Transforming Environmental Waste into Valuable Resources: Characterization of Clayey Sludge from Aggregate Quarries for Sustainable Traditional Ceramics - 2026
Transforming Environmental Waste into Valuable Resources: Characterization of Clayey Sludge from Aggregate Quarries for Sustainable Traditional Ceramics
Zahir, Safaa; Daoudi, Lahcen; El Ouahabi, Meriamet al.
green ceramic; industrial waste; pottery; recycling; valorization; Chemical compositions; Clayey materials; Environmental wastes; Green ceramic; Mineralogical compositions; Particles-size distributions; Pottery; Resource characterizations; Traditional ceramics; Valorisation; Geochemistry and Petrology
Abstract :
[en] The clayey sludge resulting from aggregate washing in quarries in the Marrakech region generates significant environmental impacts and adds an economic burden to the industry. This study aims to characterize these clayey sludges to explore their potential for ceramic applications. Fifteen samples were collected from various quarries along the major waterways of the Marrakech region. The physical properties of the clayey materials were analyzed through particle size distribution and plasticity limits. The mineralogical composition was characterized using X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). The chemical composition was determined through X-ray fluorescence (XRF). The amounts of carbonates and volatiles were determined by calcimetry and loss on ignition at 500°C and 950°C, respectively. The results revealed SiO. and Al.O. as dominant oxides, with quartz, feldspars, and clay minerals as the main phases, along with minor amounts of calcite and hematite. Illite is the dominant clay mineral, followed by kaolinite and chlorite. These clayey material exhibits low to medium plasticity and variable particle size distributions. The chemical composition of these sludges confirms their potential for red ceramic applications. However, their low plasticity, variable particle size distribution, and mineralogical composition, characterized by a low clay mineral content, limit their direct applicability. To improve their suitability for ceramic production, adding clay-rich materials is essential to enhance their mineralogical composition, granulometry, and plasticity. Furthermore, the results provide a valuable guide for selecting local materials for Marrakech pottery and can serve as a model for other regions.
Research Center/Unit :
Geology - ULiège
Disciplines :
Earth sciences & physical geography
Author, co-author :
Zahir, Safaa; Georesources, Geoenvironment and Civil Engineering Laboratory (L3G), Faculty of Science and Technology, Cadi Ayyad University, Marrakech, Morocco
Daoudi, Lahcen; Georesources, Geoenvironment and Civil Engineering Laboratory (L3G), Faculty of Science and Technology, Cadi Ayyad University, Marrakech, Morocco
El Ouahabi, Meriam ; Université de Liège - ULiège > Département de géologie > Argiles, géochimie et environnements sédimentaires
Fagel, Nathalie ; Université de Liège - ULiège > Département de géologie > Argiles, géochimie et environnements sédimentaires
Language :
English
Title :
Transforming Environmental Waste into Valuable Resources: Characterization of Clayey Sludge from Aggregate Quarries for Sustainable Traditional Ceramics
El Aallaoui A., Elghali A., Hakkou R., Taha Y., Benzaazoua M. & Ghorfi M. El. (2025) 3D geometallurgical characterization of coal mine waste rock piles for their reprocessing purpose. International Journal of Coal Science and Technology, 12, 16.
AFNOR. (1993) NF P 94-051 - Détermination des limites d’Atterberg limite de liquidité à la coupelle - Limite de plasticité au rouleau.
AFNOR. (1995) NF P94-052-1 -Détermination des limites d’Atterberg - Partie 1: limite de liquidité - Méthode du cône de pénétration.
April R.H., Hluchy M.M. & Newton R.M. (1986) The nature of vermiculite in Adirondack soils and till. Clays & Clay Minerals, 34, 549–556.
Avram S.E., Birle B.V., Tudoran L.B., Borodi G. & Petean and I. (2024a) Investigation of Used Water Sediments from Ceramic Tile Fabrication. water, 16, 1027.
Avram S.E., Tudoran L.B., Cuc S., Borodi G., Birle B.V. & Petean I. (2024b) Natural Fiber Reinforcement of Ceramic Slurry Compacts. Journal of Composite Science, 8, 542.
Avram S.E., Birle B.V., Cosma C., Tudoran L.B., Moldovan M., Cuc S., Borodi G. & Petean I. (2025a) Ecological Building Material Obtained Through the Moderate Thermal Consolidation of Ceramic Slurry Collected from Industrial Waste Waters. Materials 2025, 18,1715, 1–22.
