Marincea, Stefan ; Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie ; Department INI, Geological Institute of Romania, Bucharest, Romania
Dumitraş, Delia-Georgeta; Department INI, Geological Institute of Romania, Bucharest, Romania
Sava Ghinet, Cristina; Department INI, Geological Institute of Romania, Bucharest, Romania
Dincă, George; Department INI, Geological Institute of Romania, Bucharest, Romania
Hatert, Frédéric ; Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie ; Department INI, Geological Institute of Romania, Bucharest, Romania
Depret, Martin ; Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Costin, Gelu; Department of Earth, Environmental and Planetary Sciences, Rice University, Houston, USA
Language :
English
Title :
Hydrothermal Scheelite Associated with Upper Cretaceous Intrusions in Romania: A Mineralogical Insight to the W Metallogeny
British Geological Survey Tungsten British Geological Survey BGS Keyworth, UK 2011 1 34
Yang X. Beneficiation studies of tungsten ores—A review Min. Eng. 2018 125 111 119 10.1016/j.mineng.2018.06.001
Han Z. Golev A. Edraki M.A. Review of tungsten resources and potential extraction from mine waste Minerals 2021 11 701 10.3390/min11070701
Grohol M. Veeh C. Study on the Critical Raw Materials for the EU 2023 DG Grow, European Commission, Luxembourg Publication Office of the EU Luxembourg 2023 1 152
Rowan L.R. Critical Mineral Resources: National Policy and Critical Minerals List Congressional Research Service Report: CRS Report R47982 2025 Library of Congress Washington, DC, USA 2025 1 22
Hocquard C. Les nouveaux métaux stratégiques: Métaux high-tech, «métaux verts», métaux stratégiques, vers une convergence Mag’Mat 2008 26 1 30
Liu Y. Jia D. Zhou Y. Zhou Y. Zhao J. Li Q. Liu B. Discovery of ABO4 scheelites with the extra low thermal conductivity through high-throughput calculations J. Mater. 2020 6 702 711 10.1016/j.jmat.2020.05.009
Li S. Bychkov K.L. Butenko D.S. Terebilenko K.V. Zhu Y. Han W. Baumer V.N. Slobodyanik M.S. Ji H. Klyui N.I. Scheelite-related MIIxBi1−xV1−xMoxO4 (MII—Ca, Sr) solid solution-based photoanodes for enhanced photoelectrochemical water oxidation Dalton Trans. 2020 49 2345 2355 10.1039/C9DT04417E
Shivakumar C. Saraf R. Behera S. Dhananjaya N. Nagabhushana H. Scheelite-type MWO4 (M = Ca, Sr, and Ba) nanophosphors: Facile synthesis, structural characterization, photoluminescence, and photocatalytic properties Mater. Res. Bull. 2015 61 422 432 10.1016/j.materresbull.2014.09.096
Potanina E.A. Orlova A.I. Mikhailov D.A. Nokhrin A.V. Chuvil’deev V.N. Boldin M.S. Sakharov N.V. Lantcev E.A. Tokarev M.G. Murashov A.A. Spark Plasma Sintering of fine-grained SrWO4 and NaNd(WO4)2 tungstates ceramics with the scheelite structure for nuclear waste immobilization J. Alloys Compd. 2019 774 182 190 10.1016/j.jallcom.2018.09.348
Liu X. Yang J. Chen Q. Study on spectral characteristics and color origin of scheelite from Xuebaoding, Pingwu County, Sichuan Province, P.R. China Minerals 2022 12 1344 10.3390/min12111344
Cao Q. Shi M. Yuan Y. Ma S. Lu H. Mineralogy and geochemical characteristics of scheelite deposit at Xuebaoding in Pingwu, Sichuan Province, China Minerals 2024 14 38 10.3390/min14010038
Koch A. Űber den Vesuvian und Scheelit von Csiklova Földtany Közlöny 1924 54 85 90
Superceanu C. New occurrences of scheelite in contact deposits from the Banatitic geochemical province Rev. Min. 1956 4–5 230 234 (In Romanian)
