antiferromagnetic; bismuth ferrite; first‐principles calculations; multiferroics; second harmonic generation; strain manipulation; Antiferromagnetics; Biaxial strains; Bismuth ferrites; Ferroics; First principle calculations; Harmonics generation; Rotational anisotropy; Second harmonics; Medicine (miscellaneous); Chemical Engineering (all); Materials Science (all); Biochemistry, Genetics and Molecular Biology (miscellaneous); Engineering (all); Physics and Astronomy (all)
Abstract :
[en] Continuous strain engineering of multiferroics not only enhances understanding of their properties but also guides the optimization of their performances for use in electronic, optical, and magnetic devices. However, due to technical challenges in real-time monitoring of the ferroic orders, the precise evolution process remains unclear. Here, the evolution of the ferroelectric (FE) and antiferromagnetic (AFM) orders are revealed in multiferroic freestanding BiFeO3 films under sequential and anisotropic biaxial strain, using rotational anisotropy second harmonic generation (RA-SHG) technology and first-principles calculations. The change and recovery of RA-SHG patterns illustrate the reversible control of the in-plane FE polarization in the films by sequential strain application. The in-plane FE direction can be manipulated within ≈4° by strain along the (100) and (010) directions, while the AFM order is more significantly affected, with ≈8° rotation in RA-SHG patterns. This research unveils the appearance of new SHG peaks in freestanding BFO films under strain and shows that they evolve independently of FE-induced SHG linked to lattice changes, suggesting a spin structure-related variation. This work paves a new way for studying of strain-manipulated 2D multiferroics and highlights the promise of freestanding perovskite films as low-dimensional multifunctional devices.
Disciplines :
Physics
Author, co-author :
Wang, Jiesu ; Beijing Academy of Quantum Information Sciences, Beijing, 100193, China
Xu, Shuai ; Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China
Meyer, Sebastian ; Université de Liège - ULiège > Département de physique > Topological Orders in Matter (TOM)
Wu, Shiyao; Beijing Academy of Quantum Information Sciences, Beijing, 100193, China
Bandyopadhyay, Subhadeep ; Université de Liège - ULiège > Département de physique > Physique théorique des matériaux
He, Xu ; Université de Liège - ULiège > Département de physique > Physique théorique des matériaux
Miao, Qiyuan; Beijing Academy of Quantum Information Sciences, Beijing, 100193, China ; Institute of Ultrafast Optical Physics, Department of Applied Physics and MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing, Nanjing University of Science and Technology, Nanjing, 210094, China
Huang, Sisi; Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China
Li, Pengzhan; Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China
Zhao, Kun; Institute of Ultrafast Optical Physics, Department of Applied Physics and MIIT Key Laboratory of Semiconductor Microstructure and Quantum Sensing, Nanjing University of Science and Technology, Nanjing, 210094, China
Guo, Er-Jia ; Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China ; University of Chinese Academy of Sciences, Beijing, 100049, China
Ge, Chen ; Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China ; University of Chinese Academy of Sciences, Beijing, 100049, China
Dupé, Bertrand ; Université de Liège - ULiège > Département de physique > Topological Orders in Matter (TOM)
Ghosez, Philippe ; Université de Liège - ULiège > Département de physique > Physique théorique des matériaux
Chang, Kai ; Beijing Academy of Quantum Information Sciences, Beijing, 100193, China
Jin, Kuijuan ; Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190, China ; University of Chinese Academy of Sciences, Beijing, 100049, China
