Synthesis of poly(vinyl acetate)-b-polystyrene and poly(vinyl alcohol)-b-polystyrene copolymers by cobalt-mediated radical polymerization

Bryaskova, Rayna; Willet, Nicolas; Debuigne, Antoine; Jérôme, Robert; Detrembleur, Christophe

doi:10.1002/pola.21806

Article (Scientific journals)

Synthesis of poly(vinyl acetate)-b-polystyrene and poly(vinyl alcohol)-b-polystyrene copolymers by cobalt-mediated radical polymerization

Bryaskova, Rayna; Willet, Nicolas; Debuigne, Antoine et al.

2007 • In Journal of Polymer Science. Part A, Polymer Chemistry, 45 (1), p. 81-89

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4096

DOI
10.1002/pola.21806

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP); block copolymers

Abstract :

[en] Well-defined poly(vinyl acetate) macroinitiators, with the chains thus end-capped by a cobalt complex, were synthesized by cobalt-mediated radical polymerization and used to initiate styrene polymerization at 30 degrees C. Although the polymerization of the second block was not controlled, poly(vinyl acetate)-b-polystyrene copolymers were successfully prepared and converted into amphiphilic poly(vinyl alcohol)-b-polystyrene copolymers by the methanolysis of the ester functions of the poly(vinyl acetate) block. These poly(vinyl alcohol)-b-polystyrene copolymers self-associated in water with the formation of nanocups, at least when the poly(vinyl alcohol) content was low enough.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Bryaskova, Rayna ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Willet, Nicolas ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Depmartment of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Synthesis of poly(vinyl acetate)-b-polystyrene and poly(vinyl alcohol)-b-polystyrene copolymers by cobalt-mediated radical polymerization

Publication date :

01 January 2007

Journal title :

Journal of Polymer Science. Part A, Polymer Chemistry

ISSN :

0887-624X

eISSN :

1099-0518

Publisher :

Wiley, Hoboken, United States - New Jersey

Volume :

Issue :

Pages :

81-89

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/113453449/PDFSTART

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Available on ORBi :

since 13 January 2009

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