Isoprene-assisted radical coupling of (co)polymers prepared by cobalt-mediated radical polymerization

[en] The isoprene-assisted radical coupling (I-ARC) of polymers prepared by cobalt-mediated radical polymerization (see picture) is the first efficient radical coupling method that is not restricted to short chains. When applied to AB diblock copolymers, I-ARC constitutes a straightforward approach to the preparation of novel symmetrical ABA triblock copolymers

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Deopartment of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Isoprene-assisted radical coupling of (co)polymers prepared by cobalt-mediated radical polymerization

Publication date :

09 February 2009

Journal title :

Angewandte Chemie International Edition

ISSN :

1433-7851

eISSN :

1521-3773

Publisher :

Wiley-VCH Verlag Gmbh, Weinheim, Germany

Volume :

Issue :

Pages :

1422-1424

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/121637751/PDFSTART

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Available on ORBi :

since 19 February 2009

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