NSCF - National Natural Science Foundation of China Chinese Academy of Sciences China Postdoctoral Science Foundation F.R.S.-FNRS - Fonds de la Recherche Scientifique
Funding text :
This work is supported by the National Natural Science Foundation of China (Grant Nos. 12104054, 12404033, 12074038, 92165104, 11974390, 12222414, 12204237, and 12074416), the Beijing Natural Science Foundation (Grant No. 1222035), the National Key Basic Research Program of China (Grant Nos. 2019YFA0308500, 2020YFA0309100, and 2021YFA1400701), the Strategic Priority Research Program (B) of the Chinese Academy of Sciences (Grant No. XDB33030200), the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. Y2022003), Beijing Municipal Science & Technology Commission (Grant No. Z221100002722013), and Innovation Program for Quantum Science and Technology (2023ZD0300500), the Natural Science Foundation of Jiangsu Province (Grant No. BK20220922), the China Postdoctoral Innovative Talent Support Program (Grant No. BX20240409), and the China Postdoctoral Science Foundation (Grant No. 2024M763507). S.B, X.H, and Ph.G acknowledge the support from F.R.S.-FNRS through the PDR Grants PROMOSPAN (T.0107.20), and the computational resources from the CECI supercomputer facilities funded by the F.R.S-FNRS (Grant No. 2.5020.1) and the Tier-1 supercomputer of the Federation Wallonie-Bruxelles funded by the Walloon Region (Grant No. 1117545). S.M. is a Postdoctoral Researcher (CR) of the Fonds de la Recherche Scientifique-FNRS (F.R.S.-FNRS No. CR 1.B.324.24F). B.D. is a Research Associate (CQ) of the Fonds de la Recherche Scientifique-FNRS (F.R.S.\u2013FNRS).This work is supported by the National Natural Science Foundation of China (Grant Nos. 12104054, 12404033, 12074038, 92165104, 11974390, 12222414, 12204237, and 12074416), the Beijing Natural Science Foundation (Grant No. 1222035), the National Key Basic Research Program of China (Grant Nos. 2019YFA0308500, 2020YFA0309100, and 2021YFA1400701), the Strategic Priority Research Program (B) of the Chinese Academy of Sciences (Grant No. XDB33030200), the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant No. Y2022003), Beijing Municipal Science & Technology Commission (Grant No. Z221100002722013), and Innovation Program for Quantum Science and Technology (2023ZD0300500), the Natural Science Foundation of Jiangsu Province (Grant No. BK20220922), the China Postdoctoral Innovative Talent Support Program (Grant No. BX20240409), and the China Postdoctoral Science Foundation (Grant No. 2024M763507). S.B, X.H, and Ph.G acknowledge the support from F.R.S.\u2010FNRS through the PDR Grants PROMOSPAN (T.0107.20), and the computational resources from the CECI supercomputer facilities funded by the F.R.S\u2010FNRS (Grant No. 2.5020.1) and the Tier\u20101 supercomputer of the Federation Wallonie\u2010Bruxelles funded by the Walloon Region (Grant No. 1117545). S.M. is a Postdoctoral Researcher (CR) of the Fonds de la Recherche Scientifique\u2010FNRS (F.R.S.\u2010FNRS No. CR 1.B.324.24F). B.D. is a Research Associate (CQ) of the Fonds de la Recherche Scientifique\u2010FNRS (F.R.S.\u2013FNRS).
M. Ramazanoglu, M. Laver, W. Ratcliff II, S. M. Watson, W. C. Chen, A. Jackson, K. Kothapalli, S. Lee, S.-W. Cheong, V. Kiryukhin, Phys. Rev. Lett. 2011, 107, 207206.
J. T. Heron, J. L. Bosse, Q. He, Y. Gao, M. Trassin, L. Ye, J. D. Clarkson, C. Wang, J. Liu, S. Salahuddin, D. C. Ralph, D. G. Schlom, J. Íñiguez, B. D. Huey, R. Ramesh, Nature 2014, 516, 370.
Z. Chen, Z. Chen, C. Y. Kuo, Y. Tang, L. R. Dedon, Q. Li, L. Zhang, C. Klewe, Y. L. Huang, B. Prasad, A. Farhan, M. Yang, J. D. Clarkson, S. Das, S. Manipatruni, A. Tanaka, P. Shafer, E. Arenholz, A. Scholl, Y. H. Chu, Z. Q. Qiu, Z. Hu, L. H. Tjeng, R. Ramesh, L. W. Wang, L. W. Martin, Nat. Commun. 2018, 9, 3764.
T. Zhao, A. Scholl, F. Zavaliche, K. Lee, M. Barry, A. Doran, M. P. Cruz, Y. H. Chu, C. Ederer, N. A. Spaldin, R. R. Das, D. M. Kim, S. H. Baek, C. B. Eom, R. Ramesh, Nat. Mater. 2006, 5, 823.
