Analysis of living tert-butyl methacrylate oligoanions in tetrahydrofuran by NMR spectroscopy, viscosity and light scattering

Zune, Catherine; Dubois, Philippe; Grandjean, Jean; Jérôme, Robert

doi:10.1002/(SICI)1521-3935(19990301)200:3<562::AID-MACP562>3.0.CO;2-4

Article (Scientific journals)

Analysis of living tert-butyl methacrylate oligoanions in tetrahydrofuran by NMR spectroscopy, viscosity and light scattering

Zune, Catherine; Dubois, Philippe; Grandjean, Jean et al.

1999 • In Macromolecular Chemistry and Physics, 200 (3), p. 562-573

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/2268/4484

DOI
10.1002/(SICI)1521-3935(19990301)200:3<562::AID-MACP562>3.0.CO;2-4

Files (2)Send to Details Statistics Bibliography Similar publications

Files

Full Text

Zune C 1999 Macromol Chem Phys 562.pdf

Publisher postprint (156.84 kB)

Request a copy

Full Text Parts

Zune_C_1999_Macromol chem phys_200_3_562.pdf

Author postprint (241.52 kB)

Request a copy

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

anionic polymerization

Abstract :

[en] Previous kinetic studies concluded on the aggregation of the anionic chain ends of living tert-butyl methacrylate oligomers [PtBMA-, Li+] in THF at low temperature. This aggregation has been confirmed by viscosimetry, light scattering and gradient field NMR techniques in a range of temperature from 253 K to 298 K. These techniques have been systematically used for the analysis of both the living oligomers and the same chains recovered after hydrolysis of the anionic end groups. The structure of the growing anionic species was analyzed by means of 13C and 7Li NMR spectroscopy. 13C NMR required the selective labeling of the last monomer units by 13C atoms.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Zune, Catherine; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Dubois, Philippe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Grandjean, Jean ; Université de Liège - ULiège > Department of Chemistry > Chimie organique et spectroscopie multinucléaire (COSM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Analysis of living tert-butyl methacrylate oligoanions in tetrahydrofuran by NMR spectroscopy, viscosity and light scattering

Publication date :

March 1999

Journal title :

Macromolecular Chemistry and Physics

ISSN :

1022-1352

eISSN :

1521-3935

Publisher :

Wiley-V C H Verlag Gmbh, Weinheim, Germany

Volume :

200

Issue :

Pages :

562-573

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/45000275/PDFSTART

Available on ORBi :

since 22 January 2009

Statistics

Number of views

81 (8 by ULiège)