Avram S.E., Tudoran L.B., Borodi G., Filip M.R. & Petean I. (2025b) Urban Traffic’ s Influence on Noise and Particulate Matter Pollution. Sustainability, 17, 2077.
Aydinalp C. (2010) Some important properties and classification of vertisols under mediterranean climate. African Journal of Agricultural Research, 5, 449–452.
Baccour H., Medhioub M., Jamoussi F. & Mhiri T. (2009) Influence of firing temperature on the ceramic properties of Triassic clays from Tunisia. Journal of Materials Processing Technology, 209, 2812–2817.
Bain J.A. & Highley D.E. (1979) Regional appraisal of clay resources - A challenge to the clay mineralogist. Pp. 437–446 in: Developments in Sedimentology (M.M. Mortland & V.C. Farmer, editors). Elsevier, London, UK.
Bennour A., Mahmoudi S., Srasra E., Hatira N., Boussen S., Ouaja M. & Zargouni F. (2015) Identification and traditional ceramic application of clays from the Chouamekh region in south-eastern Tunisia. Applied Clay Science, 118, 212–220. Elsevier B.V.
Boski T., Pessoa J., Pedro P., Thorez J., Dias J.M.A. & Hall I.R. (1998) Factors governing abundance of hydrolyzable amino acids in the sediments from the N.W. European Continental Margin (47-50°N). Progress in Oceanography, 42, 145–164.
El Boudour El Idrissi H., Daoudi L., El Ouahabi M., Balo Madi A., Collin F. & Fagel N. (2016) Suitability of soils and river deposits from Marrakech for the manufacturing of earthenware. Applied Clay Science, 129, 108–115. Elsevier B.V.
El Boudour El Idrissi H., Daoudi L., El Ouahabi M., Collin F. & Fagel N. (2018) The influence of clay composition and lithology on the industrial potential of earthenware. Construction and Building Materials, 172, 650–659. Elsevier Ltd.
El Boudour El Idrissi H., Borja W., Fagel N. & Daoudi L. (2021) Simple approach to elaborate test bricks for traditional ceramic studies. Engineering Archive engrxiv.
Boussen S., Sghaier D., Chaabani F., Jamoussi B. & Bennour A. (2016) Characteristics and industrial application of the Lower Cretaceous clay deposits (Bouhedma Formation), Southeast Tunisia: Potential use for the manufacturing of ceramic tiles and bricks. Applied Clay Science, 123, 210–221. Elsevier B.V.
Carretero M.I., Dondi M., Fabbri B. & Raimondo M. (2002) The influence of shaping and firing technology on ceramic properties of calcareous and non-calcareous illitic-chloritic clays. Applied Clay Science, 20, 301–306.
Castellanos H.G., Aryanfar Y., Keçebaş A., Assad M.E.H., Islam S., Naveed Q.N. & Lasisi A. (2024) A new paradigm for mining energy from industrial sludge: A low-cost fuel. Journal of Water Process Engineering, 59, 2214–7144.
Cook H.E., Johnson P.D., Matti J.C. & Zemmels I. (1975) Methods of sample preparation and x-ray difraction data analysis. Institute of Geophysic and Planetary Physics.
Daoudi L., Hicham E.E., Latifa S., Abderrahmane A., Jamal B., Mohamed W., Meriam E. & Nathalie F. (2014) Characteristics and ceramic properties of clayey materials from Amezmiz region (Western High Atlas, Morocco). Applied Clay Science, 102, 139–147. Elsevier B.V.
Daoudi L., Knidiri A., El Boudour El Idrissi H., Rhouta B. & Fagel N. (2015) Role of the texture of fibrous clay minerals in the plasticity behavior of host materials (Plateau du Kik, Western High Atlas, Morocco). Applied Clay Science, 118, 283–289. Elsevier B.V.
Dondi M., Raimondo M. & Zanelli C. (2014) Clays and bodies for ceramic tiles: Reappraisal and technological classification. Applied Clay Science, 96, 91–109. Elsevier B.V.
Fatah T.A., Zhang R., Huang X., Zheng J., Miao Y. & Mastoi A.K. (2021) Strength and leaching behavior of contaminated mining sludge at high water content stabilized with lime activated ggbs. Materials, 14, 6524.
Ferrari S. & Gualtieri A.F. (2006) The use of illitic clays in the production of stoneware tile ceramics. Applied Clay Science, 32, 73–81.
Fiori C., Fabbri B., Donati G. & Venturi I. (1989) Mineralogical composition of the clay bodies used in the Italian tile industry. Applied Clay Science, 4, 461–473.