J. Wang, J. B. Neaton, H. Zheng, V. Nagarajan, S. B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D. G. Schlom, U. V. Waghmare, N. A. Spaldin, K. M. Rabe, M. Wuttig, R. Ramesh, Science 2003, 299, 1719.
Y. H. Chu, L. W. Martin, M. B. Holcomb, M. Gajek, S. J. Han, Q. He, N. Balke, C. H. Yang, D. Lee, W. Hu, Q. Zhan, P. L. Yang, A. Fraile-Rodríguez, A. Scholl, S. X. Wang, R. Ramesh, Nat. Mater. 2008, 7, 478.
S. Xu, J. S. Wang, P. Chen, K. J. Jin, C. Ma, S. Y. Wu, E. J. Guo, C. Ge, C. Wang, X. L. Xu, H. Yao, J. Y. Wang, D. Xie, X. Wang, K. Chang, X. D. Bai, G. Z. Yang, Nat. Commun. 2023, 14, 2274.
S. L. Tian, C. Wang, Y. Zhou, X. M. Li, P. Gao, J. S. Wang, Y. Feng, X. K. Yao, C. Ge, M. He, X. D. Bai, G. Z. Yang, K. J. Jin, ACS Appl. Mater. Interfaces 2018, 10, 43792.
H. Shima, H. Naganuma, T. Iijima, T. Nakajima, S. Okamura, Integr. Ferroelectr. 2009, 106, 11.
B. Kundys, M. Viret, D. Colson, D. Kundys, Nat. Mater. 2010, 9, 803.
D. Lebeugle, D. Colson, A. Forget, M. Viret, A. M. Bataille, A. Gukasov, Phys. Rev. Lett. 2008, 100, 227602.
D. Sando, A. Barthélémy, M. Bibes, J. Phys.: Condens. Matter 2014, 26, 473201.
A. Agbelele, D. Sando, C. Toulouse, C. Paillard, R. D. Johnson, R. Rüffer, A. F. Popkov, C. Carrétéro, P. Rovillain, J. M. L. Breton, B. Dkhil, M. Cazayous, Y. Gallais, M. A. Méasson, A. Sacuto, P. Manuel, A. K. Zvezdin, A. Barthélémy, J. Juraszek, M. Bibes, Adv. Mater. 2016, 29, 1602327.
Y. Zhang, Y. Wang, J. Qi, Y. Tian, M. Sun, J. Zhang, T. Hu, M. Wei, Y. Liu, J. Yang, Nanomaterials 2018, 8, 711.
H. Pan, S. Lan, S. Xu, Q. Zhang, H. Yao, Y. Liu, F. Meng, E.-J. Guo, L. Gu, D. Yi, X. R. Wang, H. Huang, J. L. MacManus-Driscoll, L. Chen, K. J. Jin, C. W. Nan, Y. Lin, Science 2021, 374, 100.
X. Jiang, Y. Liu, Y. Zang, Y. Liu, T. Gao, N. Zheng, Z. Gu, Y. Yang, D. Wu, Y. Nie, APL Mater. 2022, 10, 091110.
H. L. Liu, M.-T. Lin, Y. Cai, C.-H. Tung, Y. H. Chu, Appl. Phys. Lett. 2013, 103, 181907.
G. Catalan, J. F. Scott, Adv. Mater. 2009, 21, 2463.
S. Hazra, T. Schwaigert, A. Ross, H. Lu, U. Saha, V. Trinquet, B. Akkopru-Akgun, B. Z. Gregory, A. Mangu, S. Sarker, T. Kuznetsova, S. Sarker, X. Li, M. R. Barone, X. Xu, J. W. Freeland, R. Engel-Herbert, A. M. Lindenberg, A. Singer, S. Trolier-McKinstry, D. A. Muller, G.-M. Rignanese, S. Salmani-Rezaie, V. A. Stoica, A. Gruverman, L.-Q. Chen, D. G. Schlom, V. Gopalan, Adv. Mater. 2024, 2408664.