Constantinescu E. Ilinca G. Ilinca A. Laramian hydrothermal alteration and ore deposition inthe Oravița—Ciclova area, South–western Banat D. S.—Inst. Geol. Geofiz. 1988 72–73 13 26
Cioflică G. Vlad Ş. Iosof A. Panican A. Scheelite occurrences in the Bihor Massif Rev. Roum. Géol. Géoph. Géogr. 1976 20 169 177
Berza T. Constantinescu E. Vlad Ş.N. Upper Cretaceous magmatic series and associated mineralization in the Carpatho-Balkan Orogen Res. Geol. 1998 48 291 306 10.1111/j.1751-3928.1998.tb00026.x
Cioflică G. Vlad Ş. The correlation of the Laramian metallogenetic events belonging to the Carpatho-Balkan area Rev. Roum. Géol. Géophys. Géogr. Sér. Géol. 1973 17 217 224
Ciobanu C.L. Cook N.J. Stein H. Regional setting and geochronology of the Late Cretaceous Banatitic Magmatic and Metallogenetic Belt Miner. Depos. 2002 37 541 567 10.1007/s00126-002-0272-9
Zimmermann A. Stein H. Hannah J. Koželj D. Bogdanov K. Berza T. Tectonic configuration of the Apuseni—Banat—Timok—Srednogorie belt, Balkans–Southern Carpathians, constrained by high precision Re–Os molybdenite ages Miner. Depos. 2008 43 1 21 10.1007/s00126-007-0149-z
Ilinca G. Classic skarn localities of Romania: Contact metamorphism and mineralization related to Late Cretaceous magmatism Acta Min.-Petr. 2010 23 1 50
Ilinca G. Upper Cretaceous contact metamorphism and related mineralizations in Romania Acta Min.-Petr. Abstr. Ser. 2012 7 59 64
Vlad Ş.N. Banatite metallogeny of North Poiana Ruscă Mts. Revisited Geol. Anali Balkanskoga Poluostrva 2020 81 67 77 10.2298/GABP191113001V
Săndulescu M. Kräutner H. Borcoş M. Năstăseanu S. Patrulius D. Ştefănescu M. Ghenea C. Lupu M. Savu H. Bercia I. et al. Geological Map of Romania, scale 1:1,000,000 Institute of Geology and Geophysics Bucharest, Romania 1978
Meinert L.D. Dipple G.M. Nicolescu Ş. World skarn deposits Economic Geology 100th Anniversary Volume Society of Economic Geologists Littleton, CO, USA 2005 299 336
Soroiu M. Catilina R. Strutinski C. K-Ar ages on some igneous rocks from the southwestern end of the South Carpathians (Banat Hills) Rev. Roum. Phys. 1986 31 849 854
Gallhofer D. Magmatic Geochemistry and Geochronology in Relation to the Geodynamic and Metallogenetic Evolution of the Banat Region and Apuseni Mountains of Romania Ph.D. Thesis ETH Zürich Zürich, Switzerland 2015 Dissertation ETH no 22888 1 45
Bleahu M. Soroiu M. Catilina R. On the Cretaceous tectonic-magmatic evolution of the Apuseni Mountains as revealed by K-Ar dating Rev. Roum. Phys. 1984 29 123 130
Pavelescu L. Pop G.O. Weisz E. Popescu G. La nature et l’âge du batholite banatitique de Bihor Rep. XII-th Congress K.B.G.A. Cracow 1985 98 101
Cioflică G. Jude R. Lupulescu M. Cupriferous metallization processes associated with Upper Cretaceous–Eocene magmatites from Romania Rom. J. Mineral. 1992 76 1 16
Vlad Ş.N. Calcic skarns and transversal zoning in the Banat Mountains, Romania: Indicators of an Andean–type setting Miner. Depos. 1997 32 446 471 10.1007/s001260050113
Marincea Ş. Dumitraş D.-G. Contrasting types of boron-bearing deposits in magnesian skarns from Romania Ore Geol. Rev. 2019 112 102952 10.1016/j.oregeorev.2019.102952
Cioflică G. Vlad Ş. Stoici S. Repartition de la mineralization dans le skarn de Băița Bihorului Rev. Roum. Géol. Géoph. Géogr. 1971 15 43 58
