Nanostructured PMMA: from lamellar sheets to double-layered vesicles

Koulic, Christian; Jérôme, Robert

doi:10.1021/ma035557o

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Article (Scientific journals)

Nanostructured PMMA: from lamellar sheets to double-layered vesicles

Koulic, Christian; Jérôme, Robert

2004 • In Macromolecules, 37 (3), p. 888-893

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https://hdl.handle.net/2268/8344

DOI
10.1021/ma035557o

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Keywords :

nanostructured material; polymer blend; self assembly in bulk

Abstract :

[en] PMMA was nanostructured by similar to100 nm liposome-like vesicular objects by melt blending with 20 wt % of a symmetric poly(styrene)-b-poly(isoprene)-b-poly(methyl methacrylate) (PS-b-PIP-b-PMMA) triblock copolymer in the dry-brush regime. Whenever the blend was prepared by casting toluene solution, thus under zero-shear conditions, a continuous network of lamellar copolymer sheets was formed in PMMA, which however underwent a transition to the aforementioned vesicles upon application of large amplitude oscillatory shear.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Koulic, Christian; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Nanostructured PMMA: from lamellar sheets to double-layered vesicles

Publication date :

10 February 2004

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

888-893

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma035557o

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

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