G. Dong, S. Li, M. Yao, Z. Zhou, Y.-Q. Zhang, X. Han, Z. Luo, J. Yao, B. Peng, Z. Hu, H. Huang, T. Jia, J. Li, W. Ren, Z.-G. Ye, X. Ding, J. Sun, C.-W. Nan, L.-Q. Chen, J. Li, Science 2019, 366, 475.
D. Ji, S. Cai, T. R. Paudel, H. Sun, C. Zhang, L. Han, Y. Wei, Y. Zang, M. Gu, Y. Zhang, W. Gao, H. Huyan, W. Guo, D. Wu, Z. Gu, E. Y. Tsymbal, P. Wang, Y. Nie, X. Pan, Nature 2019, 570, 87.
S. Cai, Y. Lun, D. Ji, P. Lv, L. Han, C. Guo, Y. Zang, S. Gao, Y. Wei, M. Gu, C. Zhang, Z. Gu, X. Wang, C. Addiego, D. Fang, Y. Nie, J. Hong, P. Wang, X. Pan, Nat. Commun. 2022, 13, 5116.
Y. Zang, C. Di, Z. Geng, X. Yan, D. Ji, N. Zheng, X. Jiang, H. Fu, J. Wang, W. Guo, H. Sun, L. Han, Y. Zhou, Z. Gu, D. Kong, H. Aramberri, C. Cazorla, J. Íñiguez, R. Rurali, L. Chen, J. Zhou, D. Wu, M. Lu, Y. Nie, Y. Chen, X. Pan, Adv. Mater. 2022, 34, 2105778.
Z. Ding, Y. Sun, N. Zheng, X. Ma, M. Wang, Y. Zang, P. Yu, Z. Chen, P. Wang, Y. Wang, Y. Yang, Y. Nie, F. Shi, J. Du, Adv. Funct. Mater. 2023, 33, 2213725.
J.-Y. Chauleau, E. Haltz, C. Carrétéro, S. Fusil, M. Viret, Nat. Mater. 2017, 16, 803.
S. Wu, X. Chen, C. Hong, X. Hou, Z. Wang, Z. Sheng, Z. Sun, Y. Guo, S. Wu, arXiv (Cornell University) 2023.
Y. Zhou, C. Guo, G. Dong, H. Liu, Z. Zhou, B. Niu, D. Wu, T. Li, H. Huang, M. Liu, T. Min, Nano Lett. 2022, 22, 2859.
G. Dong, S. Li, T. Li, H. Wu, T. Nan, X. Wang, H. Liu, Y. Cheng, Y. Zhou, W. Qu, Y. Zhao, B. Peng, Z. Wang, Z. Hu, Z. Luo, W. Ren, S. J. Pennycook, J. Li, J. Sun, Z.-G. Ye, Z. Jiang, Z. Zhou, X. Ding, T. Min, M. Liu, Adv. Mater. 2020, 32, 2004477.
T. Moriya, Phys. Rev. 1960, 120, 91.
S.-W. Cheong, M. Mostovoy, Nat. Mater. 2007, 6, 13.
I. Dzyaloshinsky, J. Phys. Chem. Solids 1958, 4, 241.
H. Katsura, N. Nagaosa, A. V. Balatsky, Phys. Rev. Lett. 2005, 95, 057205.
D. Rahmedov, D. Wang, J. Íñiguez, L. Bellaiche, Phys. Rev. Lett. 2012, 109, 037207.
S. Meyer, B. Xu, M. J. Verstraete, L. Bellaiche, B. Dupé, Phys. Rev. B 2023, 108, 024403.
R. R. Birss, Symmetry and Magnetism, North-Holland Publishing Company, Amsterdam, 1964.
J. Shi, P. Yu, F. Liu, P. He, R. Wang, L. Qin, J. Zhou, X. Li, J. Zhou, X. Sui, S. Zhang, Y. Zhang, Q. Zhang, T. Chien Sum, X. Qiu, Z. Liu, X. Liu, Adv. Mater. 2017, 29, 1701486.
