Mechanical Engineering; Geotechnical Engineering and Engineering Geology; General Chemistry; Control and Systems Engineering
Abstract :
[en] A laboratory-scale investigation was conducted to study the effects of flotation reagents and clay minerals on the recovery of electrum from the ore treated at the Dundee Precious Metals Krumovgrad operation. The first part of the study focused on assaying the impact of clays on gold flotation by conducting desliming tests prior to flotation. It was observed that when a large portion of the fines (<10 µm) was removed through desliming, the gold grade in the concentrate increased by a factor of 9. However, this improvement was accompanied by a slight decrease in recovery. Furthermore, a new collector suite was tested in order to increase gold recovery and reduce the dosage of potassium amyl xanthate (PAX) by replacing the current promoter (AERO®238) with a new one called AERO MAXGOLD™900. The best combination was found to be 95 g/t of potassium amyl xanthate supplemented with 4.5 g/t of AERO MAXGOLD™900. The addition of this reagent was seen as a practical method to increase the gold grade in the concentrate, although it did not significantly improve the recovery rate. The potential relevance of the results to deposits and operations with similar characteristics are discussed.
Disciplines :
Geological, petroleum & mining engineering
Author, co-author :
Demeusy, Bastien
Madanski, Deyan
Gaydardzhiev, Stoyan ; Université de Liège - ULiège > Département ArGEnCo > Traitement et recyclage des matières minérales (y compris les sols)
Language :
English
Title :
Laboratory flotation study of the DPM Krumovgrad gold ore (Bulgaria) – Effects from improved collector suite and ore desliming
Agorhom, E.A., Skinner, W., Zanin, M., Post-regrind selective depression of pyrite in pyritic copper–gold flotation using aeration and diethylenetriamine. Miner. Eng. 72 (2015), 36–46, 10.1016/j.mineng.2014.11.019.
Allan, G.C., Woodcock, J.T., A review of the flotation of native gold and electrum. Miner. Eng. 14:9 (2001), 931–962, 10.1016/S0892-6875(01)00103-0.
Bulatovic, S., Wyslouzil, D.M., GOLD RECOVERY: FLOTATION. In Encyclopedia of Separation Science. 2000, Elsevier, 2965–2975.
Chandra, A.P., Gerson, A.R., A review of the fundamental studies of the copper activation mechanisms for selective flotation of the sulfide minerals, sphalerite and pyrite. Adv. Colloid Interface Sci. 145:1–2 (2009), 97–110, 10.1016/j.cis.2008.09.001.
Chanturia, V.A., Nedosekina, T.V., Gapchich, A.O., Improving gold flotation selectivity by using new collecting agents. J. Min. Sci. 48:6 (2012), 1031–1038, 10.1134/S1062739148060111.
Chipfunhu, D., Zanin, M., Grano, S., The dependency of the critical contact angle for flotation on particle size – Modelling the limits of fine particle flotation. Miner. Eng. 24:1 (2011), 50–57, 10.1016/j.mineng.2010.09.020.
Cytec industry Inc. (2002). Mining Chemicals Handbook (K. A. Day, Ed.). https://www.911metallurgist.com/wp-content/uploads/2017/03/2002-cytec-mining-handbook924751.pdf.
Demeusy, B., Madanski, D., Bouzahzah, H., Gaydardzhiev, S., Mineralogical study of electrum grain size, shape and mineral chemistry in process streams from the Krumovgrad mine, Bulgaria. Minerals Eng., 198, 2023, 108080, 10.1016/j.mineng.2023.108080.
Dunne, R., Flotation of Gold and Gold-Bearing Ores. Gold Ore Processing: Project Development and Operations, Second edition, 2016, Elsevier, 315–338.
Farrokhpay, S., The importance of rheology in mineral flotation: A review. Miner. Eng. 36–38 (2012), 272–278, 10.1016/j.mineng.2012.05.009.
Farrokhpay, S., Ndlovu, B., Bradshaw, D., Behaviour of swelling clays versus non-swelling clays in flotation. Miner. Eng. 96–97 (2016), 59–66, 10.1016/j.mineng.2016.04.011.
Gardner, J. R., & Woods, R. (1977). The hydrophilic nature of gold and platinium. 6.
Gupta, V., Particle interactions in kaolinite suspensions and corresponding aggregate structures. J. Colloid Interface Sci., 9, 2011.
Hintikka, V.V., Leppinen, J.O., Potential control in the flotation of sulphide minerals and precious metals. Miner. Eng. 8:10 (1995), 1151–1158, 10.1016/0892-6875(95)00080-A.
