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Article (Scientific journals)
Two-step backbiting reaction in the ring-opening polymerization of gamma-acryloyloxy-epsilon-caprolactone initiated with aluminium isopropoxide
Lou, Xudong; Detrembleur, Christophe; Lecomte, Philippe et al.
2002 • In Macromolecular Rapid Communications, 23 (2), p. 126-129
Peer Reviewed verified by ORBi
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https://hdl.handle.net/2268/3679
DOI
10.1002/1521-3927(20020101)23:2<126::AID-MARC126>3.0.CO;2-T
 

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Keywords :
ring-opening polymerization (ROP); lactone
Abstract :
[en] gamma-Acryloyloxyethyl-gamma-butyrolactone is formed as a byproduct when the polymerization of gamma-acryloyloxy-epsilon-caprolactone is initiated with aluminium isopropoxide in toluene. The extent of this side reaction decreases with decreasing temperature and is dependent on whether the reaction is stopped as soon as monomer conversion is complete or not. A two-step backbiting mechanism is proposed for this intramolecular transesterification reaction.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Lou, Xudong;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Lecomte, Philippe  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Two-step backbiting reaction in the ring-opening polymerization of gamma-acryloyloxy-epsilon-caprolactone initiated with aluminium isopropoxide
Publication date :
31 January 2002
Journal title :
Macromolecular Rapid Communications
ISSN :
1022-1336
eISSN :
1521-3927
Publisher :
Wiley-V C H Verlag Gmbh, Weinheim, Germany
Volume :
23
Issue :
2
Pages :
126-129
Peer reviewed :
Peer Reviewed verified by ORBi
Additional URL :
http://www3.interscience.wiley.com/cgi-bin/fulltext/89016668/PDFSTART
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
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since 06 January 2009

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