Galetakis M., Alevizos G. & Leventakis K. (2012) Evaluation of fine limestone quarry byproducts, for the production of building elements - An experimental approach. Construction and Building Materials, 26, 122–130. Elsevier Ltd.
Garrouri S., Lakhal W., Benazzouk A. & Sediki E. (2022) Potential use of Alfa fibers in construction material: Physico-mechanical and thermal characterisation of reinforced specimen. Construction and Building Materials, 342, 127787. Elsevier Ltd.
Garzón E., Sánchez-Soto P.J. & Romero E. (2010) Physical and geotechnical properties of clay phyllites. Applied Clay Science, 48, 307–318. Elsevier B.V.
González-Corrochano B., Alonso-Azcárate J. & Rodas M. (2009) Characterization of lightweight aggregates manufactured from washing aggregate sludge and fly ash. Resources, Conservation and Recycling, 53, 571–581.
Gourfi A., Daoudi L., Rhoujjati A., Benkaddour A. & Fagel N. (2020) Use of bathymetry and clay mineralogy of reservoir sediment to reconstruct the recent changes in sediment yields from a mountain catchment in the Western High Atlas region, Morocco. Catena, 191.
Gourfi A., Daoudi L., Daoud N. Ben & Fagel N. (2023) Clay minerals in soils and sediment as tracers of provenance: The case study of the N’fis watershed, Morocco. Soil Use and Management, 40, 1–20.
Gugliotta M., Saito Y., Ta T.K.O., Nguyen V.L., Uehara K., Tamura T., Nakashima R. & Lieu K.P. (2020) Sediment distribution along the fluvial to marine transition zone of the Dong Nai River System, southern Vietnam. Marine Geology, 429, 106314. Elsevier.
Haida S., Snoussi M., Latouche C. & Probst J.L. (1996) Géodynamique actuelle du bassin versant de l’Oued Tensift (Maroc): érosion mécanique et bilan des transports solides fluviaux. / Present geodynamic of the Tensift drainage basin (Morocco): mechanical erosion and fluvial transports of sediments. Sciences Géologiques. Bulletin, 49, 7–23.
Hajhouji Y. (2018) Modélisation hydrologique du bassin versant de l’oued Rheraya et sa contribution à la recharge de la nappe du Haouz (bassin du Tensift, Maroc). UNIVERSITÉ DE TOULOUSE.
Haut Commissariat au Plan. (2020) Monographie Regionale Region De Marrakech – Safi Annee 2018. 1–125 pp.
Heiri O., Lotter A. & Lemcke G. (2001) Loss on ignition as a method for estimating organic and carbonate content in sediments. Journal of Paleolimnology, 25, 101–110.
Holtz R.D. & Kovacs W.D. (1981) An Introduction to Geotechnical Engineering. P. in.: 1st editio. Prentice-Hall, Inc., Englewood Cliffs, 733 pp.
Holtzapffel T. (1985) les mineraux argileux. Préparation. Analyse diffractométrique et détermination. P. in: Société Géologique Du Nord. 12.
Khalfaoui A. & Hajjaji M. (2009) A Chloritic-illitic clay from Morocco: Temperature-time-transformation and neoformation. Applied Clay Science, 45, 83–89. Elsevier B.V.
El Khalki E.M., Tramblay Y., Amengual A., Homar V., Romero R., Saidi M.E.M. & Alaou M. (2020) Validation of the AROME, ALADIN and WRF meteorological models for flood forecasting in Morocco. Water, 12, 437.
Kłosek-Wawrzyn E., Łój G., Bugaj A. & Wons W. (2019) Waste sludge from washing dolomite aggregates as a raw material for brick production. Gospodarka Surowcami Mineralnymi - Mineral Resources Management, 35, 37–48.
Knidiri A., Daoudi L., El Ouahabi M., Rhouta B., Rocha F. & Fagel N. (2014) Palaeogeographic controls on palygorskite occurrence in Maastrichtian-Palaeogene sediments of the Western High Atlas and Meseta Basins (Morocco). Clay Minerals, 49, 595–608.
Kologrieva U., Volkov A., Krasnyanskaya I., Stulov P. & Wainstein D. (2022) Analysis of Hydrometallurgical Methods for Obtaining Vanadium Concentrates from the Waste by Chemical Production of Vanadium Pentoxide. Materials, 15.
Kreimeyer R. (1987) Some notes on the firing colour of clay bricks. Applied Clay Science, 2, 175–183.
