[en] Highly dispersed Pt/carbon xerogel catalysts are obtained by applying the “Strong Electrostatic Adsorption” (SEA) of hexachloroplatinic acid to carbon xerogels (PZC = 9.4) and platinum tetraammine chloride to oxidized carbon xerogels (PZC = 2.4). After the reduction step, all these Pt/carbon xerogel catalysts display a very high level of metal dispersion: very small platinum particles (1.1-1.3 nm) are observed by TEM. Pt particle sizes obtained by CO chemisorption are in good agreement with TEM micrographs, which shows that the metal is accessible to reactants. These Pt/carbon xerogel catalysts are very active for the hydrogenation of benzene into cyclohexane.
Disciplines :
Chemistry Chemical engineering
Author, co-author :
Lambert, Stéphanie ; Université de Liège - ULiège > Département de chimie appliquée > Génie chimique - Chimie physique appliquée
Job, Nathalie ; Université de Liège - ULiège > Département de chimie appliquée > Génie chimique - Chimie physique appliquée
D'Souza, Lawrence; University of Illinois at Chicago > Chemical Engineering Department
Pereira Ribeiro, Manuel Fernando; University of Porto, Portugal > Departamento de Engenharia Quimica > Laboratorio de Catalise e Materiais (LCM), Laboratorio Associado LSRE/LCM
Pirard, René ; Université de Liège - ULiège > Département de chimie appliquée > Génie chimique - Chimie physique appliquée
Heinrichs, Benoît ; Université de Liège - ULiège > Département de chimie appliquée > Génie chimique - Chimie physique appliquée
Figueiredo, José Luis; University of Porto > Departamento de Engenharia Quimica > Laboratorio de Catalise e Materiais (LCM), Laboratorio Associado LSRE/LCM
Pirard, Jean-Paul ; Université de Liège - ULiège > Département de chimie appliquée > Génie chimique - Chimie physique appliquée
Regalbuto, Jonh R.; University of Illinois at Chicago > Chemical Engineering Department
Language :
English
Title :
Synthesis of very highly dispersed platinum catalysts supported on carbon xerogels by the strong electrostatic adsorption method
Publication date :
January 2009
Journal title :
Journal of Catalysis
ISSN :
0021-9517
eISSN :
1090-2694
Publisher :
Academic Press, San Diego, United States - California
Volume :
261
Pages :
23-33
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] Fonds de Bay FRFC - Fonds de la Recherche Fondamentale Collective [BE] DGTRE - Région wallonne. Direction générale des Technologies, de la Recherche et de l'Énergie [BE] Pole d'Attraction Interuniversitaire (IAP-P6/17) Commission for Educational Exchange between The United States of America, Belgium and Luxembourg
Commentary :
Authors thank Elsevier to publish in Open Access this article in the postprint author version.