Number of downloads

1 (1 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

Bibliography

J-S. Wang, R. Jérôme, Ph. Teyssié, J. Phys. Org. Chem. 8, 208 (1995)
D. G. H. Ballard, R. J. Bowles, D. M. Haddleton, S. N. Richards, R. Sellens, D. L. Twose, Macromolecules 25, 5907 (1992)
O. W. Webster, W. R. Hertler, D. Y. Sogah, W. B. Farham, T. V. R. Babu, J. Am. Chem. Soc. 105, 5706 (1983)
M. Kato, M. Kamigaito, M. Sawamoto, T. Higashimura, Macromolecules 28, 1721 (1995)
a) W. Fowells, C. Schuerch, F. A. Bovey, F. P. Hood, J. Am. Chem. Soc. 89, 1396 (1967);
b) R. Volge, T. E. Hogen-Esch, Macromolecules 23, 4196 (1990)
a) L. Vancea, S. Bywater, Macromolecules 14, 1776 (1981);
b) D. J. Worsfold, S. Bywater, Macromolecules 5, 393 (1972)
a) L. Lochmann, J. Trekoval, Makromol. Chem. 183, 1361 (1982);
b) C. B. Tsvetanov, D. T. Dastschewa, I. M. Petrova, R. Panayotov, Makromol. Chem. 183, 517 (1982)
a) A. H. E. Müller, Makromol. Chem., Macromol. Symp. 32, 87 (1990);
b) A. H. E. Müller, in: "Recent Advances in Anionic Polymerization", T. E. Hogen-Esch and J. Smid, Eds., Elsevier, New-York 1987, p. 205;
c) A. H. E. Müller, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 32, 301 (1991)
a) L. Lochmann, M. Janata, L. Machova, P. Vleck, T. Mitera, A. H. E. Müller, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2, 29 (1988);
b) M. Janata, L. Lochmann, P. Vleck, J. Dybal, A. H. E. Müller, Makromol.Chem. 193, 101 (1992);
c) C. B. Tsvetanov, A. H. E. Müller, G. V. Schulz, Macromolecules 18, 863 (1985)
a) K. Hatada, T. Kitayama, K. Fujikawa, K. Ohta, H. Yuki, in Anionic Polymerization: kinetics, mechanism and synthesis. ACS Symposium series 166, J. E. McGrath, Ed., Washington DC 1981 p. 327
J. Kriz, J. Dybal, M. Janata, P. Vleck, Magn. Res. Chem. 32, S8-S12 (1994)
J-S. Wang, R. Jérôme, R. Warin, Ph. Teyssié, Macromolecules 26, 6776 (1993)
J-S. Wang, R. Jérôme, R. Warin, Ph. Teyssié, Macromolecules 27, 1691 (1994)
J-S. Wang, R. Jérôme, R. Warin, Ph. Teyssié, Macromolecules 27, 3376 (1994)
J-S. Wang, R. Jérôme, R. Warin, Ph. Teyssié, Macromolecules 26, 1402 (1993)
J. Kriz, J. Dybal, L. Lochmann, M. Janata, P. Vleck, Macromol. Chem. Phys. 196, 3005 (1995)
a) J. Kriz, P. Vleck, M. Janata, Macromol. Chem. Phys. 195, 3039 (1994);
b) J. Kriz, J. Dybal, M. Janata, P. Vleck, Macromol. Chem. Phys. 196, 3117 (1995)
a) L. M. Jackman, C. W. Debrosse, J. Am. Chem. Soc. 105, 4177 (1983);
b) L. M. Jackman, E. F. Rahiewicz, A. J. Benesi, J. Am. Chem. Soc. 113, 4101 (1991)
H. Schaald, A. H. E. Müller, H. Kalshorn, Macromol. Rapid Commun. 10, 517 (1994)
S. K. Varshney, Z. Gao, X. F. Zhong, A. Eisenberg, Macromolecules 27, 1076 (1994)
J-S. Wang, H. Zhang, R. Jérôme, Ph. Teyssié, Macromolecules 28, 1738 (1995)
J-S. Wang, R. Jérôme, R. Warin, Ph. Teyssié, Macromolecules 26, 5984 (1993)
G. Gilman, J. Organomet. Chem. 2, 447 (1964)
T. Werkhoven, J. Lugtenburg, J. Labelled Comp. Radiopharm, to be submitted
J. A. Pople, W. G. Schneider, H. J. Bernstein, in: High Resolution Nuclear Magnetic Resonance; H. Mc Graw, Ed., NewYork 1959
a) P. Stilbs, Prog. NMR Spectrosc. 19, 1 (1987);
b) R. L. Haner, T. Schleich, Methods Enzymol. 176, 418 (1989)
P. Vanhoorne, R. Jérôme, Macromolecules 28, 5664 (1995)
a) M. Janata, L. Lochmann, D. Kunkel, A. H. E. Müller, Makromol. Chem. Macromol. Symp. 60, 315 (1992);
b) A. H. E. Müller, Makromol. Chem. 182, 2863 (1981)
A. H. E. Müller, in: Anionic Polymerization: kinetics, mechanism and synthesis, ACS Symposium series 166, J. E. McGrath, Ed., Washington DC 1981 p. 441-461
N. Ropson, Ph. Dubois, R. Jérôme, Ph. Teyssié Macromolecules 27, 5950 (1994)
A. Hernandez, J. Semel, H. C. Broeker, H. Gerhord, H. S. Zachmann, Makromol. Chem., Rapid. Commun. 1, 105 (1980)
W. Burchard, Makromol. Chem., Macromol. Symp. 39, 179 (1990)
a) E. D. Meerwall, Adv. Polym. Sci. 54, 1 (1983);
b) M. Appel, G. Fleisher, J. Kärger, A-C. Dieng, G. Riess, Macromolecules 28, 2345 (1995)
V. V. Krishnan, J. Magn. Reson. 124, 468 (1997)
T. E. Long, R. D. Allen, J. E. McGrath, Recent advances in mechanistic and synthetic aspects of polymerization, in: NATO ASI series C, M. Fontanille and A. Guyot, Eds. Boston, Klumer 1987, p. 79-100
M. Lin, C. K. Larive, Anal. Biochem. 229, 214 (1995)
C. Zune, Ph. Dubois, R. Jérôme, J. Kriz, J. Dybal, L. Lochmann, P. Vlcek, M. Janata, T. Werhoven, J. Lugtenburg, Macromolecules 31, 2731 (1998)