Laita E. & Bauluz B. (2018) Mineral and textural transformations in aluminium-rich clays during ceramic firing. Applied Clay Science, 152, 284–294. Elsevier.
Lee V.G. & Yeh T.H. (2008) Sintering effects on the development of mechanical properties of fired clay ceramics. Materials Science and Engineering: A, 485, 5–13.
Loutou M., Hakkou R., Argane R., Mansori M., Grase L., Svinka R. & Mezinskis G. (2018) Clayey Quarry Sludges: Thermal Transformation, Microstructure and Technological Properties. Waste and Biomass Valorization, 9, 1805–1815. Springer Netherlands.
Low P.F. (1980) The Swelling of Clay: II. Montmorillonites 1. Soil science society of america journal, 44, 667–676.
Luo C., Deng Y., Inubushi K., Liang J., Zhu S., Wei Z., Guo X. & Luo X. (2018) Sludge biochar amendment and alfalfa revegetation improve soil physicochemical properties and increase diversity of soil microbes in soils from a rare earth element mining wasteland. International Journal of Environmental Research and Public Health, 15.
Maalla I., Boussen S., Fagel N. & Mohamed Essghaier G. (2021) Incorporation of siliceous sand and lignite tailings from Miocene deposits (Zeramdine, Eastern Tunisia) in clay bricks and ceramic tiles: technological feasibility. Arabian Journal of Geosciences, 14. Arabian Journal of Geosciences.
Madejova J. (2003) FTIR techniques in clay mineral studies. Vibrational Spectroscopy, 31, 1–10.
Magalhães C.P., Alves J.I., Duber A., Oleskowicz-Popiel P., Stams A.J.M. & Cavaleiro A.J. (2024) Metabolic versatility of anaerobic sludge towards platform chemical production from waste glycerol. Applied Microbiology and Biotechnology, 108. Springer Berlin Heidelberg.
Maletsika P.A., Nanos G.D. & Stavroulakis G.G. (2015) Peach leaf responses to soil and cement dust pollution. Environmental Science and Pollution Research, 22, 15952–15960.
Martínez-García C., Eliche-Quesada D., Pérez-Villarejo L., Iglesias-Godino F.J. & Corpas-Iglesias F.A. (2012) Sludge valorization from wastewater treatment plant to its application on the ceramic industry. Journal of Environmental Management, 95, S343–S348. Elsevier Ltd.
Maston O., Maston O., Ouahbi T., Taibi S., El A. & Sapin L. (2025) Effect of MICP treatment on the mechanical properties of clay soils Transportation Geotechnics Effect of MICP treatment on the mechanical properties of clay soils. Transportation Geotechnics, 50, 101483. Elsevier Ltd.
McManus J. (1988) Grain size distribution and interpretation. Pp. 63–85 in: Techniques in Sedimentology (M.E. Tucker, editor). Blackwell Scientific Publications, Oxford.
Mercantili L., Davis F. & Higson S.P.J. (2013) Ultrasonic Initiation of the Alkaline Hydrolysis of Triglycerides (Saponification) Without Phase Catalysis. Journal of Surfactants and Detergents, 16, 337–344.
Michard A., Saddiqi O., Chalouan A. & Frizon de Lamotte D. (2008) Continental Evolution: The Geology of Morocco Structure, Stratigraphy, and Tectonics of the Africa-Atlantic-Mediterranean Triple Junction. P. in: Lecture Notes in Earth Sciences.
Miliani P. & Corbara F. (1999) Tecnologıa, Ceramica – Le Materie Prime. P. in.: Gruppo Editoriale Faenza Editrice, Faenza, italy, 97 pp.
Ministère de l’Equipement du Transport et de la Logistique. (2016) Grands chantiers et réformes 2012-2016. 141 pp.
Ministère de l’équipement et du Transport. (2012) Inventaire des carrières. 165 pp.
Moore D.M. & Reynolds J.R. (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals. P. in: Oxford University Press. New York, 378 pp.
Murray H.H. (2007) Applied clay mineralogy: occurrences, processing and applications of kaolins, bentonites, palygorskitesepiolite, and common clays. P. in.: Elsevier, Amsterdam, 473 pp.
Nandi V. de S., Zaccaron A., Raupp-Pereira F., Arcaro S., Bernardin A.M. & Montedo O.R.K. (2023) Plastic behaviour of clay materials for the manufacture of fast-drying red ceramics. Clay Minerals, 58, 26–37.
El Ouahabi M., Daoudi L., Hatert F. & Fagel N. (2015) Modified mineral phases during clay ceramic firing. Clays and Clay Minerals, 63, 404–413.
