Dispersion Atom Transfer Radical Polymerization of vinyl monomers in supercritical carbon dioxide

Grignard, Bruno; Jérôme, Christine; Calberg, Cédric; Jérôme, Robert; Wang, Wenxin; Howdle, Steven M; Detrembleur, Christophe

doi:10.1021/ma801474s

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Article (Scientific journals)

Dispersion Atom Transfer Radical Polymerization of vinyl monomers in supercritical carbon dioxide

Grignard, Bruno; Jérôme, Christine; Calberg, Cédric et al.

2008 • In Macromolecules, 41 (22), p. 8575-8563

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/5741

DOI
10.1021/ma801474s

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Keywords :

green technology; supercritical carbon dioxide; radical polymerization; atom transfer radical polymerization (ATRP)

Abstract :

[en] Controlled dispersion atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was successfully carried out in supercritical carbon dioxide in the presence of aminated fluoropolymers. These materials played the dual role of macroligand for the copper bromide and also steric stabilizer to support formation of polymer microspheres. The livingness of the PMMA beads was confirmed by the one-pot two-step PMMA chain extension and the synthesis of poly(methyl methacrylate)-b-poly(2,2,2-trifluoroethyl methacrylate) (PMMA-b-PFMA) diblock copolymer in scCO2. Successful activator generated by electron transfer (AGET) for ATRP of MMA, using tin ethylhexanoate as a reducing agent, is also discussed, and the concept of dispersion ATRP of MMA was successfully extended to the controlled dispersion polymerization of styrene by ATRP leading to the formation of PS microparticles. Finally, due to the high solubility of the catalyst in scCO2, the purification of PMMA was investigated by supercritical fluid extraction, leading to the preparation of PMMA beads with low residual catalyst traces.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Calberg, Cédric ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Wang, Wenxin; UniVersity of Nottingham, School of Chemistry, UK

Howdle, Steven M; UniVersity of Nottingham, School of Chemistry, UK

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Dispersion Atom Transfer Radical Polymerization of vinyl monomers in supercritical carbon dioxide

Publication date :

25 November 2008

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

Issue :

Pages :

8575-8563

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma801474s

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE]
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
The Région Wallone in the frame of the Corronet project

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