Beneficial effect of carbon nanotubes on the performances of Nafion membranes in fuel cell applications

Thomassin, Jean-Michel; Kollar, Jozef; Caldarella, Giuseppe; Germain, Albert; Jérôme, Robert; Detrembleur, Christophe

doi:10.1016/j.memsci.2007.07.019

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Beneficial effect of carbon nanotubes on the performances of Nafion membranes in fuel cell applications

Thomassin, Jean-Michel; Kollar, Jozef; Caldarella, Giuseppe et al.

2007 • In Journal of Membrane Science, 303 (1-2), p. 252-257

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https://hdl.handle.net/2268/5081

DOI
10.1016/j.memsci.2007.07.019

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Keywords :

greeen technology; green energy; fuel cell; carbon nanotube

Abstract :

[en] Multi-walled carbon nanotubes (MWCNTs) were dispersed by melt-extrusion within Nafion(R) membranes in order to decrease the methanol permeability without deleterious effect on the ionic conductivity. The risk of short-circuits was minimized by keeping the carbon nanotubes content lower than the percolation threshold. Two series of carbon nanotubes grafted by carboxylic acid groups were used, i.e., commercially available carbon nanotubes and MWCNTs home-grafted by carboxylic acid containing alkyl radicals. The second series of nanotubes were more resistant to break-up during melt-processing. Methanol permeability was decreased by approximately 60% without any decrease in the ionic conductivity. In parallel, the Young's modulus was increased by 140% and 160% as compared to pure Nafion(R) at MWCNT contents of 1 and 2 wt%, respectively.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemical engineering
Materials science & engineering
Chemistry

Author, co-author :

Thomassin, Jean-Michel ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Kollar, Jozef; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Caldarella, Giuseppe ; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry

Germain, Albert ; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Beneficial effect of carbon nanotubes on the performances of Nafion membranes in fuel cell applications

Publication date :

15 October 2007

Journal title :

Journal of Membrane Science

ISSN :

0376-7388

eISSN :

1873-3123

Publisher :

Elsevier Science Bv, Amsterdam, Netherlands

Volume :

303

Issue :

1-2

Pages :

252-257

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TGK-4P77837-5-1&_cdi=5257&_user=532038&_orig=browse&_coverDate=10%2F15%2F2007&_sk=996969998&view=c&wchp=dGLzVzz-zSkzV&md5=93c0a58fcc35ed48ab4df8254d4f936f&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/502692/description#description

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
The Région wallonne in the frame of the “Pile à combustible” program INNOPILE

Commentary :

The authors acknowledge Journal of Membrane Science (Elsevier) for allowing them to archive this paper.

Available on ORBi :

since 29 January 2009

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