Oxides; Chemical synthesis; X-ray diffraction; Electrical properties; Magnetic properties
Abstract :
[en] Synthesis of polycationic compounds by the spray-drying technique is an interesting alternative in the domain of aqueous precursor synthesis methods. Spray drying yields high quality samples with good reproducibility. The possibility of scaling up for production of large quantities with fast processing time is well established by the commercial availability of powders of various compositions. In this paper, we have discussed the advantages and limitations of this method and demonstrated its interest by synthesizing a few polycationic compounds selected for their attractive properties of thermoelectricity [Bi1.68Ca2Co1.69O8, La(0.95)A(0.05)CoO(3) (A = Ca, Sr, Ba)] or magnetoresistance [La(0.70)A(0.30)MnO(3) (A=Sr, Ba)]. We have confirmed the quality of these samples by reporting their structure, magnetic and transport properties. (C) 2010 Elsevier Ltd. All rights reserved.
Disciplines :
Chemistry Physics
Author, co-author :
Rivas-Murias, B.; Université de Liège - ULiège > Département de Chimie > LCIS
Fagnard, Jean-François ; Université de Liège - ULiège > Dép. d'électric., électron. et informat. (Inst.Montefiore) > Capteurs et systèmes de mesures électriques
Vanderbemden, Philippe ; Université de Liège - ULiège > Dép. d'électric., électron. et informat. (Inst.Montefiore) > Capteurs et systèmes de mesures électriques
Traianidis, M.; Belgian Ceramic Research Centre, Mons, Belgium
Henrist, Catherine ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Cloots, Rudi ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Vertruyen, Bénédicte ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS
Language :
English
Title :
Spray drying: An alternative synthesis method for polycationic oxide compounds
Publication date :
2011
Journal title :
Journal of Physics and Chemistry of Solids
ISSN :
0022-3697
Publisher :
Pergamon-Elsevier Science Ltd, Oxford, United Kingdom
Volume :
72
Issue :
3
Pages :
158-163
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Bibliography
D. Segal J. Mater. Chem. 7 1997 1297 1305
M.I. Re Dry. Technol. 16 1998 1195 1236
S.J. Lukasiewicz J. Am. Ceram. Soc. 72 1989 617 624
A. Schrijnemakers, S. Andr, G. Lumay, N. Vandewalle, F. Boschini, R. Cloots, and B. Vertruyen J. Eur. Ceram. Soc. 29 2009 2169 2175
D. Depla, R. Mouton, and S. Hoste J. Eur. Ceram. Soc. 17 1997 153 159
B. Vertruyen, A. Rulmont, R. Cloots, J.-F. Fagnard, M. Ausloos, I. Vandriessche, and S. Hoste J. Mater. Sci. 40 2005 117 122
T. Motohashi, Y. Nonaka, and K. Sakai J. Appl. Phys. 103 2008 033705
F. Bezzi, A.L. Costa, D. Piazza, A. Ruffini, S. Albonetti, and C. Galassi J. Eur. Ceram. Soc. 25 2005 3323 3334
F. Gao, Z. Tang, and J. Xue Electrochim. Acta 53 2007 1939 1944
A. Ito, D. Li, Y. Lee, K. Kobayakawa, and Y. Sato J. Power Sources 185 2008 1429 1433
H.M. Wu, J.P. Tu, X.T. Chen, Y.F. Yuan, Y. Li, X.B. Zhao, and G.S. Cao J. Power Sources 159 2006 291 294
S. Bebelis, N. Kotsionopoulos, A. Mai, and F. Tietz J. Appl. Electrochem. 37 2007 15 20
B. Vertruyen, R. Cloots, M. Ausloos, J.-F. Fagnard, and Ph. Vanderbemden Phys. Rev. B 75 2007 165112
H. Leligny, D. Grebille, O. Prez, A.C. Masset, M. Hervieu, C. Michel, and B. Raveau Acta Cryst. B 56 2000 173 182
V. Petricek, M. Dusek, and L. Palatinus Jana 2000: Crystallographic Computing System 2000 Institute of Physics Prague
H. Muguerra, D. Grebille, E. Guilmeau, and R. Cloots Inorg. Chem. 47 2008 2464 2471
C.J. Howard, B.A. Hunter, Rietica: "A computer program for Rietveld analysis of X-ray and neutron powder diffraction patterns", Australian Nuclear Science and Technology Organization, Lucas Heights Research Laboratories.
A.J. Zhou, T.J. Zhu, and X.B. Zhao J. Mater. Sci. 43 2008 1520 1524
H.L. Ju, Y.S. Nam, J.E. Lee, and H.S. Shin J. Magn. Magn. Mater. 219 2000 1 8
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