El Ouahabi M., El Boudour El Idrissi H., Daoudi L., El Halim M. & Fagel N. (2019) Moroccan clay deposits: Physico-chemical properties in view of provenance studies on ancient ceramics. Applied Clay Science, 172, 65–74. Elsevier.
Rahou J., Rezqi H., El Ouahabi M. & Fagel N. (2022) Characterization of Moroccan steel slag waste: The potential green resource for ceramic production. Construction and Building Materials, 314, 125663. Elsevier Ltd.
Sadek H.E.H., Hessien M.A., Abd El-Shakour Z.A., Taha M.A. & Khattab R.M. (2021) The effect of sintering on the properties of magnesia-granite sludge ceramics shaped by temperature-induced forming. Journal of Materials Research and Technology, 11, 264–273. Elsevier Ltd.
Saidi M.E., Daoudi L., Aresmouk M.E. hassane & Blali A. (2003) Rôle du milieu physique dans l’amplification des crues en milieu montagnard: exemple de la crue du 17 août 1995 dans la vallée de l’Ourika (Haut-Atlas, Maroc). Secheresse, 14, 107–114.
Saikia N.J., Bharali D.J., Sengupta P., Bordoloi D., Goswamee R.L., Saikia P.C. & Borthakur P.C. (2003) Characterization, beneficiation and utilization of a kaolinite clay from Assam, India. Applied Clay Science, 24, 93–103.
Shepard F.P. (1954) Nomenclature Based on Sand-silt-clay Ratios. Journal of Sedimentary Petrology, 14, 256–259.
Sridharan A. & Choudhury D. (2002) Swelling pressure of sodium montmorillonites. Geotechnique, 52, 459–462.
Strazzera B., Dondi M. & Marsigli M. (1997) Composition and ceramic properties of Tertiary clays from southern Sardinia (Italy). Applied Clay Science, 12, 247–266.
Tarte P. (1967) Infra-red spectra of inorganic aluminates and characteristic vibrational frequencies of AlO tetrahedra and AlOs octahedra. Spectrochim. Acta Part A Mol. Spectrosc., 23, 2127–2143.
Thorez J. (1976) Practical identification of Clay minerals. P. 90 in: (G. Lelotte, editor). Institute of Mineralogy, Liège State University, Liége.
Tomanec R., Popov S., Vučinič D. & Lazič P. (1997) Vermiculite From Kopaonik (Yugoslavia) Characterization and Processing. Fizykochemiczne Problemy Mineralurgii, 31, 247–254.
Trindade M.J., Dias M.I., Coroado J. & Rocha F. (2009) Mineralogical transformations of calcareous rich clays with firing: A comparative study between calcite and dolomite rich clays from Algarve, Portugal. Applied Clay Science, 42, 345–355. Elsevier B.V.
Trindade M.J., Dias M.I., Coroado J. & Rocha F. (2010) Firing tests on clay-rich raw materials from the algarve basin (Southern Portugal): Study of mineral transformations with temperature. Clays and Clay Minerals, 58, 188–204.
Unuabonah E.I., Gu C., Weber J., Lubahn S. & Taubert A. (2013) Hybrid Clay: A New Highly E ffi cient Adsorbent for Water Treatment. ACS Sustainable Chemistry & Engineering.
Vashistha P., Kumar V., Singh S.K., Dutt D., Tomar G. & Yadav P. (2019) Valorization of paper mill lime sludge via application in building construction materials: A review. Construction and Building Materials, 211, 371–382. Elsevier Ltd.
Veerasingam S. & Venkatachalapathy R. (2014) Estimation of carbonate concentration and characterization of marine sediments by Fourier Transform Infrared Spectroscopy. Infrared Physics & Technology, 66, 136–140. Elsevier B.V.
Wang S., Pan C., Xie D., Xu M., Yan Y. & Li X. (2022) Grain size characteristics of surface sediment and its response to the dynamic sedimentary environment in Qiantang Estuary, China. International Journal of Sediment Research, 37, 457–468.
Zajec L., Gradinjan D., Klančnik K. & Gaberščik A. (2016) Limestone dust alters the optical properties and traits of Fagus sylvatica leaves. Trees - Structure and Function, 30, 2143–2152.
Zia-Khan S., Spreer W., Pengnian Y., Zhao X., Othmanli H., He X. & Müller J. (2015) Effect of dust deposition on stomatal conductance and leaf temperature of cotton in Northwest China. Water, 7, 116–131.