greeen technology; supercritical carbon dioxide; radical polymerization; atom transfer radical polymerization (ATRP)
Abstract :
[en] Synthesis of poly( 2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Calberg, Cédric ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Wang, Wenxin; University of Nothingham, School of Chemistry, UK
Howdle, Steven; University of Nothingham, School of Chemistry, UK
Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues
Publication date :
2008
Journal title :
Chemical Communications
ISSN :
1359-7345
eISSN :
1364-548X
Publisher :
Royal Society of Chemistry, Cambridge, United Kingdom
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique The ‘‘Région Wallonne’’ in the frame of the ‘‘Surfaces autonettoyantes et anticorrosion’’ (CORRONET) program F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE]