Analysis of living tert-butyl methacrylate oligoanions in tetrahydrofuran by NMR spectroscopy, viscosity and light scattering

Zune, Catherine; Dubois, Philippe; Grandjean, Jean; Jérôme, Robert

doi:10.1002/(SICI)1521-3935(19990301)200:3<562::AID-MACP562>3.0.CO;2-4

Article (Scientific journals)

Analysis of living tert-butyl methacrylate oligoanions in tetrahydrofuran by NMR spectroscopy, viscosity and light scattering

Zune, Catherine; Dubois, Philippe; Grandjean, Jean et al.

1999 • In Macromolecular Chemistry and Physics, 200 (3), p. 562-573

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4484

DOI
10.1002/(SICI)1521-3935(19990301)200:3<562::AID-MACP562>3.0.CO;2-4

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Keywords :

anionic polymerization

Abstract :

[en] Previous kinetic studies concluded on the aggregation of the anionic chain ends of living tert-butyl methacrylate oligomers [PtBMA-, Li+] in THF at low temperature. This aggregation has been confirmed by viscosimetry, light scattering and gradient field NMR techniques in a range of temperature from 253 K to 298 K. These techniques have been systematically used for the analysis of both the living oligomers and the same chains recovered after hydrolysis of the anionic end groups. The structure of the growing anionic species was analyzed by means of 13C and 7Li NMR spectroscopy. 13C NMR required the selective labeling of the last monomer units by 13C atoms.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Zune, Catherine; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Dubois, Philippe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Grandjean, Jean ; Université de Liège - ULiège > Department of Chemistry > Chimie organique et spectroscopie multinucléaire (COSM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Analysis of living tert-butyl methacrylate oligoanions in tetrahydrofuran by NMR spectroscopy, viscosity and light scattering

Publication date :

March 1999

Journal title :

Macromolecular Chemistry and Physics

ISSN :

1022-1352

eISSN :

1521-3935

Publisher :

Wiley-V C H Verlag Gmbh, Weinheim, Germany

Volume :

200

Issue :

Pages :

562-573

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/45000275/PDFSTART

Available on ORBi :

since 22 January 2009

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