ring-opening polymerization; lactone; polymer functionalization; thiol ene reaction
Abstract :
[en] The Michael-type addition of aliphatic (co)polyesters onto gamma-acryloyloxy epsilon-caprolactone units is a very straightforward technique of functionalization and grafting, which is tolerant to a variety of functional groups and does not require intermediate protection/deprotection steps.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Rieger, Jutta ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Van Butsele, Kathy ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Lecomte, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Versatile functionalization and grafting of poly(epsilon-caprolactone) by Michael-type addition
Publication date :
14 January 2005
Journal title :
Chemical Communications
ISSN :
1359-7345
eISSN :
1364-548X
Publisher :
Royal Society of Chemistry, Cambridge, United Kingdom
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
D. Tian, P. Dubois and R. Jérôme, Macromolecules, 1997, 30, 2575.
D. Tian, P. Dubois and R. Jérôme, Macromol. Symp., 1998, 130, 217.
P. Lecomte, V. d'Aloia, M. Mazza, O. Halleux, S. Gautier, C. Detrembleur and R. Jérôme, Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.), 2000, 41, 1534.
M. Heggli, N. Tirelli, A. Zisch and J. A. Hubbell, Bioconjugate Chem., 2003, 14, 967.
D. Mecerreyes, J. Humes, R. D. Miller, J. L. Hedrick, C. Detrembleur, P. Lecomte, R. Jérôme and J. San Roman, Macromol. Rapid Commun., 2000, 21, 779.
N. Tirelli, M. P. Lutolf, A. Napoli and J. A. Hubbel, Rev. Mol. Biotechnol., 2002, 90, 3.
F. Vidal and T. Hamaide, Polym. Bull., 1995, 35, 1.
X. Lou, C. Jérôme, C. Detrembleur and R. Jérôme, Langmuir, 2002, 18, 2785.
R. Gref, P. Couvreur, G. Barratt and E. Mysiakine, Biomaterials, 2003, 24, 4529.