Tămaş C.G. Andrii M.-P. Mineralogy of skarn ores from Băița Bihor, Northern Apuseni Mountains, Romania: A case study of Cu-, Bi- and Sn-minerals Minerals 2020 10 436 10.3390/min10050436
Armstrong J.T. Quantitative analysis of silicates and oxide minerals: Comparison of Monte Carlo, ZAF and Phi-Rho-Z procedures Microbeam Analysis Newbury D.E. San Francisco Press San Francisco, CA, USA 1988 239 246
Appleman D.E. Evans H.T. Jr. Indexing and least-squares refinement of powder diffraction data U.S. Geol. Surv. Comput. Contrib. 1973 20 60
Benoit P.H. Adaptation to microcomputer of the Appleman-Evans program for indexing and least-squares refinement of powder-diffraction data for unit-cell dimensions Am. Mineral. 1987 72 1018 1019
Kalinkina E.V. Kalinkin A.M. Forsling W. Makarov A.M. Sorption of atmospheric carbon dioxide and structural changes of Ca and Mg silicate minerals during grinding. II. Enstatite, åkermanite and wollastonite Int. J. Miner. Process. 2001 61 289 299 10.1016/S0301-7516(00)00038-7
Agilent Technologies Xcalibur CCD System, CrysAlis Software System Agilent Technologies Oxfordshire, UK 2012
Palatinus L. Chapuis G. Superflip—A computer program for the solution of crystal structures by charge flipping in arbitrary dimensions J. Appl. Crystallogr. 2007 40 786 790 10.1107/S0021889807029238
Petříček V. Dušek M. Palatinus L. Crystallographic computing system Jana2006: General features Z. Kristallogr. 2014 229 345 352 10.1515/zkri-2014-1737
Xu J. Ciobanu C.L. Cook N. Slattery A. Crystals from the powellite-scheelite series at the nanoscale: A case study from the Zhibula Cu skarn, Gangdese Belt, Tibet Minerals 2019 9 340 10.3390/min9060340
Wen J. Zheng S. Chu X. Jiang H. Zhao Y. Mineralogical characteristics of scheelite in the Xi’an tungsten deposit, western Hunan IOP Conf. Ser. Earth Env. Sci. 2021 658 012044 10.1088/1755-1315/658/1/012044
Ilinca G. Marincea Ş. Hydrotungstite from Oraviţa-Ciclova and Băiţa Bihor: The first occurrences in Romania Rom. J. Mineral. 1993 76 (Suppl. S1) 24 25
Poulin R.S. McDonald A.M. Kontak D.J. McClenaghan M.B. On the relationship between cathodoluminescence and the chemical composition of scheelite from geologically diverse ore-deposit environments Can. Mineral. 2016 54 1147 1173 10.3749/canmin.1500023
Xiao X. Zhou T. Shi K. White N.C. Fan Y. Wang F. Chen X. Trace elements and textures of scheelite in porphyry-skarn Cu-Au systems: The example of Dongguashan deposit, eastern China Ore Geol. Rev. 2022 149 105069 10.1016/j.oregeorev.2022.105069
Miranda A.C.R. Chemical Composition of Scheelite and its Application as An Indicator Mineral Ph.D. Thesis Laval University Québec, QC, Canada 2023 1 459
Kay M.I. Frazer B.C. Almodovar I. Neutron diffraction refinement of CaWO4 J. Chem. Phys. 1964 40 504 506 10.1063/1.1725144
Blanchard F. X-ray powder data for CaWO4, synthetic scheelite Powder Diffr. 1989 4 220 222 10.1017/S0885715600013774
Sleight A.W. Accurate cell dimensions for ABO4 molybdates and tungstates Acta Cryst. 1972 28 2899 2902 10.1107/S0567740872007186
Senyshyn A. Kraus H. Mikhailik V.B. Yakovyna V. Lattice dynamics and thermal properties of CaWO4 Phys. Rev. 2004 70 214306 10.1103/PhysRevB.70.214306
Hazen R.M. Finger L.W. Mariathasan J.W. High-pressure crystal chemistry of scheelite-type tungstates and molybdates J. Phys. Chem Solids 1985 46 253 263 10.1016/0022-3697(85)90039-3