Gasteiger H.A., Gu W., Makharia R., Mathias M.F., and Sompalli B. In: Vielstich W., Lamm A., and Gasteiger H.A. (Eds). Handbook of Fuel Cells-Fundamentals, Technology and Applications, vol. 3 (2003), Wiley, Chichester 593-610
Gasteiger H.A., Kocha S.S., Sompalli B., and Wagner F.T. Appl. Catal. B 56 (2005) 9
Moreno-Castilla C., and Maldonado-Hódar F.J. Carbon 43 (2005) 455
Fraga M.A., Jordao E., Mendes M.J., Freitas M.M.A., Faria J.L., and Figueiredo J.L. J. Catal. 209 (2002) 355
van Dam H.E., and van Bekkum H. J. Catal. 131 (1991) 335
Hao X., Quach L., Korah J., Spieker W.A., and Regalbuto J.R. J. Mol. Catal. A 219 (2004) 97
Job N., Pirard R., Marien J., and Pirard J.-P. Carbon 42 (2004) 619
Job N., Théry A., Pirard R., Marien J., Kocon L., Rouzaud J.-N., Béguin F., and Pirard J.-P. Carbon 43 (2005) 2481
Park J., and Regalbuto J.R. J. Colloid Interface Sci. 175 (1995) 239
Regalbuto J.R. In: Regalbuto J.R. (Ed). Catalyst Preparation: Science and Engineering (2007), CRC Press/Taylor & Francis Group, Boca Raton 297
Lecloux A.J. In: Anderson J.R., and Boudart M. (Eds). Catalysis: Science and Technology vol. 2 (1981), Springer-Verlag, Berlin 171
Alié C., Lambert S., Heinrichs B., and Pirard J.-P. J. Sol-Gel Sci. Technnol. 26 (2003) 827
Washburn E.W. Proc. Natl. Acad. Sci. USA 7 (1921) 115
Bergeret G., and Gallezot P. In: Ertl G., Knözinger H., and Weitkamp J. (Eds). Handbook of Heterogeneous Catalysis (1997), Wiley-VCH, Weinheim 439
Farrauto R.J., and Bartholomew C.H. Fundamentals of Industrial Catalytic Processes (1997), Blackie Academic & Professionals/Chapman & Hall, London p. 436
Aksoylu A.E., Madalena M., Freitas A., and Figueiredo J.L. Appl. Catal. A 192 (2000) 29
Aksoylu A.E., Madalena M., Freitas A., Pereira M.F.R., and Figueiredo J.L. Carbon 39 (2001) 175
Aksoylu A.E., Faria J.L., Pereira M.F.R., Figueiredo J.L., Serp P., Hierso J.-C., Feurer R., Kihn Y., and Kalck P. Appl. Catal. A 243 (2003) 357
Job N., Ribeiro Pereira M.F., Lambert S., Cabiac A., Delahay G., Colomer J.-F., Marien J., Figueiredo J.L., and Pirard J.-P. J. Catal. 240 (2006) 160
Lin S.D., and Vannice M.A. J. Catal. 143 (1993) 539
Satterfield C.N. Mass Transfer in Heterogeneous Catalysis (1970), MIT Press, Cambridge
Vinke P., van der Eijk M., Verbree M., Voskamp A.F., and van Bekkum H. Carbon 32 (1994) 675
Santhanam N., Conforti T.A., Spieker W., and Regalbuto J.R. Catal. Today 21 (1994) 141
Torres G.C., Jablonski E.L., Baronetti G.T., Castro A.A., de Miguel S.R., Scelza O.A., Blanco M.D., Pena Jiménez M.A., and Fierro J.L.G. Appl. Catal. A 161 (1997) 213
Rodríguez-Reinoso F. Carbon 36 (1998) 159
Che M., Clause O., and Marcilly C. In: Ertl G., Knözinger H., and Weitkamp J. (Eds). Handbook of Heterogeneous Catalysis (1997), Wiley-VCH, Weinheim 191
Schlögl R. In: Ertl G., Knözinger H., and Weitkamp J. (Eds). Handbook of Heterogeneous Catalysis (1997), Wiley-VCH, Weinheim 138
Coloma F., Sepúlveda-Escribano A., and Rodríguez-Reinoso F. Appl. Catal. A 150 (1997) 165
Toebes M.L., Prinsloo F.F., Bitter J.H., van Pillen A.J., and de Jong K.P. J. Catal. 214 (2003) 78
Toebes M.L., Zhang Y., Hájek J., Nijhuis T.A., Bitter J.H., Jos van Pillen A., Murzin D.Y., Koningsberger D.C., and de Jong K.P. J. Catal. 226 (2004) 215
Ramaker D.E., de Graaf J., van Veen J.A.R., and Koningsberger D.C. J. Catal. 203 (2001) 7
Domingo-Garcia M., Lopez-Garzon F.J., and Perez-Mendoza M. J. Colloid Interface Sci. 222 (2000) 233
