Article (Scientific journals)
Sequential electrografting and ring opening metathesis polymerization: a strategy for the tailoring of conductive surfaces
Voccia, Samuel; Claes, Michael; Jérôme, Robert et al.
2005In Macromolecular Rapid Communications, 26 (10), p. 779-783
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Keywords :
electropolymerization; electrografting; ring-opening metathesis polymerization (ROMP)
Abstract :
[en] An electrografting technique has been combined with ring-opening metathesis polymerization (ROMP). Poly(allyl methacrylate) chains have been chemisorbed onto steel and carbon plates under an appropriate cathodic potential in N,N-dimethylformamide. The allyl moieties have been converted into Ru catalysts active in ROMP of norbornene and its derivatives. Initiation of ROMP from the surface is an efficient strategy to prepare strongly adhering coatings of tunable thickness and hydrophilic/hydrophobic balance, depending on the norbornene derivative polymerized at the surface.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Voccia, Samuel;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Claes, Michael;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Sequential electrografting and ring opening metathesis polymerization: a strategy for the tailoring of conductive surfaces
Publication date :
19 May 2005
Journal title :
Macromolecular Rapid Communications
ISSN :
1022-1336
eISSN :
1521-3927
Publisher :
Wiley-V C H Verlag Gmbh, Weinheim, Germany
Volume :
26
Issue :
10
Pages :
779-783
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE]
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