Article (Scientific journals)
Unimolecular Dynamics from Kinetic Energy Release Distributions. V. How does the Efficiency of Phase Space Sampling vary with Internal Energy?
Hoxha, A.; Locht, Robert; Lorquet, Andrée et al.
1999In Journal of Chemical Physics, 111 (20), p. 9259-9266
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Keywords :
Retarding Field analysis; KERD; Dissociative photoionization; Maximum Entropy Method (MEM); He(I), Ne(I), Ar(II); Ab initio Calculations; C2H3+/C2H3Br
Abstract :
[en] A retarding field technique coupled with a quadrupole mass analyzer has been used to obtain the kinetic energy release distributions (KERDs) for C2H3Br+->[C2H3]++Br dissociation as a function of the internal energy. The KERDs obtained by dissociative photoionization using the He(I), Ne(I) and Ar(II) resonance lines were analyzed by the maximum entropy method and were found to be well described by introducing a single dynamical constraint, namely the relative translational momentum of the fragments. Ab initio calculations reveal the highly fluxional character of the C2H3+ ion. As the energy increases, several vibrational modes are converted in turn into large-amplitude motions. Our main result is that, upon increasing internal energy, the fraction of phase space sampled by the pair of dissociating fragments is shown to first decrease, pass through a shallow minimum around 75%, and then increase again, reaching almost 100% at high internal energies (8 eV). This behaviour at high internal energies is interpreted as resulting from the conjugated effect of intramolecular vibrational redistribution (IVR) and radiationless transitions among potential energy surfaces. Our findings are consistent with the coincidence data of Miller and Bear, reanalyzed here, and with the KERD of the metastable dissociation.
Research center :
Laboratoire de Dynamique Moléculaire
Disciplines :
Chemistry
Author, co-author :
Hoxha, A.
Locht, Robert  ;  Université de Liège - ULiège > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)
Lorquet, Andrée ;  Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire
Lorquet, Jean-Claude ;  Université de Liège - ULiège > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)
Leyh, Bernard  ;  Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire
Language :
English
Title :
Unimolecular Dynamics from Kinetic Energy Release Distributions. V. How does the Efficiency of Phase Space Sampling vary with Internal Energy?
Alternative titles :
[fr] La dynamique unimoléculaire telle que déduite des distributions d'énergie cinétique. Comment varie l'efficacité d'échantillonnage de l'espace des phases avec l'énergie interne.
Publication date :
1999
Journal title :
Journal of Chemical Physics
ISSN :
0021-9606
eISSN :
1089-7690
Publisher :
American Institute of Physics, New York, United States
Volume :
111
Issue :
20
Pages :
9259-9266
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
ARC Contract
Commentary :
- PDF-version of Editor's Postprint available on request - Version-pdf du tiré-à-part disponible sur demande
Available on ORBi :
since 29 October 2008

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