCL. The cyclic structure of the copolyester originally resulted from the polymerization initiation by a cyclic tin dialkoxide and was ultimately stabilized by the intramolecular cross-linking of a few unsaturated groups.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Li, Haiying ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Lecomte, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Amphiphilic sun-shaped polymers by grafting macrocyclic copolyesters with PEO

Publication date :

12 February 2008

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

Issue :

Pages :

650-654

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/cgi-bin/article.cgi/mamobx/2008/41/i03/pdf/ma070282o.pdf

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Available on ORBi :

since 13 November 2008

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