K. Yao, N. Finney, J. Zhang, S. L. Moore, L. Xian, N. Tancogne-Dejean, F. Liu, J. Ardelean, X. Xu, D. Halbertal, K. Watanabe, T. Taniguchi, H. Ochoa, Asenjo-Garcı́aA, X. Zhu, D. N. Basov, Á. Rubio, C. Dean, J. Hone, P. James Schuck, Sci. Adv. 2021, 7, abe8691.
J. W. McIver, D. Hsieh, S. G. Drapcho, D. H. Torchinsky, D. R. Gardner, Y. S. Lee, N. Gedik, Phys. Rev. B 2012, 86, 03532.
J. S. Wang, K. J. Jin, H. Z. Guo, J. X. Gu, Q. Wan, X. He, X. L. Li, X. L. Xu, G. Z. Yang, Sci. Rep. 2016, 6, srep38268.
J. H. Lee, K. Chu, A. A. Ünal, S. Valencia, F. Kronast, S. Kowarik, J. Seidel, C. H. Yang, Phys. Rev. B 2014, 89, 140101.
J. S. Wang, K. J. Jin, J. X. Gu, Q. Wan, H. B. Yao, G. Z. Yang, Sci. Rep. 2017, 7, 9051.
C. W. Nicholson, M. Rumo, A. Pulkkinen, G. Kremer, B. Salzmann, M. L. Mottas, B. Hildebrand, T. Jaouen, T. K. Kim, S. Mukherjee, K. Ma, M. Muntwiler, F. O. Rohr, C. Cacho, C. Monney, Commun. Mater. 2021, 2, 25.
L. Han, Y. Fang, Y. Zhao, Y. Zang, Z. Gu, Y. Nie, X. Pan, Adv. Mater. Interfaces 2020, 7, 1901604.
A. Haykal, J. Fischer, W. Akhtar, J.-Y. Chauleau, D. Sando, A. Finco, F. Godel, Y. A. Birkhölzer, C. Carrétéro, N. Jaouen, M. Bibes, M. Viret, S. Fusil, V. Jacques, V. Garcia, Nat. Commun. 2020, 11, 1704.
H. Wang, L. Zhang, J. Han, W. E., Comput. Phys. Commun. 2018, 228, 178.
J. Zeng, D. Zhang, D. Lu, P. Mo, Z. Li, Y. Chen, M. Rynik, L. Huang, Z. Li, S. Shi, Y. Wang, H. Ye, P. Tuo, J. Yang, D. Ye, Y. Li, D. Tisi, Q. Zeng, B. Han, Y. Lei, J. Chem. Phys. 2023, 159, 054801.
C. Ederer, N. A. Spaldin, Phys. Rev. B 2005, 71, 060401.
C. Weingart, N. Spaldin, E. Bousquet, Phys. Rev. B 2012, 86, 094413.
S. Meyer, B. Xu, L. Bellaiche, B. Dupé, Phys. Rev. B 2024, 109, 184431.
B. Xu, S. Meyer, M. J. Verstraete, L. Bellaiche, B. Dupé, Phys. Rev. B 2021, 103, 214423.
H. Gao, C. Chen, L. You, F. Sun, C. Lu, S. Yang, G. Zhou, D. Chen, Y. Han, J.-M. Liu, Adv. Opt. Mater. 2022, 10, 2200831.
X. Deng, C. Chen, D. Chen, X. Cai, X. Yin, C. Xu, F. Sun, C. Li, Y. Li, H. Xu, M. Ye, G. Tian, Z. Fan, Z. Hou, M. Qin, Y. Chen, Z. Luo, X. Lu, G. Zhou, L. Chen, N. Wang, Y. Zhu, X. Gao, J.-M. Liu, Matter 2021, 4, 1323.
P. Němec, M. Fiebig, T. Kampfrath, A. V. Kimel, Nat. Phys. 2018, 14, 229.
Z. Sun, Y. Yi, T. Song, G. Clark, B. Huang, Y. Shan, S. Wu, D. Huang, C. Gao, Z. Chen, M. McGuire, T. Cao, D. Xiao, W. T. Liu, W. Yao, X. Xu, S. Wu, Nature 2019, 572, 497.
