No full text
Paper published in a book (Scientific congresses and symposiums)
Structural features and transport properties of iodine intercalated misfit layer [BiCaO2]2[CoO2]1.69 single crystals
Guilmeau, E; Pollet, M; Grebille, D et al.
2005In International Conference on Thermoelectrics, ICT, Proceedings
 

Files


Full Text
No document available.

Send to



Details



Abstract :
[en] The thermopower and the electrical resistivity of [BiCaO2] 2[CoO2]1.69 and corresponding iodine intercalated single crystals have been measured. Upon intercalation, the thermopower is drastically decreased, indicating that there is a hole doping by charge transfer from the intercalated iodine layer to the hexagonal CoO 2 layer. The resistivity is increased due to stacking faults and disordered structures. Structural analyses confirmed the stacking scheme along the c direction, with the localisation of iodine between the [BiO] double layers. The effect of intercalation on the thermoelectric properties suggested discussions from the view point of hole doping and nano-block layer coupling effect. © 2005 IEEE.
Disciplines :
Chemistry
Author, co-author :
Guilmeau, E;  Laboratory of Structural Inorganic Chemistry, University of Liège, Building B6, Sart-Tilman, B4000 Liège, Belgium ; National Institute of Advanced Industrial Science and Technology, Midorigaoka, Ikeda, Osaka 563-8577, Japan
Pollet, M;  Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), CNRS, Université de Bordeaux 1, F-33608 Pessac, 87 Avenue du Dr A. Schweitzer, France
Grebille, D;  CRISMAT-ENSICAEN Laboratory, UMR CNRS 6508, 14050 Caen Cedex, 6 Bd. Maréchal Juin, France
Hervieu, M;  CRISMAT-ENSICAEN Laboratory, UMR CNRS 6508, 14050 Caen Cedex, 6 Bd. Maréchal Juin, France
Muguerra, H;  CRISMAT-ENSICAEN Laboratory, UMR CNRS 6508, 14050 Caen Cedex, 6 Bd. Maréchal Juin, France
Cloots, Rudi ;  Université de Liège - ULiège > Département de chimie (sciences) > GREEnMat
Mikami, M;  National Institute of Advanced Industrial Science and Technology, Midorigaoka, Ikeda, Osaka 563-8577, Japan
Funahashi, R;  National Institute of Advanced Industrial Science and Technology, Midorigaoka, Ikeda, Osaka 563-8577, Japan
Language :
English
Title :
Structural features and transport properties of iodine intercalated misfit layer [BiCaO2]2[CoO2]1.69 single crystals
Publication date :
2005
Event name :
ICT'05: 24th International Conference on Thermoelectrics
Event place :
Clemson sc
Event date :
19 June 2005 through 23 June 2005
Main work title :
International Conference on Thermoelectrics, ICT, Proceedings
Publisher :
Institute of Electrical and Electronics Engineers (IEEE)
ISBN/EAN :
0-7803-9552-2
Available on ORBi :
since 22 September 2025

Statistics


Number of views
8 (0 by ULiège)
Number of downloads
0 (0 by ULiège)

Scopus citations®
 
0
Scopus citations®
without self-citations
0
OpenCitations
 
0
OpenAlex citations
 
0

Bibliography


Similar publications



Contact ORBi