Insight into organometallic-mediated radical polymerization

[en] This review focuses on an emerging class of controlled radical polymerization named Organometallic-Mediated Radical Polymerization (OMRP). The latter is based on the temporary deactivation of the growing radical species by a transition metal complex and the reversible formation of a carbon-metal covalent bond. Initially developed with cobalt complexes, OMRP has extended to several metals today. As highlighted here, the choice of the metal, the structure of ligands, temperature, and additives deeply affect the course of the polymerization and its mechanism. Macromolecular engineering opportunities offered by OMRP are also described, as well as practical applications sustained by the resulting polymer materials.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Hurtgen, Marie ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Insight into organometallic-mediated radical polymerization

Publication date :

29 April 2011

Journal title :

Polymer Reviews

ISSN :

1558-3724

eISSN :

1558-3716

Publisher :

Taylor & Francis Ltd

Volume :

Issue :

Pages :

188-213

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.informaworld.com/smpp/ftinterface~content=a936906595~fulltext=713240930~frm=content

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

Available on ORBi :

since 06 May 2011

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Scopus citations^®

135

Scopus citations^®
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OpenCitations

137

OpenAlex citations

149

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