M. Nývlt, F. Bisio, J. Kirschner, Phys. Rev. B 2008, 77, 014435.
L. Mennel, M. M. Furchi, S. Wachter, M. Paur, D. K. Polyushkin, T. Mueller, Nat. Commun. 2018, 9.
L. Mennel, M. Paur, T. Mueller, APL Photonics 2019, 4.
J. Liang, J. Z. Zhang, Z. Li, H. Hong, J. Wang, Z. Zhang, X. Zhou, R. Qiao, J. Xu, Y. Feng, Z. Liu, Z. Sun, S. Meng, K. Liu, D. Yu, Nano Lett. 2017, 17, 7539.
R. Xu, J. Huang, E. S. Barnard, S. S. Hong, P. Singh, E. K. Wong, T. Jansen, V. Harbola, J. Xiao, B. Y. Wang, S. Crossley, D. Lu, S. Liu, H. Y. Hwang, Nat. Commun. 2020, 11, 3141.
B. Peng, R.-C. Peng, Y.-Q. Zhang, G. Dong, Z. Zhou, Y. Zhou, T. Li, Z. Liu, Z. Luo, S. Wang, Y. Xia, R. Qiu, X. Cheng, F. Xue, Z. Hu, W. Ren, Z.-G. Ye, L.-Q. Chen, Z. Shan, T. Min, M. Liu, Sci. Adv. 2020, 6, 5847.
S. S. Hong, M. Gu, M. Verma, V. Harbola, B. Y. Wang, D. Lu, A. Vailionis, Y. Hikita, R. Pentcheva, J. M. Rondinelli, H. Y. Hwang, Science 2020, 368, 71.
S. Huang, S. Xu, C. Ma, P. Li, E.-J. Guo, C. Ge, C. Wang, X. Xu, M. He, G. Yang, K. Jin, Adv. Sci. 2024, 11, 2307571.
S. Bandyopadhyay, B. F. Grosso, N. A. Spaldin, Ph. Ghosez. unpublished, 2024.
X. Gonze, B. Amadon, P.-M. Anglade, J.-M. Beuken, F. Bottin, P. Boulanger, F. Bruneval, D. Caliste, R. Caracas, M. Côté, T. Deutsch, L. Genovese, P. Ghosez, M. Giantomassi, S. Goedecker, D. R. Hamann, P. Hermet, F. Jollet, G. Jomard, S. Leroux, Comput. Phys. Commun. 2009, 180, 2582.
X. Gonze, J.-M. Beuken, R. Caracas, F. Detraux, M. Fuchs, G.-M. Rignanese, L. Sindic, M. Verstraete, G. Zerah, F. Jollet, M. Torrent, A. Roy, M. Mikami, P. Ghosez, J.-Y. Raty, D. C. Allan, Comput. Mater. Sci. 2002, 25, 478.
X. Gonze, Z. Kristallogr. – Cryst. Mater. 2005, 220, 558.
M. Torrent, F. Jollet, F. Bottin, G. Zérah, X. Gonze, Comput. Mater. Sci. 2008, 42, 337.
A. P. Thompson, H. M. Aktulga, R. Berger, D. S. Bolintineanu, W. M. Brown, P. S. Crozier, P. J. in ’t Veld, A. Kohlmeyer, S. G. Moore, T. D. Nguyen, R. Shan, M. J. Stevens, J. Tranchida, C. Trott, S. J. Plimpton, Comput. Phys. Commun. 2022, 271, 108171.
H. Krakauer, M. Posternak, A. J. Freeman, Phys. Rev. B 1979, 19, 1706.
E. Wimmer, H. Krakauer, M. Weinert, A. J. Freeman, Phys. Rev. B 1981, 24, 864.
D. Wortmann, G. Michalicek, R. Hilgers, A. Neukirchen, H. Janssen, U. Grytsiuk, J. Broeder, C. R. Gerhorst, Zenodo 2023.
A. Mackintosh, O. Andersen, Magnetism in Metals, Cambridge University, London, 1980, p. 149.
S. H. Vosko, L. Wilk, M. Nusair, Can. J. Phys. 1980, 58, 1200.
