Design of mesoporous carbon fibers from a poly(acrylonitrile) based block copolymer by a simple templating compression moulding process

Thomassin, Jean-Michel; Debuigne, Antoine; Jérôme, Christine; Detrembleur, Christophe

doi:10.1016/j.polymer.2010.05.010

Article (Scientific journals)

Design of mesoporous carbon fibers from a poly(acrylonitrile) based block copolymer by a simple templating compression moulding process

Thomassin, Jean-Michel; Debuigne, Antoine; Jérôme, Christine et al.

2010 • In Polymer, 51 (14), p. 2965-2971

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/91535

DOI
10.1016/j.polymer.2010.05.010

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Keywords :

fiber; carbon

Abstract :

[en] Mesoporous carbon fibers were prepared by controlled pyrolysis of poly(vinyl acetate)-b-poly(acrylonitrile) (PVAc-b-PAN) copolymer located inside a cylindrical nanoporous template. A melt-compression method was developed to help the penetration of the infusible copolymer inside the template without the use of any solvent that ensures the formation of completely filled fibers instead of nanotubes. The influence of the composition of the PVAc-b-PAN copolymer and the heating rate during pyrolysis on the porous morphology of the fibers was studied by transmission electron microscopy (TEM).

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Thomassin, Jean-Michel ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Design of mesoporous carbon fibers from a poly(acrylonitrile) based block copolymer by a simple templating compression moulding process

Publication date :

24 June 2010

Journal title :

Polymer

ISSN :

0032-3861

eISSN :

1873-2291

Publisher :

Elsevier Science, Oxford, United Kingdom

Volume :

Issue :

Pages :

2965-2971

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TXW-5033XX8-2-R&_cdi=5601&_user=532038&_pii=S003238611000412X&_origin=browse&_zone=rslt_list_item&_coverDate=06%2F24%2F2010&_sk=999489985&wchp=dGLzVzb-zSkzV&md5=86b7cc55594e6074b36af5839826f9de&ie=/sdarticle.pdf

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]

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