The in situ formation of a new initiator system for the syndiotactic anionic polymerization of methyl methacrylate in toluene at 0°C

Zundel, Thomas; Teyssié, Philippe; Jérôme, Robert

doi:10.1016/S0032-3861(02)00462-7

Article (Scientific journals)

The in situ formation of a new initiator system for the syndiotactic anionic polymerization of methyl methacrylate in toluene at 0°C

Zundel, Thomas; Teyssié, Philippe; Jérôme, Robert

2002 • In Polymer, 43 (25), p. 7191-7193

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4450

DOI
10.1016/S0032-3861(02)00462-7

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Keywords :

anionic polymerization

Abstract :

[en] This paper reports on an efficient 'in-situ' one pot synthesis of an initiatior/ligand adduct, which can be used to initiate the anionic polymerization of methyl methacrylate in toluene at 0 °C. Predominantly syndiotactic PMMA is formed.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Zundel, Thomas; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

The in situ formation of a new initiator system for the syndiotactic anionic polymerization of methyl methacrylate in toluene at 0°C

Publication date :

December 2002

Journal title :

Polymer

ISSN :

0032-3861

eISSN :

1873-2291

Publisher :

Elsevier Sci Ltd, Oxford, United Kingdom

Volume :

Issue :

Pages :

7191-7193

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TXW-472RP49-28-J&_cdi=5601&_user=532038&_orig=browse&_coverDate=12%2F31%2F2002&_sk=999569974&view=c&wchp=dGLbVzW-zSkWA&md5=0e367685e7af8832b22d920a1347e778&ie=/sdarticle.pdf

Funders :

Elf Atochem
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

Commentary :

The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.

Available on ORBi :

since 21 January 2009

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