Isoprene-assisted radical coupling of (co)polymers prepared by cobalt-mediated radical polymerization

Debuigne, Antoine; Jérôme, Christine; Detrembleur, Christophe

doi:10.1002/anie.200804880

Reference : Isoprene-assisted radical coupling of (co)polymers prepared by cobalt-mediated radica...


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/6545

Title :	Isoprene-assisted radical coupling of (co)polymers prepared by cobalt-mediated radical polymerization
Language :	English
Author, co-author :	Debuigne, Antoine [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Christine [Université de Liège - ULiège > Deopartment of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Detrembleur, Christophe [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	9-Feb-2009
Journal title :	Angewandte Chemie (International ed. in English)
Publisher :	Wiley-VCH Verlag Gmbh
Volume :	48
Issue/season :	8
Pages :	1422-1424
Peer reviewed :	Yes (verified by ORBi)
Audience :	International
ISSN :	1433-7851
e-ISSN :	1521-3773
City :	Weinheim
Country :	Germany
Keywords :	[en] radical ; cobalt-mediated radical polymerization (CMRP) ; Isoprene-Assisted Radical Coupling of polymers (I-ARC)
Abstract :	[en] The isoprene-assisted radical coupling (I-ARC) of polymers prepared by cobalt-mediated radical polymerization (see picture) is the first efficient radical coupling method that is not restricted to short chains. When applied to AB diblock copolymers, I-ARC constitutes a straightforward approach to the preparation of novel symmetrical ABA triblock copolymers
Research centres :	Center for Education and Research on Macromolecules (CERM)
Funders :	Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/6545
DOI :	10.1002/anie.200804880
Other URL :	http://www3.interscience.wiley.com/cgi-bin/fulltext/121637751/PDFSTART

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