Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues

Grignard, Bruno; Calberg, Cédric; Jérôme, Christine; Wang, Wenxin; Howdle, Steven; Detrembleur, Christophe

doi:10.1039/b812297k

Article (Scientific journals)

Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues

Grignard, Bruno; Calberg, Cédric; Jérôme, Christine et al.

2008 • In Chemical Communications, (44), p. 5803-5805

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/7042

DOI
10.1039/b812297k

PubMed
19009087

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Keywords :

greeen technology; supercritical carbon dioxide; radical polymerization; atom transfer radical polymerization (ATRP)

Abstract :

[en] Synthesis of poly( 2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Calberg, Cédric ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Wang, Wenxin; University of Nothingham, School of Chemistry, UK

Howdle, Steven; University of Nothingham, School of Chemistry, UK

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide : preparation of scCO2 soluble polymers with low catalytic residues

Publication date :

2008

Journal title :

Chemical Communications

ISSN :

1359-7345

eISSN :

1364-548X

Publisher :

Royal Society of Chemistry, Cambridge, United Kingdom

Issue :

Pages :

5803-5805

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.rsc.org/ej/CC/2008/b812297k.pdf
http://www.rsc.org/suppdata/CC/b8/b812297k/index.sht

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
The ‘‘Région Wallonne’’ in the frame of the ‘‘Surfaces autonettoyantes et anticorrosion’’ (CORRONET) program
F.R.S.-FNRS - Fonds de la Recherche Scientifique
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture

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since 26 February 2009

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