Control of the radical polymerization of tert-butyl methacrylate in water by a novel combination of sodium nitrite and iron(II) sulfate

Detrembleur, Christophe; Teyssié, Philippe; Jérôme, Robert

doi:10.1021/ma011368z

Article (Scientific journals)

Control of the radical polymerization of tert-butyl methacrylate in water by a novel combination of sodium nitrite and iron(II) sulfate

Detrembleur, Christophe; Teyssié, Philippe; Jérôme, Robert

2002 • In Macromolecules, 35 (5), p. 1611-1621

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4123

DOI
10.1021/ma011368z

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Keywords :

radical polymerization; nitroxide-mediated polymerization (NMP)

Abstract :

[en] Addition of iron(II) sulfate to sodium nitrite is a new way to control the radical polymerization of tert-butyl methacrylate (tBMA) in water at 80 degreesC. Nitric oxide is released in the reaction medium as result of the reduction of sodium nitrite by FeSO4. This reaction is of utmost importance because three repeated additions of an alkyl radical to nitric oxide leads to the formation of nitroxide radicals. The basic mechanism for the control of the radical polymerization is thus a nitroxide-mediated process.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Control of the radical polymerization of tert-butyl methacrylate in water by a novel combination of sodium nitrite and iron(II) sulfate

Publication date :

26 February 2002

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - District of Columbia

Volume :

Issue :

Pages :

1611-1621

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma011368z

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

Available on ORBi :

since 13 January 2009

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