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Article (Scientific journals)
Combination of ring-opening polymerization and "click" chemistry towards functionalization of aliphatic polyesters
Riva, Raphaël; Schmeits, Stephanie; Stoffelbach, François et al.
2005 • In Chemical Communications, (42), p. 5334-5336
Peer Reviewed verified by ORBi
Permalink
https://hdl.handle.net/2268/4203
DOI
10.1039/b510282k
PubMed
16244746
 

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Keywords :
ring-opening polymerization; lactone; click chemistry; copper-mediated Huisgen's cycloaddition; polymer functionalization
Abstract :
[en] Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 degrees C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Riva, Raphaël ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Schmeits, Stephanie ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Stoffelbach, François;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Lecomte, Philippe  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Combination of ring-opening polymerization and "click" chemistry towards functionalization of aliphatic polyesters
Publication date :
14 November 2005
Journal title :
Chemical Communications
ISSN :
1359-7345
eISSN :
1364-548X
Publisher :
Royal Society of Chemistry
Issue :
42
Pages :
5334-5336
Peer reviewed :
Peer Reviewed verified by ORBi
Additional URL :
http://www.rsc.org/ej/CC/2005/b510282k.pdf
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture
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since 14 January 2009

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