Anionic polymerization of methacrylic monomers: characterization of the propagating species

[en] Ligation of the anionic species responsible for the polymerization (LAP) of alkyl(meth)acrylates has much contributed to improve polymerization control. This ligated anionic polymerization has been firstly studied by using model compounds, such as low molecular weight lithium ester enolates. Recently, effort has been devoted to the direct analysis of the species that propagate the anionic polymerization of (meth)acrylates. In addition to IR, multinuclear NMR spectroscopy has been very instrumental in the elucidation of the structure and aggregation of the active species and how these characteristic features are modified by the addition of various types of ligands. This substantial progress in the characterization of the polyalkyl(meth)acrylate anions, ligated or not, is reported in this review.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Zune, Catherine; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Anionic polymerization of methacrylic monomers: characterization of the propagating species

Publication date :

August 1999

Journal title :

Progress in Polymer Science

ISSN :

0079-6700

Publisher :

Pergamon (Elsevier)

Volume :

Issue :

Pages :

631-664

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TX2-3X6B7NS-1-1&_cdi=5578&_user=532038&_orig=browse&_coverDate=08%2F31%2F1999&_sk=999759994&view=c&wchp=dGLbVtz-zSkzk&md5=aa1aef5f14f2b04b9665c2ea5bfbb959&ie=/sdarticle.pdf

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]

Commentary :

The authors acknowledge Progress in Polymer Science (Elsevier) for allowing them to archive this paper.

Available on ORBi :

since 21 January 2009

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