Rabuffetti F.A. Culver S.P. Suescun L. Brutchey R.L. Structural disorder in AMoO4 (A = Ca, Sr, Ba) scheelite nanocrystals Inorg. Chem. 2014 53 1056 1061 10.1021/ic4025348
Shoji T. Sasaki N. Fluorescent color and X-ray powder data of synthesized scheelite- powellite series as guides to determine its composition Min. Geol. 1978 28 397 404
Palmer M.C. Geochemical Characterisation of Scheelite from New Zealand Ph.D. Thesis Otago University Dunedin, New Zealand 2021 1 220
Lu D. Mao J. Ye H. Wang P. Chao W. Yu M. Geochemistry of scheelite from Jiangligou skarn W-(Cu-Mo) deposit in the West Qinling orogenic belt, Northwest China: Implication on the multistage ore-forming processes Ore Geol. Rev. 2023 159 105525 10.1016/j.oregeorev.2023.105525
Palache C. Berman H. Frondel C. The System of Mineralogy. II. Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, etc. John Wiley and Sons New York, NY, USA 1951 1 1124
Mandarino J.A. The Gladstone-Dale relationship—Part I: Derivation of new constants Can. Mineral. 1976 14 498 502
Zalkin A. Templeton D.H. X-ray diffraction refinement of the calcium tungstate structure J. Chem. Phys. 1964 40 501 504 10.1063/1.1725143
Mandarino J.A. The Gladstone-Dale relationship. IV. The compatibility concept and its application Can. Mineral. 1981 19 441 450
Larsen E.S. The microscopic determination of the nonopaque minerals U.S. Geol. Surv. Bull. 1921 679 1 289
Brown I.D. Altermatt D. Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database Acta Cryst. B 1985 41 244 247 10.1107/S0108768185002063
Barker A.S. Infrared lattice vibrations in calcium tungstate and calcium molybdate Phys. Rev. A 1964 135 742 747 10.1103/PhysRev.135.A742
Clark G.M. Doyle W.P. IR spectra of anhydrous molybdates and tungstates Spectrochim. Acta 1966 22 1441 1447 10.1016/0371-1951(66)80137-6
Khanna R.K. Lippincott E.R. Infrared spectra of some scheelite structures Spectrochim. Acta A 1968 24 905 908 10.1016/0584-8539(68)80189-8
Zorina M.L. Syritso L.F. IR spectra and structures of tungstates J. Appl. Crystallogr. 1972 16 774 776 10.1007/BF00616233
Tarte P. Liegeois-Duyckaerts M. Vibrational studies of molybdates, tungstates and related compounds—I. New infrared data and assignments for the scheelite-type compounds XIIMoO4 and XIIWO4 Spectrochim. Acta A 1972 28 2029 2036 10.1016/0584-8539(72)80177-6
Iishi K. Study of the force field of scheelite Z. Kristallogr. 1975 141 31 58 10.1524/zkri.1975.141.1-2.31
Zhou P.L. Infrared spectra of wolframite and scheelite from tungsten ore deposits in Southern Ganzhou, Jiangxi Province Acta Mineral. Sinca 1984 4 319 322
Akimov A.N. Nikanovich M.V. Popov V.G. Umreiko D.S. Calculation and investigation of the vibrational spectra of scheelite structures MeWO4 (Me = Ca, Sr, Ba, Pb) Zh. Prikladn. Spektr. 1986 45 225 232 (In Russian) 10.1007/BF00657462
Chukanov N.V. Infrared Spectra of Mineral Species. Extended Library Springer Geochemistry/Mineralogy Berlin/Heidelberg, Germany 2014 1 1726
Russell J.P. Loudon R. The first-order Raman spectrum of calcium tungstate Proc. Phys. Soc. 1965 85 1029 1033 10.1088/0370-1328/85/5/321
Porto S.P.S. Scott J.F. Raman Spectra of CaWO4, SrWO4, CaMoO4, and SrMoO4 Phys. Rev. 1967 157 716 721 10.1103/PhysRev.157.716
Griffith W.P. Raman studies on rock-forming minerals. Part II. Minerals containing MO3, MO4, and MO6 groups J. Chem. Soc. A 1970 2 286 291 10.1039/j19700000286
