Non-innocent Behaviour of Dithiocarboxylate Ligands Based on N-Heterocyclic Carbenes

[en] The ruthenium(II) complex [Ru(CH=CHC6H4Me-4)(κ2-S2C•NHC)(CO)(PPh3)2]+ is formed on reaction of NHC•CS2 (NHC = ICy, IMes) with [Ru(CH=CHC6H4Me-4)Cl(CO)(BTD)(PPh3)2] in the presence of NH4PF6, whereas the analogous reaction with the more bulky IDip•CS2 leads to the remarkable product, [Ru{κ2-SC(H)S(CH=CHC6H4Me-4)•IDip}Cl(CO)(PPh3)2]+.

Disciplines :

Chemistry

Author, co-author :

Naeem, Saira

Thompson, Amber L.

Delaude, Lionel ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Wilton-Ely, James D. E. T.

Language :

English

Title :

Non-innocent Behaviour of Dithiocarboxylate Ligands Based on N-Heterocyclic Carbenes

Publication date :

2010

Journal title :

Chemistry

ISSN :

0947-6539

eISSN :

1521-3765

Publisher :

Wiley, Weinheim, Germany

Volume :

Issue :

Pages :

10971-10974

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 16 November 2010

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