[en] Cathodic electrografting of poly(2-chloropropionate ethyl acrylate) (poly[cPEA]) onto steel followed by the styrene grafting-from by atom transfer radical polymerization (ATRP) is an efficient strategy to impart strong adhesion to polystyrene films onto the electrically conductive substrate. Electrografting of poly(cPEA) chains at an appropriate potential and persistence of the activated chloride in the grafted chains were confirmed by XPS. Polystyrene deposition by ATRP with a ruthenium-based catalyst was analyzed by scanning electron microscopy and Raman spectroscopy. Adhesion of the polystyrene layer to the substrate is so strong that it cannot be detached by standard Scotch brand tapes. Moreover, local thermal analysis showed a loss of mobility for the PS chains tethered at the surface.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Author, co-author :
Claes, Michaël; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Voccia, Samuel; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Gilbert, Bernard ; Université de Liège - ULiège > Department of Chemistry > Laboratory of Analytical Chemistry and Electrochemistry
Leclère, Philippe; University of Mons-Hainaut > Chemistry of New Materials Department
Geskin, Victor; Université de Liège - ULiège > Laboratory of Analytical Chemistry and Electrochemistry
Gouttebaron, Rachel; University of Mons-Hainaut (UMH) > Service de Chimie Inorganique et Analytique (LASSIE)
Hecq, Michel; University of Mons-Hainaut > Service de Chimie Inorganique et Analytique (LASSIE)
Lazzaroni, Roberto; University of Mons-Hainaut (UMH) > Chemistry of New Materials Department
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Polymer coating of steel by a combination of electrografting and atom-transfer radical polymerization
Publication date :
12 August 2003
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
Amer Chemical Soc, Washington, United States - Washington
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture CE - Commission Européenne FEDER - Fonds Européen de Développement Régional Région wallonne
Kariuki, J.; McDermott, T. Langmuir 1999, 15, 6534.
Tanguy, J.; Deniau, G.; Augé, C.; Zalczer, G.; Leoayon, G. J. Electroanal. Chem. 1904, 377, 115.
Baute, N.; Teyssié, P.; Martinot, L.; Mertens, M.; Dubois, P.; Jéróme, R.; Eur. J. Inorg. Chem. 1998, 1711. Baute, N.; Calberg, C.; Dubois, P.; Jérôme, C.; Jérôme, R.; Martinot, L.; Mertens, M.; Teyssié, P. Macromol. Symp. 1998, 134, 157.
Baute, N.; Teyssié, P.; Martinot, L.; Mertens, M.; Dubois, P.; Jéróme, R.; Eur. J. Inorg. Chem. 1998, 1711. Baute, N.; Calberg, C.; Dubois, P.; Jérôme, C.; Jérôme, R.; Martinot, L.; Mertens, M.; Teyssié, P. Macromol. Symp. 1998, 134, 157.
Delamar, M.; Désarmot, G.; Fagebaume, O.; Hitmi, R.; Pinson, J.; Savéant, J. M. Carbon 1997, 35, 801.
Yuan, W.; Iroh, J. O. Trends Polym. Sci. 1993, 1, 388.
Baute, N.; Martinot, L.; Jérôme, R. J. Electroanal. Chem. 1999, 472, 8.
Detrembleur, C.; Jérôme, C.; Claes, M.; Louette, P.; Jérôme, R. Angew. Chem., Int. Ed. Engl. 2001, 40, 1268-1271.
Schwab, P.; France, M.; Ziller, J.; Grubbs, R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2039.
Voccia, S.; Jérôme, C.; Detrembleur, C.; Gouttebaron, R.; Hecq, M.; Gilbert, B.; Jérôme, R. Chem. Mater., in press.
Matyjaszewski, K.; Patten, T. E. Adv. Mater. 1998, 10, 12.
Moad, G.; Solomon, D. H. The Chemistry of Free Radical Polymerization; Pergamon: Oxford, England, 1995.
Matyjaszewski, K. J. Macromol. Sci. Pure Appl. Chem., 1994, A31, 989.
Curran, D. P. Synthesis 1988, 489.
Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614.
Mertens, M.; Calberg, C.; Martinot, L.; Jérôme, R. Macro-molecules 1996, 29, 4910.
Mertens, M.; Calberg, C.; Baute, N.; Jérôme, R.; Martinot, L. J. Electroanal. Chem. 1998, 441, 237.
Jérôme, C.; Geskin, V.; Lazzaroni, R.; Bredas, J. L.; Thibaut, A.; Calberg, C.; Bodart, L; Mertens, M.; Martinot, L.; Rodrigue, D.; Riga, J.; Jérôme, R. Chem. Mater. 2001, 13, 1656-1664.
Jeyaprakash, J. D.; Samuel, S.; Dhamodharan, R.; Rühe, J. Macromol. Rapid Commun. 2002, 23, 277. Zhao, B.; Brittain, W. J. Prog. Polym. Sci. 2000, 25, 677.
Jeyaprakash, J. D.; Samuel, S.; Dhamodharan, R.; Rühe, J. Macromol. Rapid Commun. 2002, 23, 277. Zhao, B.; Brittain, W. J. Prog. Polym. Sci. 2000, 25, 677.
Simal, F.; Delaude, L.; Jan, D.; Demonceau, A.; Noels, A. F. Polymer Preprint 1999, 40, 336.
Simal, F.; Demonceau, A.; Noels, A. F. Tetrahedron Lett. 1999, 40, 5689.
Simal, F.; Demonceau, A.; Noels, A. F. Angew. Chem., Int. Ed. 1999, 38, 4.
Song, M.; Hammiche, A.; Pollock, H. M.; Hourston, D. J.; Reading, M. Polymer 1995, 36, 3313. Song, M.; Hourston, D. J.; Reading, M.; Hammiche, A.; Pollock, H. M. Polymer 1998, 37, 243. Reading, M.; Hourston, D. J.; Song, M.; Pollock, H. M.; Hammiche, A. Am. Lab. 1998, Jan., 13. Price, D.; Reading, M.; Hammiche, A.; Pollock, H. M. Int. J. Pharm. 1999, 192, 85.
Song, M.; Hammiche, A.; Pollock, H. M.; Hourston, D. J.; Reading, M. Polymer 1995, 36, 3313. Song, M.; Hourston, D. J.; Reading, M.; Hammiche, A.; Pollock, H. M. Polymer 1998, 37, 243. Reading, M.; Hourston, D. J.; Song, M.; Pollock, H. M.; Hammiche, A. Am. Lab. 1998, Jan., 13. Price, D.; Reading, M.; Hammiche, A.; Pollock, H. M. Int. J. Pharm. 1999, 192, 85.
Song, M.; Hammiche, A.; Pollock, H. M.; Hourston, D. J.; Reading, M. Polymer 1995, 36, 3313. Song, M.; Hourston, D. J.; Reading, M.; Hammiche, A.; Pollock, H. M. Polymer 1998, 37, 243. Reading, M.; Hourston, D. J.; Song, M.; Pollock, H. M.; Hammiche, A. Am. Lab. 1998, Jan., 13. Price, D.; Reading, M.; Hammiche, A.; Pollock, H. M. Int. J. Pharm. 1999, 192, 85.
Song, M.; Hammiche, A.; Pollock, H. M.; Hourston, D. J.; Reading, M. Polymer 1995, 36, 3313. Song, M.; Hourston, D. J.; Reading, M.; Hammiche, A.; Pollock, H. M. Polymer 1998, 37, 243. Reading, M.; Hourston, D. J.; Song, M.; Pollock, H. M.; Hammiche, A. Am. Lab. 1998, Jan., 13. Price, D.; Reading, M.; Hammiche, A.; Pollock, H. M. Int. J. Pharm. 1999, 192, 85.
Keddie, J. L.; Jones, R. A. L.; Cory, R. A. Faraday Discuss. 1994, 98, 219.
Nielsen, L.; Laudel, R. Mechanical Properties of Polymers and Composites, 2nd ed.; M. Dekker: New York, 1994; p 20.
