Article (Scientific journals)
Segregation of coronal chains in micelles formed by supramolecular interactions
Gohy, Jean-François; Khousakoun, Eric; Willet, Nicolas et al.
2004In Macromolecular Rapid Communications, 25 (17), p. 1536-1539
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Keywords :
self-assembly in solution; micelle; stimuli responsive micelle
Abstract :
[en] Spherical micelles have been formed by mixing, in DMF, a poly(styrene)-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) (PS-block-P2VP-block-PEO) triblock copolymer with either poly(acrylic acid) (PAA) or a tapered triblock copolymer consisting of a PAA central block and PEO macromonomer-based outer blocks. Noncovalent interactions between PAA and P2VP result in the micellar core while the outer corona contains both PS and PEO chains. Segregation of the coronal chains is observed when the tapered copolymer is used.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Gohy, Jean-François;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Khousakoun, Eric;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Willet, Nicolas ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Varshney, Sunil K;  Polymer Source, Dorval (Montréal), Canada
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Segregation of coronal chains in micelles formed by supramolecular interactions
Publication date :
09 September 2004
Journal title :
Macromolecular Rapid Communications
ISSN :
1022-1336
eISSN :
1521-3927
Publisher :
Wiley-V C H Verlag Gmbh, Weinheim, Germany
Volume :
25
Issue :
17
Pages :
1536-1539
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
The "Comunauté Française de Belgique" (ARC 03/08-300, NANOMOL)
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