Article (Scientific journals)
Détermination de la Structure Cristalline et de la Configuration Absolue du Bromhydrate d'Usambarensine
Dideberg, Otto; Dupont, Léon; Angenot, Luc
1975In Acta Crystallographica. Section B, Structural Crystallography and Crystal Chemistry, B31 (6), p. 1571-1575
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Keywords :
Usambarensine Hydrobromide; Strychnos usambarensis; X-Ray diffraction; Absolute configuration
Abstract :
[en] Usambarensine is a bisindolinic alkaloid found in the bark of Strychnos usambarensis roots. The crystal and molecular structure of usambarensine.2HBr.2H2O has been solved by direct methods thanks to a Hilger-Watts four-circle diffractometer. The crystals are monoclinic; refinement of the parameters was carried out with 2459 reflexions. The absolute configuration of the molecule, determined by X-ray anomalous scattering, confirms the 3 alpha cis configuration ( 11alpha cis, IUPAC) assigned earlier by spectral, chromatographic and biogenetic data.This configuration seems dependent on the presence of an ethylidenic chain in the corynane part of the molecule.
Disciplines :
Pharmacy, pharmacology & toxicology
Physics
Author, co-author :
Dideberg, Otto
Dupont, Léon
Angenot, Luc  ;  Université de Liège - ULiège > Département de pharmacie > Pharmacognosie
Language :
French
Title :
Détermination de la Structure Cristalline et de la Configuration Absolue du Bromhydrate d'Usambarensine
Alternative titles :
[en] Crystal Structure and Absolute Configuration of Usambarensine Hydrobromide
Publication date :
1975
Journal title :
Acta Crystallographica. Section B, Structural Crystallography and Crystal Chemistry
ISSN :
0567-7408
Publisher :
Munksgaard International Publishers, Copenhagen, Denmark
Volume :
B31
Issue :
6
Pages :
1571-1575
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 17 May 2010

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