Ivanova, T.A., Chanturia, V.A., Zimbovsky, I.G., New experimental evaluation techniques for selectivity of collecting agents for gold and platinum flotation from fine-impregnated noble metal ores. J. Min. Sci. 49:5 (2013), 785–794, 10.1134/S1062739149050134.
Jébrak, M., Marcoux, É., Géologie des ressources minérales. Ministère Des Ressources Naturelles Et Faune, 2008.
Kesler, S.E., Simon, A.F., Mineral resources, economics and the environment (Second edition). 2015, Cambridge University Press.
Klimpel, R.R., Industrial experiences in the evaluation of various flotation reagent schemes for the recovery of gold. Mining, Metallurgy & Exploration 16:1 (1999), 1–11, 10.1007/BF03402850.
Leppinen, J.O., Yoon, R.-H., Mielczarski, J.A., FT-IR studies of ethyl-xanthate adsorption on gold, silver and gold-silver alloys. Colloids Surf., 61, 1991, 10.1016/0166-6622(91)80309-C.
Lins, F.F., Adamian, R., The influence of some physical variables on gold flotation. Miner. Eng. 6:3 (1993), 267–277, 10.1016/0892-6875(93)90035-L.
Liu, S., Chen, X., Lauten, R.A., Peng, Y., Liu, Q., Mitigating the negative effects of clay minerals on gold flotation by a lignosulfonate-based biopolymer. Miner. Eng. 126 (2018), 9–15, 10.1016/j.mineng.2018.06.021.
McGrath, T.D.H., O'Connor, L., Eksteen, J.J., A comparison of 2D and 3D shape characterisations of free gold particles in gravity and flash flotation concentrates. Miner. Eng. 82 (2015), 45–53, 10.1016/j.mineng.2015.04.022.
Miller, J.D., Misra, M., Gopalakrishnan, S., Gold flotation from Colorado River sand with the air-sparged hydrocyclone. Mining, Metallurgy & Exploration 3:3 (1986), 145–148, 10.1007/BF03402651.
Moncayo-Riascos, I., Hoyos, B.A., Effect of collector molecular structure on the wettability of gold for froth flotation. Appl. Surf. Sci. 420 (2017), 691–699, 10.1016/j.apsusc.2017.05.197.
Ndlovu, B., Farrokhpay, S., Forbes, E., Bradshaw, D., Characterisation of kaolinite colloidal and flow behaviour via crystallinity measurements. Powder Technol. 269 (2015), 505–512, 10.1016/j.powtec.2014.09.029.
O'Connor, C.T., Dunne, R.C., The flotation of gold bearing ores—A review. Miner. Eng. 7:7 (1994), 839–849, 10.1016/0892-6875(94)90128-7.
Singer, D.A., Kouda, R., Examining risk in mineral exploration. Nat. Resour. Res. 8:2 (1999), 111–122, 10.1023/A:1021838618750.
Stefanova, V., Serafimovski, T., Tasev, G., Native gold composition and morphology through the mineral processing stages at the Bucim copper mine, Republic of Macedonia. Geol. Macedonica 34:1 (2018), 59–74.
Teague, A.J., Van Deventer, J.S.J., Swaminathan, C., A conceptual model for gold flotation. Miner. Eng. 12:9 (1999), 1001–1019, 10.1016/S0892-6875(99)00087-4.
Woods, R., Basilio, C.I., Kim, D.S., Yoon, R.-H., Chemisorption of ethyl xanthate on silver—Gold alloys. Colloids Surf. A Physicochem. Eng. Asp. 83:1 (1994), 1–7, 10.1016/0927-7757(93)02649-Y.
Woods, R., Kim, D.S., Basilio, C.I., Yoon, R.-H., A spectroelectrochemical study of chemisorption of ethyl xanthate on gold. Colloids Surf A Physicochem Eng Asp 94:1 (1995), 67–74, 10.1016/0927-7757(94)02964-T.
Xing, Y., Xu, M., Gui, X., Cao, Y., Rudolph, M., Butt, H.-J., Kappl, M., The role of surface forces in mineral flotation. Curr. Opin. Colloid Interface Sci. 44 (2019), 143–152, 10.1016/j.cocis.2019.11.005.
Yu, Y., Ma, L., Cao, M., Liu, Q., Slime coatings in froth flotation: A review. Miner. Eng. 114 (2017), 26–36, 10.1016/j.mineng.2017.09.002.
Zhang, M., Peng, Y., Effect of clay minerals on pulp rheology and the flotation of copper and gold minerals. Miner. Eng. 70 (2015), 8–13, 10.1016/j.mineng.2014.08.014.
Zhou, J.Y., Cabri, L.J., Gold process mineralogy: Objectives, techniques, and applications. JOM 56:7 (2004), 49–52, 10.1007/s11837-004-0093-7.