[en] The first hydrothermal synthesis of an Al-rich alluaudite-type compound, namely disodium dimanganese aluminium tris(phosphate), which has been obtained at 1073 K and 0.1 GPa starting from the composition Na2Mn2Al(PO4)(3), is reported. The crystal structure, which has been refined in the monoclinic C2/c space group, is identical to that of natural alluaudite. The structure consists of kinked chains of edge-sharing M1 and M2 octahedra, which contain Mn2+ and Al3+ ions. The chains are stacked parallel to {101} and are connected in the b direction by the P1 and P2 tetrahedra. These interconnected chains produce channels parallel to c, which contain the large A1 and AT sites occupied by Na+ and Mn2+ ions.
Disciplines :
Chemistry Earth sciences & physical geography
Author, co-author :
Hatert, Frédéric ; Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Language :
English
Title :
Na(1.50)Mn(2.48)Al(0.85)(Po4)3, a New Synthetic Alluaudite-Type Compound
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Bibliography
Brier, M. (2000). Diploma thesis, University of Stuttgart, Germany.
Brown, I. D. & Altermatt, D. (1985). Acta Cryst. B41, 244-247.
Dowty, E. (1993). ATOMS for Windows. Version 2.3. Shape Software, 521 Hidden Valley Road, Kingsport, TN 37663, USA.
Fransolet, A.-M. (1975). PhD thesis, University of Liège, Belgium.
Hatert, F. (2002). PhD thesis, University of Liège, Belgium.
Hatert, F. (2004). Mem. Acad. R. Belg. Cl. Sci. Coll. 8° 3eme Ser. 21, 1-96.
Hatert, F., Keller, P., Lissner, F., Antenucci, D. & Fransolet, A.-M. (2000). Eur. J. Mineral. 12, 847-857.
Hatert, F., Lefèvre, P., Fransolet, A.-M., Spirlet, M.-R., Rebbouh, L., Fontan, F. & Keller, P. (2005). Eur. J. Mineral. 17, 749-759.
Hatert, F., Rebbouh, L., Hermann, R., Fransolet, A.-M., Long, G. J. & Grandjean, F. (2005). Am. Mineral. 90, 653-662.
Moore, P. B. (1971). Am. Mineral. 56, 1955-1975.
Moore, P. B. & Molin-Case, J. (1974). Am. Mineral. 59, 280-290.
Sheldrick, G. M. (1990). Acta Cryst. A46, 467-473.
Sheldrick, G. M. (1991). SHELXTL-Plus. Release 4.1. Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA.
Sheldrick, G. M. (1997). SHELXL97. University of Göttingen, Germany.
Tuttle, O. F. (1949). Geol. Soc. Am. Bull. 60, 1727-1729.
Zhesheng, M., Nicheng, S. & Zhizhong, P. (1983). Sci. Sinica Ser. B, 26, 876-884.
This website uses cookies to improve user experience. Read more
Save & Close
Accept all
Decline all
Show detailsHide details
Cookie declaration
About cookies
Strictly necessary
Performance
Strictly necessary cookies allow core website functionality such as user login and account management. The website cannot be used properly without strictly necessary cookies.
This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.
Performance cookies are used to see how visitors use the website, eg. analytics cookies. Those cookies cannot be used to directly identify a certain visitor.
Used to store the attribution information, the referrer initially used to visit the website
Cookies are small text files that are placed on your computer by websites that you visit. Websites use cookies to help users navigate efficiently and perform certain functions. Cookies that are required for the website to operate properly are allowed to be set without your permission. All other cookies need to be approved before they can be set in the browser.
You can change your consent to cookie usage at any time on our Privacy Policy page.
