[en] Thermoelectric power and thermal conductivity of YBa2(Cu1-xFex)(3)O-7-delta polycrystals for 0<x<0.03 and with y% CuO (y equals 0 and 5) extrinsic impurity were simultaneously measured as a function of temperature. Samples were prepared following the same synthesis runs, and characterized by X-ray, EDX, and magnetic susceptibility techniques. When increasing copper oxide concentration, the transition is unaffected with respect to the pure sample, and the thermal transport coefficients correspond to very well oxygenated systems. Fe doped samples showed a lower transition temperature and features corresponding to low oxygenation systems. Fe doped sample with CuO revealed also the partial absorption of Fe by the ''extra CuO phase'' due to the 'dilution' of iron in the excess of CuO al grain boundaries. Fe-doping and excess CuO markedly reduce the thermal conductivity.
Disciplines :
Physics
Author, co-author :
Bougrine, Hassan ; Université de Liège - ULiège > CARE "Le Réseau des bibliothèques" > Bibliothèque des Sciences et Techniques
Ausloos, Marcel ; Université de Liège - ULiège > Département de physique > Physique statistique appliquée et des matériaux - S.U.P.R.A.S.
HOUSSA, M.
MEHBOD, M.
Language :
English
Title :
THERMOELECTRIC-POWER AND THERMAL-CONDUCTIVITY IN YBA2(CU1-XFEX)(3)O-7-DELTA WITH OR WITHOUT EXCESS OF COPPER-OXIDE
Sergeenkov, Ausloos, Bougrine, Cloots, Gridin, Thermoelectric power of textured Bi2Sr2CaCu2O8: Evidence for field-induced hysteretic behavior (1993) Physical Review B, 48, p. 16680
I. Grandjean (unpublished)
Cornejo, Trefny, Yarar, Thermoelectric power of YBa2Cu3O7−δ superconductive thin films as a function of oxygen contents (1993) Journal of Materials Research, 8, p. 255
Ouseph, O'Bryan, Thermoelectric power of YBa2Cu3O7-δ (1990) Physical Review B, 41 B, p. 4123
Tewordt, Wölkhausen, Theory of thermal conductivity of the lattice for high-Tc superconductors (1989) Solid State Communications, 70, p. 839
Peacor, Richardson, Nori, Uher, Theoretical analysis of the thermal conductivity of YBa2Cu3O7-δ single crystals (1991) Physical Review B, 44, p. 9508
Ausloos, Houssa, Thermal conductivity of an untwinned YBa2Cu3O7−δ single crystal (1993) Physica C: Superconductivity, 218, p. 15
Houssa, Bougrine, Ausloos, Grandjean, Mehbod, (1994) J. Phys.: Cond. Matt., , to be publ. in