Liegeois-Duyckaerts M. Tarte P. Vibrational studies of molybdates, tungstates and related compounds—II. New Raman data and assignments for the scheelite-type compounds Spectrochim. Acta A 1972 28 2037 2051 10.1016/0584-8539(72)80178-8
Basiev T.T. Sobol A.A. Voronko Y.K. Zverev P.G. Spontaneous Raman spectroscopy of tungstate and molybdate crystals for Raman lasers Opt. Mater. 2000 15 205 216 10.1016/S0925-3467(00)00037-9
Crane M. Frost R.L. Williams P.A. Kloprogge J.T. Raman spectroscopy of the molybdate minerals chillagite (tungstenian wulfenite-I4), stolzite, scheelite, wolframite and wulfenite J. Raman Spectrosc. 2002 33 62 66 10.1002/jrs.820
Frost R.L. Duong L. Weier M. Raman microscopy of selected tungstate minerals Spectrochim. Acta A Mol. Biomol. Spectrosc. 2004 60 1853 1859 10.1016/j.saa.2003.10.002
Müller A. Krebs B. Normal coordinate treatment of XY4-type molecules and ions with Td symmetry. Part I. Force constants of a modified valence force field and of the Urey-Bradley force field J. Molec. Spectr. 1967 24 180 197 10.1016/0022-2852(67)90081-1
Khanna R.K. Brower W.S. Guscott B.R. Lippincott E.R. Laser induced Raman spectra of some tungstates and molybdates J. Res. Nat. Inst. Stand. Techn. Phys. Chem. A 1968 72 81 84 10.6028/jres.072A.008
Kanamori H. Hayashi S. Ikeda Y.Y. External lattice vibration modes in scheelites J. Phys. Soc. Jap. 1974 36 511 516 10.1143/JPSJ.36.511
Daniel M.F. Desbat B. Lassegues J.C. Gerand B. Figlarz M. Infrared and Raman study of WO3⋅xH2O tungsten trioxide hydrates J. Solid State Chem. 1987 67 235 247 10.1016/0022-4596(87)90359-8
Gunasekaran S. Anbalagan G. Pandi S. Raman and infrared spectra of carbonates of calcite structure J. Raman Spectr. 2006 37 892 899 10.1002/jrs.1518
Newberry R. Swanson S. Scheelite skarn granitoids: An evaluation of the roles of magmatic source and process Ore Geol. Rev. 1986 1 57 81 10.1016/0169-1368(86)90005-3
Hsu L.C. Galli P. E, Origin of the scheelite-powellite series of minerals Econ. Geol. 1973 68 681 696 10.2113/gsecongeo.68.5.681
Hsu L.C. Effects of oxygen and sulfur fugacities on the scheelite-tungstenite and powellite-molybdenite stability relations Econ. Geol. 1977 72 664 670 10.2113/gsecongeo.72.4.664
Ishihara S. The magnetite-series and ilmenite-series granitic rocks Mining Geol. 1977 27 293 305
Ishihara S. The granitoid series and mineralization Economic Geology 75th Anniversary Volume The Economic Geology Publishing Company Littleton, CO, USA 1981 458 484
Sato K. Tungsten skarn deposit of the Fujigatani Mine, Southwest Japan Econ. Geol. 1980 75 1066 1082 10.2113/gsecongeo.75.7.1066
Song G.X. Qin K.Z. Li G. Evans N.J. Chen J. Scheelite elemental and isotopic signatures: Implication for the genesis of skarn-type W-Mo deposits in the Chizhou area, Anhui Province, eastern China Amer. Miner. 2014 99 303 317 10.2138/am.2014.4431
Warr L.N. IMA-CNMNC approved mineral symbols Min. Mag. 2021 85 291 320 10.1180/mgm.2021.43
Wang X.-S. Williams-Jones A.E. Hu R.Z. Lin-Bo S. Xian-Wu B. The role of fluorine in granite-related hydrothermal tungsten ore genesis: Results of experiments and modelling Geochim. Cosmochim. Acta 2021 292 170 187 10.1016/j.gca.2020.09.032
Qiu Y. Zhang R. Chou I.-M. Wang X. Hu W. Zhang W. Lu J. Li G. Li Z. Boron-rich ore-forming fluids in hydrothermal W-Sn deposits from South China: Insights from in situ Raman spectroscopic characterization of fluid inclusions Ore Geol. Rev. 2021 132 104048 10.1016/j.oregeorev.2021.104048