Article (Scientific journals)
An X-ray scattering technique for characterizing Mercury’s carbon enrichments with BepiColombo
Fox, Adam R D; Martindale, Adrian; Barry, Tiffany L et al.
2026In RAS Techniques and Instruments, 5
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Keywords :
BepiColombo; Carbon; Data Methods; Low Reflectance Material; MIXS; X-ray Scattering; Astronomy and Astrophysics; Engineering (miscellaneous); Earth and Planetary Sciences (miscellaneous); Artificial Intelligence
Abstract :
[en] Spatially resolved observations of carbon abundances on Mercury’s surface are of great scientific importance for the origin and evolution of volatile elements and for the planet’s reflectance properties, notably for Mercury’s Low Reflectance Material (LRM) and with broader impacts for constraining Mercury’s history. However, such measurements are extremely challenging, even with BepiColombo’s state-of-the-art instrument suite. To overcome the issues with direct measurement, we have created an entirely new, indirect method for characterizing localized carbon enrichments on Mercury with the Mercury Imaging X-ray Spectrometer (MIXS). Elevated abundances of low atomic number elements increase the spectral intensity of scattered, high-energy X-rays (8–10 keV). This provides a proxy for graphite enrichment, which is the currently preferred hypothesis for the dominant darkening phase in the LRM. We report experimental X-ray measurements, including scattered X-rays and XRF, for a library of reference materials and graphite-spiked samples of varying abundances using the MIXS Ground Reference Facility. By modelling the results using established theory and data bases of X-ray fundamental parameters, we validate the method and enable reliable extrapolation to future MIXS observations. Using modelled solar flares, fitted to solar X-ray observations from the MESSENGER mission, we estimate that integration times of hundreds of seconds during intense flares can resolve increases in scatter intensity created by various expected carbon abundances. Through detailed analysis we find that it may be possible to place an upper bound on graphite content on localized scales, strengthening the scientific rationale for dedicated ‘stare’ observations of LRM-rich regions during BepiColombo’s extended mission.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Fox, Adam R D ;  School of Physics and Astronomy, University of Leicester, Space Park Leicester, Leicester, United Kingdom
Martindale, Adrian ;  School of Physics and Astronomy, University of Leicester, Leicester, United Kingdom
Barry, Tiffany L;  School of Geography, Geology and the Environment, University of Leicester, Leicester, United Kingdom
Lindsay, Simon T ;  School of Physics and Astronomy, University of Leicester, Leicester, United Kingdom
Charlier, Bernard  ;  Université de Liège - ULiège > Département de géologie > Pétrologie, géochimie endogènes et pétrophysique
Namur, Olivier;  Department of Earth and Environmental Sciences, KU Leuven, Leuven, Belgium
Hall, Graeme P ;  School of Physics and Astronomy, University of Leicester, Leicester, United Kingdom
Bunce, Emma J;  School of Physics and Astronomy, University of Leicester, Leicester, United Kingdom ; Institute for Space, University of Leicester, Leicester, United Kingdom
Bridges, John C;  School of Physics and Astronomy, University of Leicester, Space Park Leicester, Leicester, United Kingdom
Cartwright, Julia A ;  School of Physics and Astronomy, University of Leicester, Leicester, United Kingdom ; Institute for Space, University of Leicester, Leicester, United Kingdom
Tikkanen, Tuomo;  School of Physics and Astronomy, University of Leicester, Leicester, United Kingdom
Language :
English
Title :
An X-ray scattering technique for characterizing Mercury’s carbon enrichments with BepiColombo
Publication date :
2026
Journal title :
RAS Techniques and Instruments
eISSN :
2752-8200
Publisher :
Oxford University Press
Volume :
5
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
UKSA - UK Space Agency
University of Leicester
STFC - Science and Technology Facilities Council
ESA - European Space Agency
ERC - European Research Council
EU - European Union
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since 29 May 2026

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