[en] Mechanical and thermal properties of SBS thermoplastic elastomers, in which S stands for polystyrene and B for polybutadiene, can be remarkably improved through end-capping by syndiotactic poly(methyl methacrylate) sequences. Furthermore, the upper service temperature of these sPMMA teleblock copolymers can also be enhanced by blending with isotactic PMMA so that the rubbery PBD soft segments are connected to high-melting stereocomplexed hard segments. The factors which affect the mechanical and thermal properties of these novel thermoplastic elastomers have been extensively investigated.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Yu, Yisong; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Dubois, Philippe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Difunctional initiator based on 1,3-diisopropenylbenzene. 7. Mechanical and thermal properties of new butadiene-based thermoplastic elastomers
Publication date :
November 1997
Journal title :
Rubber Chemistry and Technology
ISSN :
0035-9475
Publisher :
Amer Chemical Soc Inc, Akron, United States - Ohio
Volume :
70
Issue :
5
Pages :
820-838
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique Shell
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