Improvement of the barrier properties of Nafion® by fluoro-modified montmorillonite

Thomassin, Jean-Michel; Pagnoulle, Christophe; Bizzari, Didier; Caldarella, Giuseppe; Germain, Albert; Jérôme, Robert

doi:10.1016/j.ssi.2006.04.023

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Article (Scientific journals)

Improvement of the barrier properties of Nafion® by fluoro-modified montmorillonite

Thomassin, Jean-Michel; Pagnoulle, Christophe; Bizzari, Didier et al.

2006 • In Solid State Ionics, 177 (13-14), p. 1137-1144

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/5477

DOI
10.1016/j.ssi.2006.04.023

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Keywords :

nanostructured material; nanocomposite; clay; fuel cell

Abstract :

[en] Montmorillonite (MMT) was modified by two types of cationic fluorosurfactants in order to improve compatibility with and dispersion within Nafion® membranes. Perfluoropolyether-containing cationic surfactant improved efficiency, by improving the barrier properties of Nafion® towards methanol. Moreover, the fluoro-modified MMT had no deleterious impact on the ionic conductivity of the membranes in contrast to conventional organo-modified MMT. The performances of a small size fuel cell were accordingly improved.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Thomassin, Jean-Michel ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Pagnoulle, Christophe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Bizzari, Didier; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry

Caldarella, Giuseppe ; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry

Germain, Albert ; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Improvement of the barrier properties of Nafion® by fluoro-modified montmorillonite

Publication date :

May 2006

Journal title :

Solid State Ionics

ISSN :

0167-2738

Publisher :

Elsevier Science, Amsterdam, Netherlands

Volume :

177

Issue :

13-14

Pages :

1137-1144

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TY4-4K7NHF0-4-16&_cdi=5608&_user=532038&_orig=browse&_coverDate=05%2F31%2F2006&_sk=998229986&view=c&wchp=dGLbVlW-zSkzk&md5=4f304420cdd97912df24643057e15e91&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/505677/description

Funders :

Région wallonne
BELSPO - Service Public Fédéral de Programmation Politique scientifique

Funding text :

CERM is grateful to the Région Wallonne for financial support in the frame of the NANOCELL program. It is also indebted to the “Belgian Science Policy” for financial support in the frame of the “Interuniversity Attraction Poles Programme (PAI V/03)”.

Commentary :

The authors acknowledge Solid State Ionics (Elsevier) for allowing them to archive this paper.

Available on ORBi :

since 02 February 2009

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Bibliography

Giannelis E.P. Adv. Mater. 8 (1996) 29
Choi H.J., Kim S.G., Hyun Y.H., and Jhon M.S. (25). Macromol. Rapid Commun. 22 (2001) 320
Riva A., Zanetti M., Braglia M., and Camino G. Polym. Degrad. Stab. 77 (2002) 299
LeBaron P.C., Wang Z., and Pinnavaia T.J. Appl. Clay Sci. 15 (1999) 11
Vaia R.A., Price G., Ruth P.N., Nguyen H.T., and Lichtenhan J. Appl. Clay Sci. 15 (1999) 67
Choi Y.S., Choi M.H., Wang K.H., Kim S.O., Kim Y.K., and Chung I.J. Macrmolecules 34 (2001) 8978
Fischer H.R., Gielgens L.H., and Koster T.P. Acta Polym. 50 (1999) 122
Bharadwaj R.K. Macromolecules 34 (2001) 9189
Messersmith P.B., and Giannelis E.P. J. Polym. Sci., A 33 (1995) 1047
Yano K., Usuki A., Okada A., Kurauchi T., and Kamigaito O. J. Polym. Sci., A 31 (1993) 2493
Yano K., Usuki A., and Okada A. J. Polym. Sci., A 35 (1997) 2289
Xie W., Gao Z., Pan W.P., Hunter D., Singh A., and Vaia R. Chem. Mater. 13 (2001) 2979
Gilman J.W. Appl. Clay Sci. 15 (1999) 31
Tien Y.I., and Wei K.H. Macromolecules 34 (2001) 9045
Yao K.J., Song M., Hourston D.J., and Luo D.Z. Polymer 43 (2002) 1017
Wang Z., and Pinnavaia T.J. Chem. Mater. 10 (1998) 3769
Yano K., Usuki A., Okada A., Kurauchi T., and Kamigato O. J. Polym. Sci., A 31 (1993) 2493
Fu X., and Qutubuddin S. Polymer 42 (2001) 807
Wu J., Lin J., Li G., and Wie C. Pol. Int. 50 (2001) 1050
Yu Y.H., Lin C.Y., Yeh J.M., and Lin W.H. Polymer 44 (2003) 3553
Strawhecker K.E., and Manias E. Chem. Mater. 12 (2000) 2943
Ogata N., Kawakage S., and Ogihara T. J. Appl. Polym. Sci. 66 (1997) 573
Thomassin J.M., Pagnoulle C., Bizzarri D., Caldarella G., Germain A., and Jerome R. e-Polymer 018 (2004)
Tricoli V., Carretta N., and Bartolozzi M. J. Electrochem. Soc. 147 (2000) 1286