Synthesis of end-functional poly(vinyl acetate) by cobalt-mediated radical polymerization

Debuigne, Antoine; Caille, Jean-Raphaël; Jérôme, Robert

doi:10.1021/ma047726q

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Article (Scientific journals)

Synthesis of end-functional poly(vinyl acetate) by cobalt-mediated radical polymerization

Debuigne, Antoine; Caille, Jean-Raphaël; Jérôme, Robert

2005 • In Macromolecules, 38 (13), p. 5452-5458

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https://hdl.handle.net/2268/4063

DOI
10.1021/ma047726q

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP)

Abstract :

[en] Poly(vinyl acetate) (PVAc) chains prepared by cobalt-mediated radical polymerization in the presence of cobalt(II) acetylacetonate (Co(acac)(2)) were quenched by radical scavengers, such as thiol compounds and nitroxides, to displace the covalently bonded Co(acac)(2) moiety and to end-cap them with a reactive group. The cobalt complex was completely removed by filtration, as confirmed by the induction coupled plasma (ICP) analysis of the polymer before and after treatment. Growing poly(vinyl acetate) chains can be end-functionalized either by addition of an appropriately functionalized nonpolymerizable olefin or by displacement of the Co(acac)(2) moiety by a functionalized nitroxide. This strategy allows PVAc to be synthesized with a predictable molecular weight, a reasonably low polydispersity (M-w/M-n similar to 1.1-1.3), and a functional omega end group, e.g., hydroxyl and epoxy.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Caille, Jean-Raphaël; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Synthesis of end-functional poly(vinyl acetate) by cobalt-mediated radical polymerization

Publication date :

28 June 2005

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

5452-5458

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma047726q

Funders :

Solvay sa
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

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